Skip to main content
Log in

Structural, mechanical and magnetic properties of PVA-PVP: iron oxide nanocomposite

  • Published:
Applied Physics A Aims and scope Submit manuscript

Abstract

Polyvinyl alcohol: Polyvinylpyrrolidone composite (PVA-PVP), reinforced with iron oxide nanoparticles (IONPs) was prepared by casting technique. The structural properties of the pure PVA-PVP composite and the reinforced sample were tested using X-ray diffraction, which showed significant change for the reinforced sample by showing many peaks consistent with the Magnetite phase. The FE-SEM for the reinforced sample showed that NPs are embedded within the polymer, and the composite appeared of higher compact than the pure ones. The stress–strain test shows increased composite stiffness and reduced elongation after reinforcing the sample with the IONPs. The DSC analysis displays a significant effect of the IONPs on the thermal stability of the copolymer by increasing its melting point. The magnetic characteristics of PVA-PVP: IONPs indicate a typical S-shape hysteresis loop of saturation value 0.5 emu/g. The composite showed diluted magnetization properties. The resultant samples can be used in applications of external magnetic field.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. X. Hong, L. Zou, J. Zhao, C. Li, L. Cong, I.O.P. Conf, Ser. Mater. Sci. Eng. 439, 042011 (2018)

    Google Scholar 

  2. S.B. Aziz, R.T. Abdulwahid, M.A. Rasheed, O.G.H. Abdullah, H.M. Ahmed, Polymers (Basel) 9, 486 (2017)

    Article  Google Scholar 

  3. A. Nikmah, A. Taufiq, A. Hidayat, Int. Conf. Life Sci. Technol. 276, 012046 (2019)

    Google Scholar 

  4. W.F. Elmobarak, F. Almomani, Chemosphere 265, 129054 (2021)

    Article  ADS  Google Scholar 

  5. J. Qu, Y. Dong, Y. Wang, H. Xing, Sens. Bio-Sensing Res. 3, 74–78 (2015)

    Article  Google Scholar 

  6. B. Ekwealor, F.I. Ezema, J. Ovonic Res. 9, 35–43 (2013)

    Google Scholar 

  7. N. Yulfriska, D. Rianto, F. Murti, Y. Darvina, and R. Ramli, (2018) Optical Properties of Fe3O4 Thin Films Prepared from the Iron Sand by Spin Coating Method, in: IOP Conf. Ser. Mater. Sci. Eng. pp. 1–7.

  8. K. Omri, N. Alonizan, J. Mater. Sci. Mater. Electron. 33, 15448–15459 (2022)

    Article  Google Scholar 

  9. P. Liu, Z. Yao, V.M.H. Ng, J. Zhou, L.B. Kong, K. Yue, Compos. Part A Appl. Sci. Manuf. 115, 371–382 (2018)

    Article  Google Scholar 

  10. J. Zhao, S. Zhang, W. Liu, Z. Du, H. Fang, Electrochim. Acta 121, 428–433 (2014)

    Article  ADS  Google Scholar 

  11. Y. Chen, P. Pötschke, J. Pionteck, B. Voit, H. Qi, Am. Chem. Soc. 12, 22088–22098 (2020)

    Google Scholar 

  12. X.G. Li, S. Takahashi, K. Watanabe, Y. Kikuchi, M. Koishi, Powder Technol. 133, 156–163 (2003)

    Article  Google Scholar 

  13. B. Ozkahraman, E.T. Irmak, Anadolu Univ. J. Sci. Technol. A- Appl. Sci. Eng. 18, 543–553 (2017)

    Google Scholar 

  14. D.R. Askeland, P.P. Fulay, Essential of materials science and Engineering, Second Edi, Cengage Learning Inc, USA. (2010)

  15. P. Liu, Z. Yao, J. Zhou, Z. Yang, L.B. Kong, J. Mater. Chem. C 4, 9738–9749 (2016)

    Article  Google Scholar 

  16. A.A. Roselin, N. Anandhan, G. Gopu, I.J.P. Doss, K.P. Ganesan, R.P. Selvam, T. Marimuthu, G. Sivakumar, Appl. Phys. A 125, 669 (2019)

    Article  ADS  Google Scholar 

  17. K. Omri, F. Alharbi, J. Mater. Sci. Mater. Electron. 32, 24229–24239 (2021)

    Article  Google Scholar 

  18. Z. Guo, K. Shin, A.B. Karki, D.P. Young, R.B. Kaner, H.T. Hahn, J Nanopart Res 11, 1441–1452 (2009)

    Article  Google Scholar 

  19. V.D. Phadtare, V.G. Parale, K.-Y. Lee, T. Kim, ijaya R. Puri, and H.-H. Park, J. Alloys. Compd (2019). https://doi.org/10.1016/j.jallcom.2019.07.048

    Article  Google Scholar 

  20. Z.K. Heiba, A.M. El-naggar, M.B. Mohamed, A.M. Kamal, M.M. Osman, A.A. Albassam, G. Lakshminarayana, Opt. Mater. (Amst) 122, 111788 (2021)

    Article  Google Scholar 

  21. M.J. Tommalieh, N.S. Awwad, H.A. Ibrahium, A.A. Menazea, Radiat. Phys. Chem. 179, 109195 (2021)

    Article  Google Scholar 

  22. H.V. Kavya, K.S. Nithin, B.K. Kendagannaswamy, S. Sachhidananda, N.A. Chamaraja, Optik (Stuttg) 227, 166008 (2021)

    Article  ADS  Google Scholar 

  23. Y.N. Chen, C. Jiao, Y. Zhao, J. Zhang, H. Wang, ACS Omega 3, 11788–11795 (2018)

    Article  Google Scholar 

  24. X. Gong, C.Y. Tang, L. Pan, Z. Hao, C.P. Tsui, Compos. Part B Eng. 60, 144–149 (2014)

    Article  Google Scholar 

  25. W. El Hotaby, H.H.A. Sherif, B.A. Hemdan, W.A. Khalil, S.K.H. Khalil, Acta Phys. Pol. A 131, 1554–1560 (2017)

    Article  ADS  Google Scholar 

  26. J. Lv, W. Gu, X. Cui, S. Dai, B. Zhang, G. Ji, Sci. Rep. 9, 4271 (2019)

    Article  ADS  Google Scholar 

  27. M.N. Alfindee, Z.J. Sweah, T.A. Saki, Egypt. J. Chem. 64, 2679–2684 (2021)

    Google Scholar 

  28. Y. Zhao, J.A. Baeza, N. Koteswara Rao, L. Calvo, M.A. Gilarranz, Y.D. Li, L. Lefferts, J. Catal. 318, 162–169 (2014)

    Article  Google Scholar 

  29. K. Jeyabanu, K. Sundaramahalingam, P. Devendran, A. Manikandan, N. Nallamuthu, Phys. B Condens. Matter 572, 129–138 (2019)

    Article  ADS  Google Scholar 

  30. V. Siva, D. Vanitha, A. Murugan, A. Shameem, S.A. Bahadur, Compos. Commun. 23, 100597 (2021)

    Article  Google Scholar 

  31. P. Dhatarwal, R.J. Sengwa, Phys. B Condens. Matter 613, 412989 (2021)

    Article  Google Scholar 

  32. L.R.G. Treloa, Trans. Faraday Soc. 40, 59–70 (1944)

    Article  Google Scholar 

  33. H.M. Zidan, E.M. Abdelrazek, A.M. Abdelghany, A.E. Tarabiah, J. Mater. Res. Technol. 8, 904–913 (2019)

    Article  Google Scholar 

  34. H. GhaedRahmati, M. Frounchi, S. Dadbin, Mater. Sci. Eng. B 276, 115535 (2022)

    Article  Google Scholar 

  35. T.H.H. Elagib, E.A.M. Hassan, B. Liu, K. Han, M. Yu, Carbon Lett. 30, 235–245 (2020)

    Article  Google Scholar 

  36. Asmaa S. Khalil, M.K. Jawad, M.A. Alsammarraie, H.I. Jaafar, Asian J. Chem. 29, 675–678 (2017)

    Article  Google Scholar 

  37. P. Singh, D.C. Bharati, P.N. Gupta, A.L. Saroj, J. Non. Cryst. Solids 494, 21–30 (2018)

    Article  ADS  Google Scholar 

  38. B.M. Baraker, B. Lobo, Mater. Today Proc. 5, 3036–3043 (2018)

    Article  Google Scholar 

  39. J. Lee, Q. Lu, J. Lee, H. Choi, Polymers 11, 219 (2019)

    Article  Google Scholar 

  40. D. Ficai, M. Gheorghe, G. Dolete, B. Mihailescu, P. Svasta, A. Ficai, G. Constantinescu, E. Andronescu, Micromachines 13, 351–358 (2022)

    Article  Google Scholar 

Download references

Acknowledgements

The authors would thank the university of Baghdad and Alnukhba University College for their support.

Funding

No financial or non-financial interests directly or indirectly relate to the work submitted for publication.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Nadir F. Habubi.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mahmood, H.S., Habubi, N.F. Structural, mechanical and magnetic properties of PVA-PVP: iron oxide nanocomposite. Appl. Phys. A 128, 956 (2022). https://doi.org/10.1007/s00339-022-06107-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s00339-022-06107-6

Keywords

Navigation