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Comparison between centrosymmetric and non-centrosymmetric chromium substituted M-type barium hexaferrites

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Abstract

In this research project a series of chromium substituted barium hexa-ferrites with formula BaCrxFe(12-x)O19 (x = 0.1, 0.2, 0.3, 0.4, 0.5, 0.6) have been synthesized using powder metallurgy route, sintered at 1100 °C for 2 h. The structural, functional analysis, surface morphology, magnetic and ferroelectric properties have been investigated using X-ray diffractometer, Fourier infrared spectroscopy, scanning electron microscopy, vibrating sample magnetometer, and ferroelectric technique, respectively. The structural analysis reveals the formation of barium hexaferrite structure with minor secondary phase of Hematite α- Fe2O3 in first five samples. Surface morphology shows that all grains have definite grains shape and grain boundaries. VSM analysis revealed the antiferromagnetic loops due to existence of hematite phase in (x = 0 to x = 0.5) samples, whereas the sample (x = 0.6) shows the ferro-magnetic behavior. Ferroelectric measurement shows centrosymmetric and non-centrosymmetric orientation and maximum remnant polarization due to presence of more Fe2+ ions in (x = 0.1–0.5) so that not proper closing of first five samples enhanced the magnetoelectric (ME) coupling.

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Authors and Affiliations

  1. Department of Physics, Lahore College for Women University, Lahore, 54000, Pakistan

    Safia Anjum & Anam Mansoor

  2. Department of Physics, Lahore Garrison University, Lahore, Pakistan

    Zeeshan Mustafa

  3. Department of Physics, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Beijing, China

    Zeeshan Mustafa

  4. Centre of Excellence in Solid State Physics, University of the Punjab, Lahore, Punjab, Pakistan

    Shahid Atiq

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Anjum, S., Mansoor, A., Mustafa, Z. et al. Comparison between centrosymmetric and non-centrosymmetric chromium substituted M-type barium hexaferrites. Appl. Phys. A 126, 731 (2020). https://doi.org/10.1007/s00339-020-03900-z

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