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Geological, geochemical and mineralogical features of some bauxite deposits from Nurra (Western Sardinia, Italy): insights on conditions of formation and parental affinity

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Abstract

Bauxite deposits are widespread in NW Sardinia. They formed during the middle Cretaceous, in consequence of a period of emergence of the Mesozoic carbonate shelf. In the Nurra area the geometries derived by the Middle Cretaceous tectonic phases controlled the ore typologies. Two bauxite profiles, laying on different bedrocks, were sampled. The bauxitization proceeded from the surface downward, with the accumulation of Al2O3 and residual ‘immobile’ elements (Al, Ti, HFSE), and corresponding mobility and loss of SiO2 and Fe2O3. Epigenetic kaolinite formed close to faults and joints, probably as a result of silicification, introduced by low temperature hydrothermal solutions. Rare earth elements, especially LREE, are concentrated in Fe-rich bauxite horizons, probably due to scavenging by goethite. REE-enrichment is not observed in the boehmite-rich horizons. Very high REE contents are observed in a Fe-depleted horizon due to the occurrence of REE accessory minerals, probably of the bastnäsite group. Conservative indices, including TiO2/Al2O3 and Ti/Cr ratios, and Eu anomalies (Eu/Eu*), suggest that the deposits formed by weathering of sediments derived from mafic rocks of the Hercynian basement. This, in turn, implies that the basement was exposed during middle Cretaceous.

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Acknowledgments

We thank Sardabauxiti for their logistic support and access to the Olmedo mine and also Igor M. Villa and an anonymous referee for precious comments and review. This study was financially supported by a grant from Fondazione Banco di Sardegna.

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Authors and Affiliations

  1. Istituto di Scienze Geologico-Mineralogiche, Università degli Studi di Sassari, Corso Angioj 10, Sassari, 07100, Italy

    Paola Mameli & Giacomo Oggiano

  2. Dipartimento di Scienze Geologiche, Università degli Studi della Basilicata, Campus di Macchia Romana, Potenza, 85100, Italy

    Giovanni Mongelli

  3. Dipartimento di Scienze della Terra e Geologico-Ambientali, Università degli Studi di Bologna, Piazza di Porta S. Donato, Bologna, 40126, Italy

    Enrico Dinelli

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  1. Paola Mameli
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Correspondence to Paola Mameli.

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Mameli, P., Mongelli, G., Oggiano, G. et al. Geological, geochemical and mineralogical features of some bauxite deposits from Nurra (Western Sardinia, Italy): insights on conditions of formation and parental affinity. Int J Earth Sci (Geol Rundsch) 96, 887–902 (2007). https://doi.org/10.1007/s00531-006-0142-2

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