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Inclusional association as studied by the drying dissipative structure. Part 3. Drying pattern of aqueous mixtures of β-cyclodextrin and n-alkyltrimethylammonium bromide

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Abstract

Macroscopic and microscopic drying patterns were observed on a cover glass and a watch glass during the course of dryness of aqueous mixtures of β-cyclodextrin (βCD) with n-alkyltrimethylammonium bromide (alkyl: n-decyl, n-dodecyl, n-tetradecyl, and n-hexadecyl). Macroscopic patterns of the broad rings and the spoke lines appeared. The inclusional association constants of βCD with the cationic surfactants were determined from the bent points in the curves of the drying broad-ring size vs. surfactant concentration when a finite amount of cyclodextrin presents. The short and thick rod-like microscopic drying patterns were observed for the inclusional complexes.

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Acknowledgment

The author would like to acknowledge the research funds from AMX Co. (Tokyo).

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  1. Institute for Colloidal Organization, Hatoyama 3-1-112, Uji, Kyoto, 611-0012, Japan

    Tsuneo Okubo

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  1. Tsuneo Okubo
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Correspondence to Tsuneo Okubo.

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Okubo, T. Inclusional association as studied by the drying dissipative structure. Part 3. Drying pattern of aqueous mixtures of β-cyclodextrin and n-alkyltrimethylammonium bromide. Colloid Polym Sci 291, 2599–2605 (2013). https://doi.org/10.1007/s00396-013-3009-7

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  • DOI: https://doi.org/10.1007/s00396-013-3009-7

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