Skip to main content
SpringerLink
Log in

Investigation of the degradation mechanisms in BaMgAl10O17:Eu2+ phosphor: on the influence of thermal  process on operational durability

  • Published:
Applied Physics B Aims and scope Submit manuscript

Abstract

The thermal and operational degradation in optical property of a europium-doped barium magnesium aluminate (BaMgAl10O17:Eu2+, BAM) phosphor was studied. BAM was heat-treated at 500°C under various conditions to determine the mechanism of thermal degradation. Operational degradation tests were then performed under a discharging Xe/Ne mixed gas to study the influence of thermal history on operational degradation. It was found that the atmosphere during thermal processing was the major factor affecting not only the thermal degradation, but also the operational degradation. The sample heat-treated under a reducing atmosphere showed enhanced stability during operation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. C.R. Ronda, J. Lumin. 72, 49 (1997)

    Article  Google Scholar 

  2. A.W. De Jager-Veenis, A. Bril, J. Electrochem. Soc. 123, 1253 (1976)

    Article  Google Scholar 

  3. T. Justel, J.C. Krupa, D.U. Wiechert, J. Lumin. 93, 179 (2001)

    Article  Google Scholar 

  4. S. Zhang, T. Kono, A. Ito, T. Yasaka, H. Uchiike, J. Lumin. 106, 39 (2004)

    Article  Google Scholar 

  5. B. Howe, A.L. Diaz, J. Lumin. 109, 51 (2004)

    Article  Google Scholar 

  6. B. Moine, G. Bizarri, Mater. Sci. Eng. B 105, 2 (2003)

    Article  Google Scholar 

  7. S. Zhang, IEEE Trans. Plasma Sci. 34, 294 (2006)

    Article  ADS  Google Scholar 

  8. N. Iyi, Z. Inoue, S. Kimura, J. Solid State Chem. 61, 236 (1986)

    Article  ADS  Google Scholar 

  9. T. Onimaru, S. Fukuta, T. Misawa, K. Sakita, K. Betsui, J. Soc. Inf. Disp. 13, 45 (2005)

    Article  Google Scholar 

  10. Z. Wu, A.N. Cormack, J. Electroceram. 10, 179 (2003)

    Article  Google Scholar 

  11. K.B. Kim, Y.I. Kim, H.G. Chun, T.Y. Cho, J.S. Jung, J.G. Kang, Chem. Mater. 14, 5045 (2002)

    Article  Google Scholar 

  12. S. Oshio, S. Matsuoka, S. Tanaka, H. Kobayashi, J. Electrochem. Soc. 145, 3903 (1998)

    Article  Google Scholar 

  13. K.S. Sohn, S.S. Kim, H.D. Park, Appl. Phys. Lett. 81, 1759 (2002)

    Article  ADS  Google Scholar 

  14. H. Yamada, W.S. Shi, C.N. Xu, J. Electrochem. Soc. 151, E349 (2004)

    Article  Google Scholar 

  15. G. Bizarri, B. Moine, J. Lumin. 113, 199 (2005)

    Article  Google Scholar 

  16. K.C. Mishra, K.H. Johnson, P.C. Schmidit, J. Electrochem. Soc. 153, H202 (2006)

    Article  Google Scholar 

  17. I. Hirosawa, T. Honma, K. Kato, N. Kijima, Y. Shimomura, J. Soc. Inf. Disp. 13, 673 (2005)

    Article  Google Scholar 

  18. K.B. Kim, K.W. Koo, T.Y. Cho, H.G. Chun, Mater. Chem. Phys. 80, 682 (2003)

    Article  Google Scholar 

  19. B. Dawson, M. Ferguson, G. Marking, A.L. Diaz, Chem. Mater. 16, 5311 (2004)

    Article  Google Scholar 

  20. B. Moine, G. Biazarri, Opt. Mater. 28, 587 (2006)

    Article  ADS  Google Scholar 

  21. T. Jüstel, H. Bechter, W. Mayr, D.U. Wiechert, J. Lumin. 104, 137 (2003)

    Article  Google Scholar 

  22. B. Howe, A.L. Diaz, J. Lumin. 109, 51 (2004)

    Article  Google Scholar 

  23. H. Adachi, M. Tsukada, C.J. Satoko, Phys. Soc. Jpn. 45, 875 (1978)

    Article  ADS  Google Scholar 

  24. A. Ellens, F. Zwaschka, F. Kummer, A. Meijerink, M. Raukas, K. Mixhra, J. Lumin. 93, 147 (2001)

    Article  Google Scholar 

  25. V. Pike, S. Patraw, A.L. Diaz, B.G. DeBoer, J. Solid State Chem. 173, 359 (2003)

    Article  ADS  Google Scholar 

  26. D.R. Gaskell, Introduction to the Thermodynamics of Materials (Taylor & Francis, New York, 2003)

    Google Scholar 

  27. B.D. Evans, J. Nucl. Mater. 219, 202 (1995)

    Article  ADS  Google Scholar 

  28. K.H. Lee, J.H. Crawford Jr., Appl. Phys. Lett. 33, 274 (1978)

    ADS  Google Scholar 

  29. R. Ramírez, M. Tardío, R. Gonzàlez, J.E. Muñoz Santiuste, J. Appl. Phys. 101, 123520 (2007)

    Article  ADS  Google Scholar 

  30. J. Solé, L. Bausa, D. Jaque, An Introduction to the Optical Spectroscopy of Inorganic Solids (Wiley, New York, 2005)

    Book  Google Scholar 

  31. R.S. Mulliken, J. Chem. Phys. 23, 1833 (1955)

    Article  ADS  Google Scholar 

  32. R.S. Mulliken, J. Chem. Phys. 23, 1841 (1955)

    Article  ADS  Google Scholar 

  33. R.S. Mulliken, J. Chem. Phys. 23, 2338 (1955)

    Article  ADS  Google Scholar 

  34. N.C. Mohanty, S.V. Mishra, S.V. Bhat, P.K. Basu, D. Kanjilal, J. Phys. D 36, 3151 (2003)

    Article  ADS  Google Scholar 

  35. S. Nagata, S. Yamamoto, K. Toh, B. Tsuchiya, N. Ohtsu, T. Shikama, H. Naramoto, J. Nucl. Mater. 329, 1507 (2004)

    Article  ADS  Google Scholar 

  36. J. Wong, J.L. Ferriera, E.F. Lindsey, D.L. Haupt, I.D. Hutcheon, J.H. Kinney, J. Non-Cryst. Solids 352, 255 (2006)

    Article  ADS  Google Scholar 

  37. K. Awazu, J. Non-Cryst. Solids 337, 241 (2004)

    Article  ADS  Google Scholar 

  38. S. Xu, X. Yuan, X. Zu, H. Lv, X. Jiang, L. Zhang, W. Zheng, J. Non-Cryst. Solids 353, 4212 (2007)

    Article  ADS  Google Scholar 

  39. B.P. Uberuaga, D. Bacorisen, R. Smith, J.A. Ball, R.W. Grimes, A.F. Voter, K.E. Sickafus, Phys. Rev. B 75, 104116 (2007)

    Article  ADS  Google Scholar 

  40. K. Ando, Y. Oishi, J. Chem. Phys. 61, 625 (1974)

    Article  ADS  Google Scholar 

  41. R. Lindner, A. Akerstrom, Z. Phys. Chem. 18, 303 (1958)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Materials Science and Engineering, Seoul National University, Seoul, 151-742, Korea

    Y. Kim & S. Kang

  2. Samsung SDI Co., Ltd, Yongin-si, Gyeonggi-do, 446-577, Korea

    Y. Kim

Authors
  1. Y. Kim
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. Kang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. Kang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kim, Y., Kang, S. Investigation of the degradation mechanisms in BaMgAl10O17:Eu2+ phosphor: on the influence of thermal  process on operational durability. Appl. Phys. B 98, 429–434 (2010). https://doi.org/10.1007/s00340-009-3779-2

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00340-009-3779-2

PACS

Search

Navigation