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Synthesis of CeO2 nanoparticles by precipitation in reversal microemulsions and their physical–chemical and biological properties

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Abstract

Cerium dioxide nanoparticles (CeO2) were synthesized by precipitation in the reversal microemulsions based on different surfactants. Crystallographic properties and morphology of CeO2 nanoparticles were studied by X-ray diffraction method and transmission electron microscopy. It was established that CeO2 nanoparticles synthesized in the reversal microemulsions had sizes in the range of 6–10 nm. Zeta-potential values of nanoparticles were measured by dynamic light scattering method and stability of CeO2 in the aqueous suspension was estimated. It was shown that CeO2 nanoparticles formed high-stable aqueous suspensions. It was studied that CeO2 nanoparticles displayed catalase-like activity and they could be promising for development of the antioxidant nanomaterials for treatment of the sequences of oxidative stress.

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Acknowledgements

This work was supported by the NAS of Ukraine in the framework of Target Program of Scientific Researches of the National Academy of Sciences of Ukraine “Materials for medicine and medical technology and technologies for their obtaining and application” No 0017U001915 (2017–2021), Grants of the National Academy of Sciences of Ukraine to research laboratories/groups of young scientists of the National Academy of Sciences of Ukraine No 0118U002326 and common Ukrainian-Slovak JOINT RESEARCH project. The appreciation for the possibility of electron microscopic studies is expressed to Kharchuk Maxim and Center for Shared Use of Danylo Zabolotny Institute of Microbiology and Virology of NAS of Ukraine.

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Authors and Affiliations

  1. V.I. Vernadskii Institute of General and Inorganic Chemistry of the NAS of Ukraine, 32/34 Palladina Ave., Kiev, 03142, Ukraine

    Yulia Shlapa, Illia Timashkov & Anatolii Belous

  2. RE Kavetskii Institute of Experimental Pathology, Oncology and Radiobiology of the NAS of Ukraine, 45, Vasylkivska Str., Kiev, 03022, Ukraine

    Veronika Sarnatskaya, Larysa Yushko, Bogdan Gerashchenko, Iryna Nychyporenko & Vladimir Nikolaev

  3. Institute of Experimental Physics of SAS, Watsonova 47, 040 01, Kosice, Slovakia

    Iryna Antal & Milan Timko

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  1. Yulia Shlapa
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Correspondence to Yulia Shlapa.

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Shlapa, Y., Sarnatskaya, V., Timashkov, I. et al. Synthesis of CeO2 nanoparticles by precipitation in reversal microemulsions and their physical–chemical and biological properties. Appl. Phys. A 125, 412 (2019). https://doi.org/10.1007/s00339-019-2706-6

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