Abstract
(1 − x)Na0.5Bi0.5TiO3–xBaTiO3 (BNT–xBT) thin films with x = 0, 0.04, 0.06, 0.08 were prepared on Pt(111)/Ti/SiO2/Si substrates via water-based sol–gel method. A new crystallization process called stepwise crystallization was used to obtain pure perovskite phase observed by XRD. Piezoelectric property and ferroelectric property of BNT–xBT thin films are investigated, and BNT–BT0.06 shows best piezoelectric and ferroelectric properties among the different compositions. The maximum strain value of 1.4–1.8 % and d 33 of 83 pm/V are observed for BNT–BT0.06 thin films. AFM and PFM images reveal the dense morphology and large piezoresponse of BNT–BT thin films without orientation.
Similar content being viewed by others
References
M. Abazari, A. Safari, S.S.N. Bharadwaja, S. Trolier-McKinstry, Dielectric and piezoelectric properties of lead-free (Bi, Na)TiO3-based thin films. Appl. Phys. Lett. 96(8), 082903 (2010)
R. Ding, D. Wang, D. Chu, S. Li, D. Damjanovic, Crystallographic orientation dependence on electrical properties of (Bi, Na)TiO3-based thin films. J. Am. Ceram. Soc. 96(11), 3530–3535 (2013)
Y. Saito, H. Takao, T. Tani, T. Nonoyama, K. Takatori, T. Homma, T. Nagaya, M. Nakamura, Lead-free piezoceramics. Nature 432, 84–87 (2004)
X.-C. Zheng, G.-P. Zheng, Z. Lin, Z.-Y. Jiang, Thermo-electrical energy conversions in Bi0.5Na0.5TiO3–BaTiO3 thin films prepared by sol–gel method. Thin Solid Films 522, 125–128 (2012)
K.A. Razak, C.J. Yip, S. Sreekantan, Synthesis of (Bi0.5Na0.5)TiO3 (BNT) and Pr doped BNT using the soft combustion technique and its properties. J. Alloys Compd. 509(6), 2936–2941 (2011)
D. Alonso-Sanjosé, R. Jiménez, I. Bretos, M.L. Calzada, Lead-free ferroelectric (Na1/2Bi1/2)TiO3–BaTiO3 thin films in the morphotropic phase boundary composition: solution processing and properties. J. Am. Ceram. Soc. 92(10), 2218–2225 (2009)
M. Cernea, G. Poli, G.V. Aldica, C. Berbecaru, B.S. Vasile, C. Galassi, Preparation and properties of nanocrystalline BNT–BTx piezoelectric ceramics by sol–gel and spark plasma sintering. Curr. Appl. Phys. 12(4), 1100–1105 (2012)
X. Chen, W. Pan, H. Tian, X. Gong, X. Bian, P. Liu, Microstructure, dielectric and ferroelectric properties of 0.94Bi0.5Na0.5TiO3–0.06BaTiO3 (NBTB) and 0.05BiFeO3–0.95NBTB ceramics: effect of sintering atmosphere. J. Alloys Compd. 509(5), 1824–1829 (2011)
S.K. Acharya, T.-M. Kim, J.-H. Hyung, B.-G. Ahn, S.-K. Lee, Ferroelectric and piezoelectric properties of lead-free Bi0.5Na0.5TiO3–Bi0.5K0.5TiO3–BaTiO3-thin films near the morphotropic phase boundary. J. Alloys Compd. 586, 549–554 (2014)
A. Chaouchi, S. Kennour, S. d’Astorg, M. Rguiti, C. Courtois, S. Marinel, M. Aliouat, Characterization of sol–gel synthesised lead-free (1 − x)Na0.5Bi0.5TiO3–xBaTiO3-based ceramics. J. Alloys Compd. 509(37), 9138–9143 (2011)
Q. Xu, D.-P. Huang, M. Chen, W. Chen, H.-X. Liu, B.-H. Kim, Effect of bismuth excess on ferroelectric and piezoelectric properties of a (Na0.5Bi0.5)TiO3–BaTiO3 composition near the morphotropic phase boundary. J. Alloys Compd. 471(1-2), 310–316 (2009)
S.W. Li, P. Li, H. Zeng, J. Hao, Z. Yue, J. Zhai, Structural modification and piezoelectric properties in Bi0.5Na0.5TiO3–BaTiO3–SrTiO3 thin films. J. Mater. Sci. Mater. Electron. 27, 215–220 (2016)
W. Cui, X. Wang, L. Li, Large piezoresponse of Na0.5Bi0.5TiO3–K0.5Bi0.5TiO3 thin films prepared via water-based sol–gel method. Ceram. Int. 41, S37–S40 (2015)
X. Fang, B. Shen, J. Zhai, X. Yao, Preparation, dielectric and ferroelectric properties of (Na0.5Bi0.5)0.94Ba0.06TiO3 thin films by a sol–gel process. J. Sol-Gel. Sci. Technol. 58(1), 1–5 (2010)
C.H. Yang, W.B. Wu, F. Yang, H.T. Wu, X.Y. Zhang, Dielectric and ferroelectric properties of A-site non-stoichiometric Na0.5Bi0.5TiO3-based thin films. Mater. Lett. 66(1), 86–88 (2012)
D.H. Kang, B.S. Lee, H.K. An, Y.H. Kim, D.S. Paik, H.I. Hwang, N.K. Cho, Characteristics of yttrium substituted sodium bismuth titanate thin films. Mater. Lett. 64(21), 2331–2333 (2010)
W. Cui, X. Wang, L. Li, Effects of seed layer and crystallization process on crystal orientation and properties of NKBT thin films. J. Sol-Gel. Sci. Technol. 75(3), 703–709 (2015)
Z.H. Zhou, J.M. Xue, W.Z. Li, J. Wang, H. Zhu, J.M. Miao, Ferroelectric and electrical behavior of (Na0.5Bi0.5)TiO3 thin films. Appl. Phys. Lett. 85(5), 804 (2004)
J.A.E. Shaoping Li, R.E. Newnham, L.E. Cross, Diffuse phase transition in ferroelectrics with mesoscopic heterogeneity: mean-field theory. Phys. Rev. B 55, 12067 (1997)
Y. Wu, X. Wang, C. Zhong, L. Li, Effect of anneal conditions on electrical properties of Mn-doped (Na0.85K0.15)0.5Bi0.5TiO3 thin films prepared by sol–gel method. J. Am. Ceram. Soc. 94(6), 1843–1849 (2011)
H. Dong, X.J. Zheng, W. Li, Y.Q. Gong, J.F. Peng, Z. Zhu, The dielectric relaxation behavior of (Na0.82K0.18)0.5Bi0.5TiO3 ferroelectric thin film. J. Appl. Phys. 110(12), 124109 (2011)
A.L. Kholkin, E.K. Akdogan, A. Safari, P.F. Chauvy, N. Setter, Characterization of the effective electrostriction coefficients in ferroelectric thin films. J. Appl. Phys. 89(12), 8066 (2001)
P. Muralt, PZT thin films for microsensors and actuators: Where do we stand? IEEE Trans. Ultrason. Ferroelectr. Freq. Control 47(4), 903 (2000)
Q.G. Chi, W.L. Li, Y. Zhao, W.D. Fei, Low temperature preparation and electric properties of highly (100)-oriented Pb0.8 La0.1Ca0.1Ti0.975O3 thin films prepared by a sol–gel route. J. Sol-Gel. Sci. Technol. 54(3), 286–291 (2010)
Acknowledgments
The work was supported by Ministry of Sciences and Technology of China through National Basic Research Program of China (973 Program 2015CB654604), National Natural Science Foundation of China for Creative Research Groups (Grant No. 51221291), National Natural Science Foundation of China (Grant No. 51272123), and also supported by CBMI Construction Co., Ltd.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Cui, W., Wang, X. & Li, L. Large piezoelectric properties of (1 − x)Na0.5Bi0.5TiO3–xBaTiO3 thin films prepared by sol–gel method. J Mater Sci: Mater Electron 27, 7287–7291 (2016). https://doi.org/10.1007/s10854-016-4696-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-016-4696-x