Abstract
A sulfonic acid functional hydrogel was prepared starting from the copolymerization of 2-acrylamido-2-methyl-1-propanesulfonic acid as monomer and tetraallyl ammonium bromide as a cross-linking agent in the presence of K2S2O8 as a radical initiator. Aniline was interacted with the hydrogel, and oxidative polymerization reaction of anilinium sulfonate salt containing hydrogel was performed by using ammonium persulfate to obtain conducting gel material. The electrical/dielectric properties of the PANI-coated hydrogel were analyzed using impedance spectroscopy. The frequency dependence of the real (ε′) and imaginary (ε″) parts of the dielectric constant (ε), dissipation factor, the real (σ′) and imaginary (σ″) parts of the ionic conductivity (σ), Cole–Cole plots and impedance parameters values for the PANI-coated hydrogel were analyzed in the frequency range of 100 Hz–15 MHz at room temperature. PANI-coated hydrogel shows the non-Debye relaxation type in the materials. The conductivity mechanisms of PANI-coated hydrogel are super linear power law and extended pair approximation.
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Dispenza C, Lo Presti C, Belfiore C, Spadaro G, Piazza S (2006) Electrically conductive hydrogel composites made of polyaniline nanoparticles and poly (N-vinyl-2-pyrrolidone). Polymer 47:961–971. https://doi.org/10.1016/j.polymer.2005.12.071
Blanchet GB, Fincher CR, Lefenfeld M, Roger JA (2004) Contact resistance in organic thin film transistors. App Phys Lett 84:296–298. https://doi.org/10.1063/1.1639937
Tittu M, Hiekkataipale P, Kainen JH, Makela T, Ikkala O (2002) Viscoelastic and electrical transitions in gelation of electrically conducting polyaniline. Macromolecules 35:5212–5217. https://doi.org/10.1021/ma011943z
Akbayir C, Bulut F, Farrell T, Goldschmidt A, Günther R, Kam AP, Miclea P, Scherf U, Seekamp J, Solovyev VG, Sotomayor Torres CM (2003) Nanostructured conjugated polymeric system for photovoltatic applications. Rev Adv Mater Sci 5:205–210
Tiitu M, Talo A, Forsén O, Ikkala O (2005) Aminic epoxy resin hardeners as reactive solvents for conjugated polymers: polyaniline base/epoxy composites for anticorrosion coatings. Polymer 46:6855–6861. https://doi.org/10.1016/j.polymer.2005.05.119
Li M, Guo Y, Wei Y, MacDiarmid AG, Lelkes PI (2006) Electrospinning polyaniline-contained gelatin nanofibers for tissue engineering applications. Biomaterials 27:2705–2715. https://doi.org/10.1016/j.biomaterials.2005.11.037
Kim DH, Abidian M, Martin DC (2004) Conducting polymers grown in hydrogel scaffolds coated on neural prosthetic devices. Biomed Mat Res Part A 71:577–585. https://doi.org/10.1002/jbm.a.30124
Qiang Y, Antony J, Sharma A, Nutting J, Meyer D (2005) Iron/iron oxide core shell nano clusters for biomedical application. Nanopart Res 8:489–496. https://doi.org/10.1007/s11051-005-9011-3
Steyskal J, Gilberg KG (2002) Polyaniline, preparation of a conducting polymer (IUPAC Technical Report). Pure Appl Chem 74:857–867. https://doi.org/10.1351/pac200274050857
Tang Q, Wu J, Sun H, Lin J, Fan S, Hu D (2008) Polyaniline/polyacrylamide conducting composite hydrogel with a porous structure. Carbonhydrate Polym 74:215–219. https://doi.org/10.1016/j.carbpol.2008.02.008
Syed AA, Dinesan MK (1991) Polyaniline—a novel polymeric material-review. Talanta 38(8):815–837. https://doi.org/10.1016/0039-9140(91)80261-W
Kulkarni SB, Joshi SS, Lokhande CD (2011) Facile and efficient route for preparation of nanostructured polyaniline thin films: Schematic model for simplest oxidative chemical polymerization. Chem Eng J 166:1179–1185. https://doi.org/10.1016/j.cej.2010.12.032
Pascoal AM, Mitidieri S, Fernandes KF (2011) Immobilisation of alpha-amylase from Aspergillus niger onto polyaniline. Food Bioprod Process 89:300–306. https://doi.org/10.1016/j.fbp.2010.07.002
Owino JHO, Arotiba OA, Baker PGL, Guiseppi-Elie A, Iwuoha EI (2008) Synthesis and characterization of poly (2-hydroxyethyl methacrylate)-polyaniline based hydrogel composites. React Funct Polym 68:1239–1244. https://doi.org/10.1016/j.reactfunctpolym.2008.05.005
Kuo CW, Wen TC (2008) Dispersible polyaniline nanoparticles in aqueous poly (styrenesulfonic acid) via the interfacial polymerization route. Eur Polym J 44:3393–3401. https://doi.org/10.1016/j.eurpolymj.2008.07.018
Jin X, Xiao CF, Wang WY (2010) Electrical and mechanical properties of novel polyaniline coated polycaprolactam fibers. Synth Met 160(5-6):368–372. https://doi.org/10.1016/j.synthmet.2009.11.006
Gupta B, Prakash R (2009) Synthesis of processible doped polyaniline-polyacrylic acid composites. J Appl Polym Sci 114(2):874–882. https://doi.org/10.1002/app.30554
Mojtabavi EA, Nasirian S (2019) Flexible self-powered ultraviolet-visible photodetector based on polyaniline-titanium dioxide heterostructures: the study of the rearrangement of layers. App Surf Sci 492:189–198. https://doi.org/10.1016/j.apsusc.2019.06.218
Bayramoglu G, Metin AU, Altintas B, Arica MY (2010) Reversible immobilization of glucose oxidase on polyaniline grafted polyacrylonitrile conductive composite membrane. Bioresour Technol 101(18):6881–6887. https://doi.org/10.1016/j.biortech.2010.04.025
Senkal BF, Erkal D, Yavuz E (2006) Removal of dyes from water by poly (vinyl pyrrolidone) hydrogel. Polym Adv Technol 17:924–927. https://doi.org/10.1002/pat.836
Yan B, Chen Z, Cai L, Chen Z, Fu J, Xu Q (2015) Fabrication of polyaniline hydrogel: synthesis, characterization and adsorption of methylene blue. Appl Surf Sci 356:39–47. https://doi.org/10.1016/j.apsusc.2015.08.024
Xiao Y, Yan XH, Cao JX, Ding JW, Mao YL, Xiang J (2004) Specific heat and quantized thermal conductance of single-walled boron nitride nanotubes. Phys ReV B 69:205415. https://doi.org/10.1103/PhysRevB.69.205415
Meller A (1983) Gmelin handbuch der anorganische chemie boron compounds. Springer, Berlin
Pouch JJ, Alterovitz SA (1990) Synthesis and properties of boron nitride. Brookfield, Trans Techn
Jonscher AK (1978) The universal dielectric response: a review of data their new interpretation. Chelsea Dielectrics Group, London
Özerol EA, Bozdoğan AC, Şenkal BF, Okutan M (2016) The effect on the impedance characteristics of the metal oxides (Al2O3 and ZnO) doping into polyaniline. Mater Sci Semicond Process 56:357–361
Özerol EA (2019) Electro-optical properties of poly (N-vinyl carbazole) nanoclay composites. Polym Bull 76(10):5301–5311
Meller A (1983) Gmelin handbuch der anorganische chemie, boron compounds Springer, Berlin, 2nd Supplement, 1
Öztürk M, Coşkun R, Okutan M, Yalçın O (2018) Origin of the synthetic circuits and the Brownian motion in stretchable crystal violet doped and biocompatible composite hydrogels. J Mol Liq 249:211–218. https://doi.org/10.1016/j.molliq.2017.11.008
Okutan M, Coşkun R, Öztürk M, Yalçın O (2015) Dielectric properties of Rhodamine-B and metal doped hydrogels. Phys B 457:5–11
Jacob R, Nair HG, Isac J (2015) "Impedance spectroscopy and dielectric studies of nanocrystalline iron doped barium strontium titanate ceramics". Process Appl Ceram 9(2):73–79. https://doi.org/10.2298/PAC1502073J
Thakur S, Rai R, Bdikin I, Valente MA (2016) Impedance and modulus spectroscopy characterization of Tb modified Bi0. 8A0. 1Pb0. 1Fe0. 9Ti0. 1O3 ceramics. Materials Research 19(1):1–8. https://doi.org/10.1590/1980-5373-MR-2015-0504
Coşkun R, Okutan M, Öztürk M, Yalçın O (2019) Origin of the synthetic circuits and comparison effects of different dose malachite green oxalate doped hydrogel. Mater Chem Phys 222:361–368. https://doi.org/10.1016/j.matchemphys.2018.10.012
Coşkun R, Okutan M, Öztürk M, Yalçın O (2019) Experimental model to describe the dielectric response of different dye and nanoparticles doped hydrogels for biological cell membranes and biological systems. J Mol Liq 296:112072. https://doi.org/10.1016/j.molliq.2019.112072
Mitsumata T, Gong JP, Ikeda K, Osada Y (1998) Low-frequency dielectric relaxation of polyelectrolyte gels. J Phys Chem B 102:5246–5251
Radoń A, Łukowiec D, Kremzer M, Mikuła J, Włodarczyk P (2018) Electrical conduction mechanism and dielectric properties of spherical shaped Fe3O4 nanoparticles synthesized by co-precipitation method. Materials 11(5):735–757
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Okutan, M., Yavuz, E., Ahlatcıoğlu Özerol, E. et al. Impedance spectroscopy of polyaniline coated hydrogel. Polym. Bull. 78, 4473–4486 (2021). https://doi.org/10.1007/s00289-020-03295-0
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DOI: https://doi.org/10.1007/s00289-020-03295-0