Abstract
Sol–gel techniques were used to prepare thin films of Pb(Zr x ,Ti1−x )O3 (PZT) with three different Zr/Ti ratios and a graded PZT film with three different compositional layers. A Michelson interferometer was used to measure the thickness strains due to an applied ac electric field. Effective d 33 piezoelectric strain coefficients were computed from the experimental data. Interfacial pinning caused these coefficients to differ from the true ones. They were corrected for the pinning using both an analytical model and finite-element analysis. The corrected coefficients of the PZT (52/48) sample were in excellent agreement with values of bulk materials. The coefficients of the multilayer sample were very low, probably due to insufficient poling or domain switching.
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References
C. Paz de Araujo, J.F. Scott, G.W. Taylor, Ferroelectric Thin Films: Synthesis and Basic Properties (Taylor & Francis, Philadelphia, 1996)
O. Auciello, J.F. Scott, R. Ramesh, Phys. Today 51, 22 (1998)
R.W. Whatmore, Q. Zhang, Z. Huang, R.A. Dorey, Mater. Sci. Semicond. Process. 5(2–3), 65 (2002)
Z. Chen, K. Arita, M. Lim, C.A.P. de Araujo, Integr. Ferroelectr. 24, 181 (1999)
W. Wu, Y. Wang, G.K.H. Pang, K.H. Wong, C.L. Choy, Appl. Phys. Lett. 85, 1583 (2004)
V. Nagarajan, C.L. Jia, H. Kohlstedt, R. Waser, I.B. Misirlioglu, S.P. Alpaya, R. Ramesh, Appl. Phys. Lett. 86, 192910 (2005)
P. Khaenamkaew, S. Muensit, I.K. Bdikin, A.L. Kholkin, Mater. Chem. Phys. 102, 159 (2007)
P. Khaenamkaew, I.D. Bdikin, A.L. Kholkin, S. Muensit, Ceram. Int. 34, 1027 (2008)
J.F. Nye, Physical Properties of Crystals (Clarendon Press, Oxford, 1957)
S. Muensit, I.L. Guy, Appl. Phys. Lett. 72, 1896 (1998)
A.L. Kholkin, D.V. Taylor, N. Setter, Presented at the 11th IEEE Int. Symp. Applications of Ferroelectrics, Montreux, Switzerland, 1998
S. Muensit, I.L. Guy, Ferroelectrics 271, 1987 (2002)
A.J. Bell, J. Mater. Sci. 41, 13 (2006)
Z.-G. Ban, S.P. Alpay, J.V. Mantese, Phys. Rev. B 67, 18410 (2003)
S. Zhong, S.P. Alpay, A.L. Roytburd, J.V. Mantese, IEEE Trans. Ultrason. Ferroelectr. Freq. Control 53, 2349 (2006)
S. Zhong, Z.-G. Ban, S.P. Alpay, J.V. Mantese, Appl. Phys. Lett. 89, 142913 (2006)
G. Akcay, S. Zhong, B.S. Allimi, S.P. Alpay, J.V. Mantese, Appl. Phys. Lett. 91, 012904 (2007)
R.E. Newnham, Properties of Materials: Anisotropy, Symmetry, Structure (Oxford University Press, Oxford, 2004)
D. Royer, V. Kmetik, Electron. Lett. 28, 1828 (1992)
K. Lefki, G.J.M. Dormans, J. Appl. Phys. 76, 1764 (1994)
B. Jaffe, W.R. Cook Jr., H. Jaffe, Piezoelectric Ceramics (Academic, London, 1971)
FlexPDE (PDE Solutions, Inc., Antioch, CA, 1999)
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Muensit, S., Sukwisut, P., Khaenamkeaw, P. et al. Piezoelectric coefficients of multilayer Pb(Zr,Ti)O3 thin films. Appl. Phys. A 92, 659–663 (2008). https://doi.org/10.1007/s00339-008-4602-3
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DOI: https://doi.org/10.1007/s00339-008-4602-3