Abstract.
The crystallization of 2-propanol was investigated in order to monitor the change of the molecular dynamics with increasing crystallinity by means of real-time dielectric spectroscopy and neutron-diffraction experiments. Both experiments were performed during isothermal crystallization at 135.5 K, above the glass-transition temperature (Tg=115 K). In the dielectric spectrum was observed a moderate shift of the peak of the α-relaxation and a broadening of the spectrum. The crystallization at that temperature is explained with a simple model of the transformed volume fraction based on steady-state homogeneous nucleation of crystallites which grow at a constant rate. Although no direct information about the morphology of the sample is available, the indirect measurements by means of neutron diffraction indicate a three-dimensional crystal growth.
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Received: 17 July 2001 / Accepted: 24 October 2001
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Jiménez-Ruiz, M., Ezquerra, T., Sics, I. et al. Crystallization of 2-propanol studied by neutron diffraction and dielectric spectroscopy in real-time . Appl Phys A 74 (Suppl 1), s543–s545 (2002). https://doi.org/10.1007/s003390101119
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DOI: https://doi.org/10.1007/s003390101119