Boron isotope enrichment in nanosecond pulsed laser-ablation plume

Abstract.

Boron isotopic enrichment is observed in the laser ablation of B₄C target using nanosecond (ns) wide 532 nm laser beam of a Nd-YAG laser. B¹⁰/B¹¹ ratio of 0.9 against the natural abundance of 0.25 is obtained at a laser power density of 8×10⁸ W/cm² (fluence of 6.4 J/cm²). The enrichment as a function of laser power density is demonstrated using a quadrupole mass spectrometer. Apart from higher enrichment factor, only singly charged ions are found in the laser plume from the B₄C target, in contrast to the multiply charged ions from the BN target reported in a recent report using femtosecond (fs) laser pulses. This study indicates the possibility of using less expensive, widely used ns lasers, which can also yield a higher throughput per pulse than a fs laser for isotope enrichment.