Abstract
In this work, the preparation of micron-sized polymer particles with nonspherical shapes via seeded dispersion polymerization of 2-ethylhexyl methacrylate (EHMA) with polystyrene (PS) seed particles in the presence of decane droplets and evaporation of decane after the polymerization under various polymerization conditions was discussed. The effect of monomer and decane content and polarity of the medium on the shape of the obtained particles was investigated. The experimental results showed that decreasing the amount of monomer and hydrocarbon volume of PEHMA/hydrocarbon domains, the particles decreased but they grew symmetrically, resulting in symmetric shapes. Furthermore, it was suggested that because of changing the solubility of the oligoradicals and hydrocarbon in the medium, the shape of the particles changed with changing the polarity of the medium. With decreasing the polarity of the medium, solubility of the oligoradicals in the medium increases and bigger polymer domains form on the surface of PS particles which can absorb higher amounts of decane. All of these can contribute to an increase in volume reduction after extraction of PEHMA/decane, resulting in various particle shapes. Further decreasing in polarity of the medium leads to an increase in the solubility of decane in the medium and decreasing the absorbed amount of decane by PS particles and PEHMA domains, resulting in lower volume reduction after evaporation of decane.
References
Okubo M, Minami H (1996) Colloid Polym Sci 274:433–438
Okubo M, Minami H (1997) Colloid Polym Sci 275:992–997
Saito N, Kagari Y, Okubo M (2006) Langmuir 22:9397–9402
Tanaka T, Nakatsuru R, Kagari Y, Saito N, Okubo M (2006) Langmuir 24:12267–12271
Okubo M, Konishi Y, Takebe M, Minami H (2000) Colloid Polym Sci 278:919–926
Champion JA, Katare YK, Mitragotri S (2007) Proc Natl Acad Sci USA 104:11901–11904
Okubo M, Murakami Y, Tsukuda Y (1993) Chem Express 4:253–256
Okubo M, Murakami Y, Fujiwara T (1996) Colloid Polym Sci 274:520–524
Okubo M, Fujiwara T, Yamaguchi A (1997) Colloid Polym Sci 276:186–189
Okubo M, Kanaida K, Matsumoto T (1987) Colloid Polym Sci 265:876–881
Okubo M, Miya T, Minami H (2001) J Appl Polym Sci 83:2013–2021
Okubo M, Fujibayashi T, Yamada M, Minami H (2005) Colloid Polym Sci 283:1041–1045
Huang H, Liu H (2010) J Polymer Sci: Part A: Polymer Chemistry 48:5198–5205
Tolue S, Ghafelebashi SM, Moghbeli MR (2009) Eur Polym J 45:714–720
Okubo M, Katsuta Y, Matsumoto T (1980) J Polym Sci Polym Lett Ed 18:481–486
Okubo M, Wang Z, Yamashita T, Ise E, Minami H (2001) J Polym Sci 39:3106–3111
Okubo M, Minami H, Morikawa K (2001) Colloid Polym Sci 279:931–935
Okubo M, Takekoh R, Suzuki A (2002) Colloid Polym Sci 280:1057–1061
Okubo M, Fujibayashi T, Terada A (2005) Colloid Polym Sci 283:793–798
Fujibayashi T, Okubo M (2007) Langmuir 23:7958–7962
Hosseinzadeh S, Saadat Y, Abdolbaghi S (2012) Colloid Polym Sci. doi:10.1007/s00396-012-2638-6
Saadat Y, Hosseinzadeh S, Afshar-Taromi F, Eslami H (2012) Colloid Polym Sci. doi:10.1007/s00396-012-2677-z
Tseng CM, Lu YY, El-Aasser MS, Vanderho JW (1986) J Polym Sci Part A Polym Chem 24:2995–3007
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Eslami, H., Hosseinzadeh, S., Saadat, Y. et al. Effect of monomer and hydrocarbon content and polarity of the medium on the preparation of nonspherical particles via seeded dispersion polymerization in the presence of saturated hydrocarbon droplets. Colloid Polym Sci 290, 1463–1469 (2012). https://doi.org/10.1007/s00396-012-2723-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00396-012-2723-x