Abstract
Fuego volcano in Guatemala erupted in 1974 in a basaltic sub-Plinian event, which has been well documented and studied. In 1999, after a period of quiescence lasting 20 years, Fuego erupted again, this time less violently, but with persistent low-level activity. This study investigates the link between these episodes. Previous melt inclusion studies have shown magma erupted in 1974 to have been a volatile-rich hybrid tapped from a vertically extensive system. By contrast, magma erupted in 1999 and 2003 is similar in composition to that erupted in 1974, but melt inclusions are more evolved. Although melt inclusions from the later period are CO2 rich (up to ∼1,500 ppm), they have low H2O concentration (max 1.5 wt.%, compared to ∼6 wt.% in 1974). These melt inclusions have a modified H2O concentration due to diffusive re-equilibration at shallow pressures. Despite this diffusive exchange, both eruptions show evidence of recent mingling of the same low and higher K melts, one of which was slightly cooler than the other and as a result traversed the amphibole stability field. (210Pb/226Ra) data on selected bulk rock samples from 1974 suggest that whereas the cooler, more evolved end-member may have been degassing since the last major eruption in the 1930s, the warmer end-member intruded at most a decade prior to the 1974 eruption. The two end-members are thus batches of the same magma emplaced shallowly ∼30 years apart during which time the older batch was cooled and differentiated before mixing with the younger influx. The presence of the same two melts in the later eruptions suggests that magma in 1999 and 2003 is partly residual from 1974. The current eruptive activity is clearing the system of this residual magma prior to an expected new magma batch.
Similar content being viewed by others
References
Anderson AT Jr (1984) Probable relations between plagioclase zoning and magma dynamics, Fuego Volcano, Guatemala. Am Miner 69:660–676
Andres RJ, Rose WI, Stoiber RE, Williams SN, Matias O, Morales R (1993) A summary of sulfur dioxide emission rate measurements from Guatemalan volcanoes. Bull Volcanol 55:379–388
Atlas ZD, Dixon JE, Sen G, Finny M, Martin-Del Pozzo AL (2006) Melt inclusions from Volca’n Popocate’petl and Volca’n de Colima, Mexico: melt evolution due to vapor-saturated crystallization during ascent. J Volcanol Geotherm Res 153:221–240
Baker DR (2008) The fidelity of melt inclusions as records of melt composition. Contrib Miner Petrol 156:377–395
Berlo K, Turner S (2010) 210Pb–226Ra disequilibria in volcanic rocks. Earth Planet Sci Lett 296:155–164
Blundy J, Cashman K (2008) Petrologic reconstruction of magmatic system variables and processes. Rev Min Geochem 69:179–239
Blundy J, Cashman KV, Rust A, Witham F (2010) A case for CO2-rich arc magmas. Earth Planet Sci Lett 290:289–301
Chesner CA, Halsor SP (2006) The Escuintla and La Democracia debris avalanche deposits, Guatemala: constraining their sources. GSA special publication 412:105–120
Chesner CA, Rose WI Jr (1984) Geochemistry and evolution of the Fuego volcanic complex, Guatemala. J Volcanol Geotherm Res 21:25–44
Collins SJ, Pyle DM, Maclennan J (2009) Melt inclusions track pre-eruption storage and dehydration of magmas at Etna. Geology 37:571–574
Danyuchevsky LV, McNeill AW, Sobolev AV (2002) Experimental and petrological studies of melt inclusions in phenocrysts from mantle-derived magmas: an overview of techniques, advantages and complications. Chem Geol 183:5–24
Faure F, Schiano P (2005) Experimental investigation of equilibration conditions during forsterite growth and melt inclusion formation. Earth Planet Sci Lett 236:882–898
Foden JD, Green DH (1992) Possible role of amphibole in the origin of andesite: some experimental and natural evidence. Contrib Miner Petrol 109:479–493
Gaetani GA, Watson EB (2000) Open system behavior of olivine-hosted melt inclusions. Earth Planet Sci Lett 183:27–41
Gaetani GA, O’Leary JA, Shimizu N (2009) Mechanisms and timescales for re-equilibration of water in Olivine-hosted melt inclusions. Eos Trans AGU 90, Fall Meet Suppl, Abstract V51E-1770.
Gauthier PJ, Condomines M (1999) 210Pb–226Ra radioactive disequilibria in recent lavas and radon degassing: inferences on the magma chamber dynamics at Stromboli and Merapi volcanoes. Earth Planet Sci Lett 172:111–126
Ghaleb B, Pons-Branchu E, Deschamps P (2004) Improved method for radium extraction from environmental samples and its analysis by thermal ionization mass spectrometry. JAAS 19:906–910
Gill JB, Williams RW (1990) Th isotope and U-series studies of subduction-related volcanic rocks. Geochim Cosmochim Acta 54:1427–1442
Grove TL, Elkins-Tanton LT, Parman SW, Chatterjee N, Müntener O, Gaetani GA (2003) Fractional crystallization and mantle-melting controls on calc-alkaline differentiation trends. Contrib Miner Petrol 145:515–533
Halsor SP, Rose WI (1988) Common characteristics of paired volcanoes in northern Central America. J Geophys Res 93:4467–4476
Harris DM, Anderson AT (1984) Volatiles H2O, CO2 and Cl in a subduction related basalt. Contrib Miner Petrol 87:120–128
Humphreys MCS, Menand T, Blundy JD, Klimm K (2008) Magma ascent rates in explosive eruptions: constraints from H2O diffusion in melt inclusions. Earth Planet Sci Lett 270:25–40
Johnson ER, Wallace PJ, Cashman KV, Granados HD, Kent AJR (2008) Magmatic volatile contents and degassing-induced crystallization at Volcan Jorullo, Mexico: implications for melt evolution and the plumbing systems of monogenetic volcanoes. Earth Planet Sci Lett 269:478–487
Liu Y, Samaha N-T, Baker DR (2007) Sulfur concentration at sulfide saturation (SCSS) in magmatic silicate melts. Geochim Cosmochim Acta 71:1783–1799
Lloyd AS, Plank T, Ruprecht P, Hauri EH, Rose WI (2010) Volatile loss from melt inclusions in clasts of differing sizes. American Geophysical Union, Fall Meeting 2010, abstract #V24C-04
Lyons JJ, Waite GP, Rose WI, Chigna G (2009) Patterns in open vent, strombolian behavior at Fuego volcano, Guatemala, 2005–2007. Bull Volcanol 72:1–15
Martin DP, Rose WI Jr (1981) Behavioral patterns of Fuego volcano, Guatemala. J Volcanol Geotherm Res 10:67–81
Massare D, Métrich N, Clocchiatti R (2002) High-temperature experiments on silicate melt inclusions in olivine at 1 atm: inference on temperatures of homogenization and H2O concentrations. Chem Geol 183:87–98
Métrich N, Rutherford MJ (1998) Low pressure crystallization paths of H2O-saturated basaltic-hawaiitic melts from Mt Etna: implications for open-system degassing of basaltic volcanoes—thermochemical and dynamical inferences. Geochim Cosmochim Acta 62:1195–1205
Papale P, Moretti R, Barbato D (2006) The compositional dependence of the saturation surface of H2O+CO2 fluids in silicate melts. Chem Geol 229:78–95
Portnyagin M, Almeev R, Matveev S, Holtz F (2008) Experimental evidence for rapid water exchange between melt inclusions in olivine and host magma. Earth Planet Sci Lett 272:541–552
Putirka KD (2008) Thermometers and barometers for volcanic systems. Rev Min Geochem 69:61–120
Reubi O, Blundy J (2008) Assimilation of plutonic roots, formation of high-K ‘exotic’ melt inclusions and the genesis of andesitic magmas at Volcán de Colima, Mexico. J Pet 49:2221–2243
Ridolfi F, Renzulli A, Puerini M (2009) Stability and chemical equilibrium of amphibole in calc-alkaline magmas: an overview, new thermobarometric formulations and application to subduction-related volcanoes. Contrib Miner Petrol 160:45–66
Roberge J, Delgado-Granados H, Wallace PJ (2009) Mafic magma recharge supplies high CO2 and SO2 gas fluxes from Popocatépetl volcano, Mexico. Geology 37:107–110
Rodríguez LA, Watson IM, Rose WI, Branan YK, Bluth GJS, Chigna G, Matías O, Escobar D, Carn SA, Fischer TP (2004) SO2 emissions to the atmosphere from active volcanoes in Guatemala and El Salvador, 1999–2002. J Volcanol Geotherm Res 138:325–344
Roggensack K (2001) Unraveling the 1974 eruption of Fuego volcano (Guatemala) with small crystals and their young melt inclusions. Geology 29:911–914
Rose WI, Anderson AT Jr, Woodruff LG, Bonis SB (1978) The October 1974 basaltic tephra from Fuego volcano: description and history of the magma body. J Volcanol Geotherm Res 4:3–53
Rubin KH, Macdougall JD (1989) Submarine magma degassing and explosive magmatism at Macdonald (Tamarii) seamount. Nature 341:50–52
Rust AC, Cashman KV, Wallace PJ (2004) Magma degassing buffered by vapor flow through brecciated conduit margins. Geology 32:349–352
Sadofsky SJ, Portnyagin M, Hoernle K, van den Bogaard P (2007) Subduction cycling of volatiles and trace elements through the central American volcanic arc: evidence from melt inclusions. Contrib Mineral Petrol 155:433–456
Seaman SJ (2000) Crystal clusters, feldspar glomerocrysts, and magma envelopes in the Atascosa lookout lava flow, Southern Arizona, USA: recorders of magmatic events. J Pet 41:693–716
Siebert L, Simkin T (2002–2009) Volcanoes of the world: an illustrated catalog of Holocene volcanoes and their eruptions. Smithsonian Institution, Global Volcanism Program Digital Information Series, GVP-3. http://www.volcano.si.edu/world/2002–2009
Sisson TW, Grove TL (1993) Temperatures and H2O contents of low MgO high alumina basalts. Contrib Miner Petrol 113:167–184
Sisson TW, Layne GD (1993) H2O in basalt and basaltic andesite melt inclusions from four subduction-related volcanoes. Earth Planet Sci Lett 117:619–635
Spilliaert N, Allard P, Metrich N, Sobolev AV (2006) Melt inclusion record of the conditions of ascent, degassing, and extrusion of volatile rich alkali basalt during the powerful 2002 flank eruption of Mount Etna (Italy). J Geophys Res 111:B04203
Stewart DC (1975) Crystal clots in calc-alkaline andesites as breakdown products of high-Al amphiboles. Contrib Miner Petrol 53:195–204
Stewart ML, Pearce TH (2004) Sieve-textured plagioclase in dacitic magma: interference imaging results. Am Miner 89:348–351
Toplis MJ (2005) The thermodynamics of iron and magnesium partitioning between olivine and liquid: criteria for assessing and predicting equilibrium in natural and experimental systems. Contrib Miner Petrol 149:22–39
Van Orman JA, Saal AE (2009) Influence of crustal cumulates on 210Pb disequilibria in basalts. Earth Planet Sci Lett 284:284–291
Vigouroux N, Wallace PJ, Kent AJR (2008) Volatiles in high-K magmas from the western Trans-Mexican Volcanic Belt: evidence for fluid-flux melting and extreme enrichment of the mantle wedge by subduction processes. J Pet 49:1589–1618
Acknowledgements
KB and JS thank Otoniel Matias (and INSIVUMEH), John Lyons and Bill Rose for indispensable help with sample collection. The help of Lynda Williams and Richard Hervig was fundamental to data collection at the Arizona State University National SIMS Facility, which is supported by NSF EAR-0622775. Gordon Moore kindly lent us his H2O–CO2 glass standards. Bill Rose and Olivier Reubi are thanked for their thorough reviews of an earlier version of this work. During this research, KB was supported by a Rubicon fellowship from the Netherlands Organisation for Scientific Research (NWO) and JS by a grant from the Natural Sciences and Engineering Research Council of Canada (NSERC).
Author information
Authors and Affiliations
Corresponding author
Additional information
Editorial responsibility: M. Manga
Electronic supplementary material
Below is the link to the electronic supplementary material.
Supplementary data table (excel file
(1) Bulk rock XRF and ICP-MS data, (2) bulk rock 210Pb and 226Ra activities and (3) melt inclusion compositions, major elements (EMPA, anhydrous), trace elements (SIMS) and H2O + CO2 (SIMS). Olivine host composition and calculated pressure and temperature for olivine–host pairs. (XLS 74 kb)
Rights and permissions
About this article
Cite this article
Berlo, K., Stix, J., Roggensack, K. et al. A tale of two magmas, Fuego, Guatemala. Bull Volcanol 74, 377–390 (2012). https://doi.org/10.1007/s00445-011-0530-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00445-011-0530-8