Abstract
A thermal model to describe high-power nanosecond pulsed laser ablation of yttria (Y2O3) has been developed. This model simulates ablation of material occurring primarily through vaporization and also accounts for attenuation of the incident laser beam in the evolving vapor plume. Theoretical estimates of process features such as time evolution of target temperature distribution, melt depth and ablation rate and their dependence on laser parameters particularly for laser fluences in the range of 6 to 30 J/cm2 are investigated. Calculated maximum surface temperatures when compared with the estimated critical temperature for yttria indicate absence of explosive boiling at typical laser fluxes of 10 to 30 J/cm2. Material ejection in large fragments associated with explosive boiling of the target needs to be avoided when depositing thin films via the pulsed laser deposition (PLD) technique as it leads to coatings with high residual porosity and poor compaction restricting the protective quality of such corrosion-resistant yttria coatings. Our model calculations facilitate proper selection of laser parameters to be employed for deposition of PLD yttria corrosion-resistive coatings. Such coatings have been found to be highly effective in handling and containment of liquid uranium.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs00339-013-7706-3/MediaObjects/339_2013_7706_Fig1_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs00339-013-7706-3/MediaObjects/339_2013_7706_Fig2_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs00339-013-7706-3/MediaObjects/339_2013_7706_Fig3_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs00339-013-7706-3/MediaObjects/339_2013_7706_Fig4_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs00339-013-7706-3/MediaObjects/339_2013_7706_Fig5_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs00339-013-7706-3/MediaObjects/339_2013_7706_Fig6_HTML.gif)
Similar content being viewed by others
References
D.B. Chrisey, G.K. Hubler (eds.), Pulsed Laser Deposition of Thin Films (Wiley Interscience, New York, 1994)
M. Ali, T. Wagner, N. Shakoor, P.A. Molian, J. Laser Appl., 169–183 (2008)
S. Besner, A.V. Kabashin, M. Meunier, Appl. Phys. A 88, 269–272 (2007)
V. Zorba, N. Boukos, I. Zergioti, C. Fotakis, Appl. Opt. 47, 1846–1850 (2008)
A. Bogaerts, Z. Chen, R. Gijbels, A. Vertes, Spectrochim. Acta, Part B 58, 1867–1893 (2003)
D. Bauerle, Laser Processing and Chemistry, 3rd edn. (Springer, Berlin, 2000)
R.J. Gaboriaud, F. Pailloux, J. Perriere, Appl. Surf. Sci. 186, 477–482 (2002)
C. Martinet, A. Pillonnet, J. Lancok, C. Garapon, J. Lumin. 126, 807–816 (2007)
S.H. Lee, C.H. Cho, Y.S. Lee, H.S. Lee, J.G. Kim, Korean J. Chem. Eng. 27(6), 1786–1790 (2010)
C. Tourneir, B. Lorrain, F.L. Guyadec, L. Coudurier, N. Eustathopoulos, J. Nucl. Mater. 254, 215–220 (1998)
J.W. Koger, C.E. Holcombe, J.G. Banker, Thin Solid Films 39, 297–303 (1976)
R.C. Ewing, Proc. Natl. Acad. Sci. 96, 3432–3439 (1999)
T. Yoneoka, T. Terai, Y. Takahashi, J. Nucl. Mater. 248, 343–347 (1997)
T. Terai, J. Nucl. Mater. 248, 153–158 (1997)
Y. Song, I. Lee, D.Y. Lee, D. Kim, S. Kim, K. Lee, Mater. Sci. Eng. A 332, 129–133 (2002)
X.Q. Cao, R. Vassen, D. Stoever, J. Eur. Ceram. Soc. 24, 1–10 (2004)
G. Antou, F. Hlawaka, A. Cornet, C. Becker, D. Ruch, A. Riche, Surf. Coat. Technol. 200, 6062–6072 (2006)
A. Shinozawa, K. Eguchi, M. Kambara, T. Yoshida, J. Therm. Spray Technol. 19(1–2), 190–197 (2010)
A. Ichinose, A. Kikuchi, K. Tachikawa, S. Akita, Physica C 302, 51–56 (1998)
J. Hudner, H. Ohlsen, E. Fredriksson, Vacuum 46, 967–970 (1995)
A. Sawada, A. Suzuki, H. Maier, F. Koch, T. Terai, T. Muroga, Fusion Eng. Des. 75–79, 737–740 (2005)
E.W. Kreutz, Appl. Surf. Sci. 127–129, 606–613 (1998)
A.K. Singh, T.R.G. Kutty, S. Sinha, J. Nucl. Mater. 420, 374–381 (2012)
S. Sinha, J. Nucl. Mater. 396, 257–263 (2010)
S. Sinha, T.R.G. Kutty, P.V.A. Padmanabhan, K.G.K. Warrier, J. Laser Appl. 21, 149–153 (2009)
A. Miotello, R. Kelly, Appl. Phys. A 69, S67 (1999)
R. Kelly, A. Miotello, Nucl. Instrum. Methods Phys. Res. B 122, 374–400 (1997)
M. Von Allmen, Laser Beam Interactions with Materials (Springer, Heidelberg, 1987)
A.A. Morozov, Appl. Phys. A 79, 997–999 (2004)
S. Zhang, R. Xiao, J. Appl. Phys. 83, 3842–3848 (1998)
N.M. Bulgakova, A.V. Bulgakov, Appl. Phys. A 73, 199–208 (2001)
R. Kelly, J. Chem. Phys. 92, 5047–5056 (1990)
Z.D. Reed, M.A. Duncan, J. Phys. Chem. A 112, 5354–5362 (2008)
K. Serivalsatit, B. Kokuoz, B.Y. Kokuoz, M. Kennedy, J. Ballato, J. Am. Ceram. Soc. 93(5), 1320–1325 (2010)
I. Barin, O. Knacke, Thermochemical Properties of Inorganic Substances (Springer, Berlin, 1977)
D.L. Perry, S.L. Phillips, in Handbook of Inorganic Compounds (CRC Press, New York, 1995), p. 448
Y.A. Landa, Y.A. Polonskii, B.S. Glazachev, T.V. Milovidova, Ogneupory 2, 16–18 (1974) (All-Union Inst. Refract., Transl.)
FACT—FactSage 5.00 compound database (March 2001)
A.V. Bulgakov, N.M. Bulgakova, Quantum Electron. 29(5), 433–437 (1999)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Sinha, S. Nanosecond laser ablation for pulsed laser deposition of yttria. Appl. Phys. A 112, 855–862 (2013). https://doi.org/10.1007/s00339-013-7706-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00339-013-7706-3