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Dynamics of diffuse carbon dioxide emissions from Cumbre Vieja volcano, La Palma, Canary Islands

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Abstract

We report herein the results of 13 soil CO2 efflux surveys at Cumbre Vieja volcano, La Palma Island, the most active basaltic volcano in the Canary Islands. The CO2 efflux measurements were undertaken using the accumulation chamber method between 2001 and 2013 to constrain the total CO2 output from the studied area and to evaluate occasional CO2 efflux surveys as a volcanic surveillance tool for Cumbre Vieja. Soil CO2 efflux values ranged from non-detectable up to 2442 g m−2 days−1, with the highest values observed in the south, where the last volcanic eruption took place (Teneguía, 1971). Isotopic analyses of soil gas carbon dioxide suggest an organic origin as the main contribution to the CO2 efflux, with a very small magmatic gas component observed at the southern part of the volcano. Total biogenic and magmatic combined CO2 emission rates showed a high temporal variability, ranging between 320 and 1544 t days−1 and averaging 1147 t days−1 over the 220-km2 region. Two significant increases in the CO2 emission observed in 2011 and 2013 were likely caused by an enhanced magmatic endogenous contribution revealed by significant changes in the 3He/4He ratio in a CO2-rich cold spring. The relatively stable emission rate presented in this work defines the background CO2 emission range for Cumbre Vieja during a volcanic quiescence period.

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References

  • Allard P, Carbonelle J, Dajlevic D, Le Bronec J, Morel P, Robe MC, Maurenas JM, Faivre-Pierret R, Martins D, Sabroux JC, Zettwoog P (1991) Eruptive and diffuse emissions of CO2 from Mount Edna. Nature 351:387–391

    Article  Google Scholar 

  • Ancoechea E, Hernán F, Cendrero A, Cantragrel JM, Fúster JM, Ibarrola E, Coello J (1994) Constructive and destructive episodes in the building of a young Oceanic Island, La Palma, Canary Islands, and genesis of the Caldera de Taburiente. J Volcanol Geotherm Res 60:243–262

    Article  Google Scholar 

  • Arpa MC, Hernández PA, Padrón E, Reniva P, Padilla GD, Bariso E, Melián GV, Barrancos J, Nolasco D, Calvo D, Pérez NM, Solidum RU (2013) Geochemical evidence of magma intrusion inferred from diffuse CO2 emissions and fumarole plume chemistry: the 2010–2011 volcanic unrest at Taal volcano, Philippines. Bull Volcanol 75:747. doi:10.1007/s00445-013-0747-9

    Article  Google Scholar 

  • Barnes I, Irwin WP, White DE (1978) Global distribution of carbon dioxide discharges and major zones of seismicity. US Geol Surv Water Res Investig 78–39:1–12

    Google Scholar 

  • Barnes I, Evans WC, White D (1988) The role of mantle CO2 in volcanism. Appl Geochem 3:281–285

    Article  Google Scholar 

  • Baubron JC, Allard P, Toutain JP (1990) Diffuse volcanic emissions of carbon dioxide from Vulcano Island (Italy). Nature 344:51–53

    Article  Google Scholar 

  • Burton MR, Sawyer GM, Granieri D (2013) Deep carbon emission from volcanoes. Rev Mineral Geochem 75:323–354

    Article  Google Scholar 

  • Carapezza ML, Inguaggiato S, Brusca L, Longo M (2004) Geochemical precursors of the activity of an open-conduit volcano: the Stromboli 2002–2003 eruptive events. Geophys Res Lett 31:L07620

    Article  Google Scholar 

  • Cardellini C, Chiodini G, Frondini F (2003) Application of stochastic simulation to CO2 flux from soil: mapping and quantification of gas release. J Geophys Res 108:2425. doi:10.1029/2002JB002165

    Article  Google Scholar 

  • Carracedo JC (1996) A simple model for the genesis of large gravitational landslide hazards in the Canary Islands. In: McGuire WJ, Jones AP, Neuberg J (eds) Volcano instability on earth and other planets. Geol Soc Spec Pub110:125–135

  • Carracedo JC, Day S, Guillou H, Rodríguez-Badiola E, Canas JA, Pérez-Torrado FJ (1998) Hotspot volcanism close to a passive continental margin: the Canary Islands. Geol Mag 135:591–604

    Article  Google Scholar 

  • Cerling TE, Solomon DK, Quade J, Bowman JR (1991) On the isotopic composition of carbon in soil carbon dioxide. Geochim Cosmochim Acta 55:3403–3405

    Article  Google Scholar 

  • Chiodini G, Frondini F, Raco B (1996) Diffuse emission of CO2 from the Fossa crater, Vulcano Island (Italy). Bull Volcanol 58:41–50

    Article  Google Scholar 

  • Chiodini G, Cioni R, Guidi M, Raco B, Marini L (1998) Soil CO2 flux measurements in volcanic and geothermal areas. Appl Geochem 13:543–552

    Article  Google Scholar 

  • Clarke WB, Jenkins WB, Top Z (1976) Determination of tritium by mass spectrometric measurement of 3He. Int J Appl Radiat Isot 27:515–522. doi:10.1016/0020-708X(76)90082-X

    Article  Google Scholar 

  • Craig H (1953) The geochemistry of the stable carbon isotope. Geochim Cosmochim Acta 3:53–92

    Article  Google Scholar 

  • Day JMD, Hilton DR (2011) Origin of 3He/4He ratios in HIMU-type basalts constrained from Canary Island lavas. Earth Planet Sci Lett 305:226–234

    Article  Google Scholar 

  • Day SJ, Carracedo JC, Guillou H, Gravestock P (1999) Recent structural evolution of the Cumbre Vieja volcano, Canary Islands: volcanic rift zones reconfiguration as a precursor to volcano flank instability? J Volcanol Geotherm Res 94:135–167

    Article  Google Scholar 

  • Deutsch CV, Journel AG (1998) GSLIB: Geostatistical Software Library and Users Guide, 2nd ed. Oxford U

  • Frondini F, Chiodini G, Caliro S, Cardelini C, Granieri D, Ventura G (2004) Diffuse CO2 degassing at Vesuvio, Italy. Bull Volcanol 66:642–651

    Article  Google Scholar 

  • Gerlach TM, Doukas MP, McGee KA, Kessler R (2001) Soil efflux and total emission rates of magmatic CO2 at the Horseshoe Lake tree kill, Mammoth Mountain, California, 1995–1999. Chem Geol 177:101–116

    Article  Google Scholar 

  • Giammanco S, Gurrieri S, Valenza M (1998a) Anomalous soil CO2 degassing in relation to faults and eruptive fissures on Mount Etna (Sicily, Italy). Bull Volcanol 69:252–259

    Article  Google Scholar 

  • Giammanco S, Inguaggiato S, Valenza M (1998b) Soil and fumarole gases of Mount Edna: geochemistry and relations with volcanic activity. J Volcanol Geotherm Res 81:297–310

    Article  Google Scholar 

  • Giammanco S, Gurrieri S, Valenza M (2006) Fault-controlled soil CO2 degassing and shallow magma bodies: summit and lower east rift of Kilauea volcano (Hawaii), 1997. Pure Appl Geophys 163:853–867

    Article  Google Scholar 

  • González PJ, Tiampo KF, Camacho AG, Fernández J (2010) Shallow flank deformation at Cumbre Vieja volcano (Canary Islands): implications on the stability of steep-sided volcano flanks at oceanic islands. Earth Planet Sci Lett 297:545–557. doi:10.1016/j.epsl.2010.07.006

    Article  Google Scholar 

  • Graham DW (2002) Noble gases in MORB and OIB: observational constraints for the characterization of mantle source reservoirs. Rev Mineral Geochem 46:247–318

    Article  Google Scholar 

  • Granieri D, Carapezza ML, Chiodini G, Avino R, Caliro S, Ranaldi M, Ricci T, Tarchini L (2006) Correlated increase in CO2 fumarolic content and diffuse emission from La Fossa crater (Vulcano, Italy): evidence of volcanic unrest or increasing gas release from a stationary deep magma body? Geophys Res Lett 33:L13316

    Article  Google Scholar 

  • Hernández PA, Notsu K, Salazar JM, Mori T, Natale G, Okada H, Virgili G, Shimoike Y, Sato M, Pérez NM (2001a) Carbon dioxide degassing by advective flow from Usu volcano, Japan. Science 292:83–86

    Article  Google Scholar 

  • Hernández PA, Salazar JM, Shimoike Y, Mori T, Notsu K, Pérez NM (2001b) Diffuse emission of CO2 from Miyakejima volcano, Japan. Chem Geol 177:175–185

    Article  Google Scholar 

  • Hernández PA, Notsu K, Tsurumi M, Mori T, Ohno M, Shimoike Y, Salazar J, Pérez N (2003) Carbon dioxide emissions from soils at Hakkoda, north Japan. J Geophys Res 108(B4):2210

    Article  Google Scholar 

  • Hernández PA, Notsu K, Okada H, Mori T, Sato M, Barahona F, Pérez NM (2006) Diffuse emission of CO2 from Showa-Shinzan, Hokkaido, Japan: a sign of volcanic dome degassing. Pure appl geophys 163:869–881

    Article  Google Scholar 

  • Hernández PA, Padilla G, Padrón E, Pérez NM, Calvo D, Nolasco D, Melián G, Barrancos J, Dionis S, Rodríguez F, Sumino H (2012a) Analysis of long- and short-term temporal variations of the diffuse CO2 emission from Timanfaya volcano, Lanzarote, Canary Islands. Appl Geochem 27(12):2486–2499. doi:10.1016/j.apgeochem.2012.08.008

    Article  Google Scholar 

  • Hernández PA, Pérez NM, Fridriksson T, Egbert J, Ilyinskaya E, Thárhallsson A, Ívarsson G, Gíslason G, Gunnarsson I, Jónsson B, Padrón E, Melián G, Mori T, Notsu K (2012b) Diffuse volcanic degassing and thermal energy release from Hengill volcanic system, Iceland. Bull Volcanol 74:2435–2448. doi:10.1007/s00445-012-0673-2

    Article  Google Scholar 

  • Hilton DR, MacPherson CG, Elliot TR (2000) Helium isotope ratios in mafic phenocrysts and geothermal fluids from La Palma, the Canary Islands (Spain): Implications for HIMU mantle sources. Geochim Cosmochim Acta 64(12):2119–2132

    Article  Google Scholar 

  • Javoy M, Pineau F, Ilyama I (1978) Experimental determination of the isotopic fractionation between gaseous CO2 and carbon dissolved in tholeitic magma. Contrib Mineral Petrol 67:35–39

    Article  Google Scholar 

  • Maljanen M, Martikainen PJ, Aaltonen H, Silvola J (2002) Short-term variation in fluxes of carbon dioxide, nitrous oxide and methane in cultivated and forested organic boreal soils. Soil Biol Biochem 34:577–584

    Article  Google Scholar 

  • Marty B, Jambon A (1987) C/3He in volatile fluxes from the solid Earth: implications for carbon geodynamics. Earth Planet Sci Lett 83:16–26

    Article  Google Scholar 

  • Matsuda J, Matsumoto T, Sumino H, Nagao K, Yamamoto J, Miura Y, Kaneoka I, Takahata N, Sano Y (2002) The 3He/4He ratio of the new internal He Standard of Japan (HESJ). Geochem J 36:191–195

    Article  Google Scholar 

  • McGee KA, Sutton AJ, Elias T, Doukas MP, Gerlach TM (2006) Puhimau thermal area: a window into the upper east rift zone of Kilahuea volcano, Hawaii? Pure Appl Geophys 163:837–851

    Article  Google Scholar 

  • Melián G, Hernández PA, Padrón E, Pérez NM, Barrancos J, Padilla G, Dionis S, Rodríguez F, Calvo D (2014) Spatial and temporal variations of diffuse CO2 degassing at El Hierro volcanic system: relation to the 2011–2012 submarine eruption. J Geophys Res 119(9):6976–6991

    Article  Google Scholar 

  • Navarro JM (1993) Avance del Plan Hidrológico Insular. Conserjería de Obras Publicas Vivienda y Aguas. 242 pp

  • Notsu K, Mori T, Chanchah Do Vale S, Kagi H, Ito T (2006) Monitoring quiescent volcanoes by diffuse CO2 degassing: case study of Mt. Fuji, Japan. Pure Appl Geophys 163:825–835

    Article  Google Scholar 

  • Padilla G, Hernández P, Pérez NM, Pereda E, Padrón E, Melián G, Barrancos J, Rodríguez F, Dionis S, Calvo D, Herrera M, Strauch W, Muñoz A (2013) Anomalous Diffuse CO2 Emissions at the Masaya Volcano (Nicaragua) Related to Seismic-Volcanic Unrest. Pure Appl Geophys 1–14. doi:10.1007/s00024-013-0756-9

  • Padrón E, Melián G, Marrero R, Nolasco D, Barrancos J, Padilla G, Hernández PA, Pérez NM (2008) Changes in the diffuse CO2 emission and relation to seismic activity in and around El Hierro, Canary Islands. Pure Appl Geophys 165:95–114. doi:10.1007/978-3-7643-8738-9_7

    Article  Google Scholar 

  • Padrón E, Hernández PA, Pérez NM, Toulkeridis T, Melián G, Barrancos J, Virgili G, Sumino H, Notsu K (2012a) Fumarole/plume and diffuse CO2 emission from Sierra Negra caldera, Galapagos archipelago. Bull Volcanol 74:1509–1519. doi:10.1007/s00445-012-0610-4

    Article  Google Scholar 

  • Padrón E, Pérez NM, Hernández PA, Sumino H, Melián G, Barrancos J, Nolasco D, Padilla G (2012b) Helium emisión at Cumbre Vieja volcano, La Palma, Canary Islands. Chem Geol 312–313:138–147

    Article  Google Scholar 

  • Pan V, Holloway JR, Hervig RL (1991) The pressure and temperature dependence of carbon dioxide solubility in tholeiitic basalts melts. Geochim Cosmochim Acta 55:1587–1595

    Article  Google Scholar 

  • Parkinson KJ (1981) An improved method for measuring soil respiration in the field. J Appl Ecol 18:221–228

    Article  Google Scholar 

  • Pérez NM, Wakita H, Nakai S, Sano Y, Williams SN (1994) 3He/4He isotopic ratios in volcanic-hydrothermal discharges from the Canary Islands, Spain: implications on the origin of the volcanic activity. Mineral Mag 58A:709–710

    Article  Google Scholar 

  • Pérez NM, Hanor JS, Means J, Álvarez CE, Hernández Moreno JM (1996) Volcanogenic mercury pollution in the ground water system of La Palma, Canary Islands, Spain. Geogaceta 20(6):1302–1304

    Google Scholar 

  • Pérez NM, Padilla GD, Padrón E, Hernández PA, Melián G, Barrancos J, Dionis S, Nolasco D, Rodríguez F, Calvo D, Hernández I (2012) Precursory diffuse CO2 and H2S emission signatures of the 2011–2012 El Hierro submarine eruption, Canary Islands. Geophys Res Lett 39:L16311. doi:10.1029/2012GL052410

    Article  Google Scholar 

  • Pérez NM, Hernández PA, Padrón E, Melián G, Nolasco D, Barrancos J, Padilla G, Calvo D, Rodríguez F, Dionis S, Chiodini G (2013) An increasing trend of diffuse CO2 emission from Teide volcano (Tenerife, Canary Islands): geochemical evidence of magma degassing episodes. J Geol Soc London 170(4):585–592. doi:10.1144/jgs2012-125

    Article  Google Scholar 

  • Salazar JM, Hernández PA, Pérez NM, Melián G, Álvarez J, Segura F, Notsu K (2001) Diffuse emissions of carbon dioxide from Cerro Negro volcano, Nicaragua, Central America. Geophys Res Lett 28:4275–4278

    Article  Google Scholar 

  • Salazar JM, Pérez NM, Hernández PA, Soriano T, Barahona F, Olmos R, Cartagena R, López DL, Lima N, Melián G, Padrón E, Galindo I, Notsu K (2002) Precursory diffuse carbon dioxide degassing signatures of recent earthquakes in El Salvador, Central America. Earth Planet Sci Lett 205(1–2):81–89

    Article  Google Scholar 

  • Sano Y, Marty B (1995) Origin of carbon in fumarolic gas from island arcs. Chem Geol 119:265–274

    Article  Google Scholar 

  • Sano Y, Urabe A, Wakita H (1985) Chemical and isotopic composition of gases in geothermal fluids in Iceland. Geochem J 19:135–148

    Article  Google Scholar 

  • Sinclair AJ (1974) Selection of thresholds in geochemical data using probability graphs. J Geochem Explor 3:129–149

    Article  Google Scholar 

  • Staudigel H, Feraud G, Giannerini G (1986) The history of intrusive activity on the island of La Palma (Canary Islands). J Volcanol Geotherm Res 27:299–322

    Article  Google Scholar 

  • Stolper E, Holloway JR (1988) Experimental determination of the solubility of carbon dioxide in molten basalt at low pressure. Earth Planet Sci Lett 87:397–408

    Article  Google Scholar 

  • Sumino H, Nagao K, Notsu K (2001) Highly sensitive and precise measurement of helium isotopes using a mass spectrometer with double collector system. J Mass Spectrom Soc Jpn 492:61–68

    Article  Google Scholar 

  • Tennant CB, White ML (1959) Study of the distribution of some geochemical data. Econ Geol 54:1281–1290

    Article  Google Scholar 

  • Veeger AI (1991) Geochemical methods for evaluating the origin and evolution of ground water in volcanic rocks at La Palma Canary Islands, Spain. PhD Thesis, The University of Arizona, 241 pp

  • Viveiros F, Ferreira T, Cabral Vieira J, Silva C, Gaspar JL (2008) Environmental influences on soil CO2 degassing at Furnas and Fogo volcanoes (São Miguel Island, Azores archipelago). J Volcanol Geotherm Res 177:883–893

    Article  Google Scholar 

  • Ward SN, Day S (2001) Cumbre Vieja Volcano—potential collapse and tsunami at La Palma, Canary Islands. Geophys Res Lett 28:3397–3400. doi:10.1029/2001GL013110

    Article  Google Scholar 

  • Zar JH (1984) Biostatistical Análisis, 2nd edn. Prentice-Hall, Englewood, p 663

    Google Scholar 

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Acknowledgments

The authors wish to thank A. Alfaya, L. Fuentes, M. Brito, A. Concepción, A. Mena, R. Delgado, T. Cabrera, S. Vargas, M.D. Peraza, and G. López for their help during the fieldwork. Funds provided by projects ALERTA and ALERTA II (financially supported by INTERREG IIIB Azores-Canaries-Madeira), PI2001/025 (financially supported by Dirección General de Universidades e Investigación, Canary Islands Government), MAKAVOL (MAC/3/C161) by the European Union MAC2007–2013 Transnational Cooperation Program, ProID20100160 by Canarian Agency for Research, Innovation and Information Society (Canary Island Government) and by Cabildo Insular de Tenerife and Cabildo Insular de La Palma supported this work. We also thank the municipality of Fuencaliente for logistical support.

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  1. Eleazar Padrón

    Present address: Enviromental Research Division, Instituto Tecnológico y de Energías Renovables (ITER), 38611 Granadilla, Santa Cruz de Tenerife, Spain

Authors and Affiliations

  1. Enviromental Research Division, Instituto Tecnológico y de Energías Renovables (ITER), 38611 Granadilla, Santa Cruz de Tenerife, Spain

    Nemesio M. Pérez, Gladys Melián, Pedro A. Hernández, Germán Padilla & José Barrancos

  2. Instituto Volcanológico de Canarias (INVOLCAN), Antiguo Hotel Taoro, Parque Taoro, 22, 38400, Puerto de La Cruz, Tenerife, Spain

    Eleazar Padrón, Nemesio M. Pérez, Fátima Rodríguez, Gladys Melián, Pedro A. Hernández, Germán Padilla, José Barrancos, Samara Dionis & David Calvo

  3. Geochemical Research Center, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-0033, Japan

    Hirochika Sumino

  4. Center for Integrated Research and Education of Natural Hazards, Shizuoka University, Shizuoka, 422-8529, Japan

    Kenji Notsu

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  1. Eleazar Padrón
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Correspondence to Eleazar Padrón.

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Padrón, E., Pérez, N.M., Rodríguez, F. et al. Dynamics of diffuse carbon dioxide emissions from Cumbre Vieja volcano, La Palma, Canary Islands. Bull Volcanol 77, 28 (2015). https://doi.org/10.1007/s00445-015-0914-2

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