Abstract
Dissipative particle dynamics is a mesoscopic simulation method which allows one to predict the self-assembly of amphiphilic polymers and surfactants. It was possible to reproduce the formation of microemulsions of the oil/water (o/w), water/oil (w/o), and L3-type of C10E4 in water and n-decane with excellent accuracy. We are able to predict the experimentally not investigated emulsion formation of a poly(ethylene butylene)–poly(ethylene oxide) in water and methylcyclohexane.
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Schulz, S.G., Kuhn, H., Schmid, G. et al. Phase behavior of amphiphilic polymers: A dissipative particles dynamics study. Colloid Polym Sci 283, 284–290 (2004). https://doi.org/10.1007/s00396-004-1137-9
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DOI: https://doi.org/10.1007/s00396-004-1137-9