Skip to main content
Log in

Tunable aggregation of Au nanoparticles in Au/SiO2 composite film and its photo-absorbance

  • Published:
Applied Physics A Aims and scope Submit manuscript

Abstract

An Au/SiO2 nanocomposite film was prepared as an Au nanoparticulate monolayer by co-sputtering to achieve tunable aggregation of Au nanoparticles on the substrate. The Au nanoparticles in the Au/SiO2 nanocomposite film were aggregated through water treatment because of disintegration of the SiO2 phase by water and the attractive force between Au nanoparticles with a free surface. For a partially 4-fluorobenzylmercaptane-immobilized Au/SiO2 nanocomposite film, the Au nanoparticles were aggregated homogeneously with their limited neighbors differently from the fully exposed Au nanoparticles without the molecular immobilization. The surface plasmon band was red shifted to 560 nm with increased intensity by the controlled aggregation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. M.-C. Daniel, D. Astruc, Chem. Rev. 104, 293 (2004)

    Article  Google Scholar 

  2. T.J. Norman Jr., C.D. Grant, D. Magana, J.Z. Zhang, J. Liu, D. Cao, F. Bridges, A. Van Buuren, J. Phys. Chem. B 106, 7005 (2002)

    Article  Google Scholar 

  3. M.-Q. Zhu, L.-Q. Wang, G.J. Exarhos, A.D.Q. Li, J. Am. Chem. Soc. 126, 2656 (2004)

    Article  Google Scholar 

  4. Z. Zhong, S. Patskovsky, P. Bouvrette, J.H.T. Luong, A. Gedanken, J. Phys. Chem. B 108, 4046 (2004)

    Article  Google Scholar 

  5. X.-H.N. Xu, S. Huang, W. Brownlow, K. Salaita, R.B. Jeffers, J. Phys. Chem. B 108, 15543 (2004)

    Article  Google Scholar 

  6. Y. Liu, H. Wang, Y. Chen, C.-F. Ke, M. Liu, J. Am. Chem. Soc. 127, 657 (2005)

    Article  Google Scholar 

  7. O. Uzun, B.L. Frankamp, A. Sanyal, V.M. Rotello, Chem. Mater. 18, 5404 (2006)

    Article  Google Scholar 

  8. A. Okugaichi, K. Torigoe, T. Yoshimura, K. Esumi, Colloid Surf. A 273, 154 (2006)

    Article  Google Scholar 

  9. W. Zhao, T.M.H. Lee, S.S.Y. Leung, I.-M. Hsing, Langmuir 23, 7143 (2007)

    Article  Google Scholar 

  10. J. Chen, J. Jiang, X. Gao, J. Gong, G. Shen, R. Yu, Colloid Surf. A 294, 80 (2007)

    Article  Google Scholar 

  11. Y. Yang, S. Matsubara, M. Nogami, J. Shi, Mater. Sci. Eng. B 140, 172 (2007)

    Article  Google Scholar 

  12. A. Fahmi, A. D’Aleo, R.M. Williams, L. De Cola, N. Gindy, F. Voegtle, Langmuir 23, 7831 (2007)

    Article  Google Scholar 

  13. J.J. Storhoff, R. Elghanian, R.C. Mucie, C.A. Mirkin, R.L. Letsinger, J. Am. Chem. Soc. 120, 1959 (1998)

    Article  Google Scholar 

  14. C.A. Mirkin, Inorg. Chem. 39, 2258 (2000)

    Article  Google Scholar 

  15. J. Liu, Y. Lu, J. Am. Chem. Soc. 127, 12677 (2005)

    Article  Google Scholar 

  16. I. Tokareva, E. Hutter, J. Am. Chem. Soc. 126, 15784 (2004)

    Article  Google Scholar 

  17. L. Jiang, H. Zhang, J. Zhuang, B. Yang, W. Yang, T. Li, C. Sun, Adv. Mater. 17, 2066 (2005)

    Article  Google Scholar 

  18. A.K. Boal, F. Ilhan, J.E. DeRouchey, T. Thurn-Albrecht, T.P. Russell, V.M. Rotello, Nature 404, 746 (2000)

    Article  ADS  Google Scholar 

  19. A.A. Lazarides, G.C. Schatz, J. Phys. Chem. 104, 460 (2000)

    Google Scholar 

  20. J.J. Storhoff, A.A. Lazarides, R.C. Muchi, C.A. Mirkin, R.L. Letsinger, G.C. Schatz, J. Am. Chem. Soc. 122, 4640 (2000)

    Article  Google Scholar 

  21. R. Jin, G. Wu, Z. Li, C.A. Mirkin, G.C. Schatz, J. Am. Chem. Soc. 125, 1643 (2003)

    Article  Google Scholar 

  22. M.K. Beissenhirtz, R. Elnathan, Y. Weizmann, I. Willner, Small 3, 375 (2007)

    Article  Google Scholar 

  23. V. Sauthanam, J.L.R. Argarwal, R.P. Andres, Langmuir 19, 7881 (2003)

    Article  Google Scholar 

  24. S. Lal, S.L. Westcott, R.N. Taylor, J.B. Jackson, P. Nordlander, J. Phys. Chem. B 106, 5609 (2002)

    Article  Google Scholar 

  25. K.-S. Lee, T.-S. Lee, W.-M. Kim, S. Cho, S. Lee, Appl. Phys. Lett. 91, 141905 (2007)

    Article  ADS  Google Scholar 

  26. H. Wang, C.S. Levin, N.J. Halas, J. Am. Chem. Soc. 127, 14992 (2005)

    Article  Google Scholar 

  27. C.-F. Chen, S.-D. Tzeng, H.-Y. Chen, K.-J. Lin, S. Gwo, J. Am. Chem. Soc. 130, 824 (2008)

    Article  Google Scholar 

  28. D.-G. Kim, Y. Shimizu, T. Sasaki, N. Koshizaki, B.H. Lee, D.-S. Kim, Y.J. Lee, Y.D. Kim, Nanotechnology 18, 145703 (2007)

    Article  ADS  Google Scholar 

  29. D.-G. Kim, E. Koyama, Y. Kikkawa, K. Kirihara, Y. Naitoh, D.-S. Kim, H. Tokuhisa, M. Kanesato, N. Koshizaki, Nanotechnology 18, 205501 (2007)

    Article  ADS  Google Scholar 

  30. P.A. Domenico, F.W. Schwartz, Physical and Chemical Hydrogeology (Wiley, New York, 1997)

    Google Scholar 

  31. A.N. Shipway, M. Lahav, R. Gabai, I. Willner, Langmuir 16, 8789 (2000)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Dae-Gun Kim.

Additional information

PACS

78.40.-q

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kim, DG., Koyama, E., Tokuhisa, H. et al. Tunable aggregation of Au nanoparticles in Au/SiO2 composite film and its photo-absorbance. Appl. Phys. A 92, 263–266 (2008). https://doi.org/10.1007/s00339-008-4525-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00339-008-4525-z

Keywords

Navigation