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Fabrication of electrospun nanocomposite polyethersulfone membrane for microfiltration

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Abstract

Nanocomposite membranes comprising two or more layers with different structural properties are used in filtration apparatus. In the present study, polyethersulfone (PES) nanofibrous composite membranes were fabricated by means of electrospinning and the influence of solvent type, temperature and polymer concentration on PES electrospinning process was investigated. To get bead-free nanofibers, electrospinning process parameters were optimized. To fabricate the nanocomposite membranes with varying properties five different flow rates of polymer solutions (0.1, 0.4, 0.7, 1 and 1.3 ml/h) were used. Solvent vapor treatment was carried out to enhance the mechanical properties of the nanocomposite membranes by increasing the fiber adhesion. Morphology of the membranes was studied using scanning electron microscope, and mechanical properties were evaluated by tensile test. Pore size of the membrane was assessed by bubble point method. Retention test was conducted using nanoparticle suspensions containing equally sized particles and the water flux was measured through dead-end filtration system. Finally, fabricated membranes were used for filtering out bacteria and fungus from culture media. Results show that the fiber diameter, fiber adhesion and also membrane thickness have significant impact on potential membrane retention, water flux and bacterial removal.

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References

  1. Homaeigohar SS, Buhr K, Ebert K (2010) Polyethersulfone electrospun nanofibrous composite membrane for liquid filtration. Membr Sci 36:68–77

    Article  Google Scholar 

  2. Huang ZM, Zhang YZ, Kotaki M, Ramakrishna S (2003) A review on polymer nanofibers by electrospinning and their applications in nanocomposites. Compos Sci Tech 63:2223–2253

    Article  CAS  Google Scholar 

  3. Nakata K, Kim SH, Ohkoshi Y, Gotoh Y, Nagura M (2007) Electrospinning of polyethersulfone and evaluation of the filtration efficiency. Sen-I Gakkash 63:307–312

    Article  CAS  Google Scholar 

  4. Yung L, Ma H, Wang X, Yoon K, Wang R, Hsiao B, Chu B (2010) Fabrication of thin-film nanofibrous composite membranes by interfacial polymerization using ionic liquids as additives. Membr Sci 365:52–58

    Article  CAS  Google Scholar 

  5. Tang Z, Qiu C, McCutcheon JR, Yoon K, Ma H, Fang D, Lee E, Kopp C, Hsiao BS, Chu B (2009) Design and fabrication of electrospun polyethersulfone nanofibrous scaffold for high-flux nanofiltration membranes. Polym J Phys 47:2288–2300

    Article  CAS  Google Scholar 

  6. Raghava RK, Gomes VG, Hassan M (2014) Carbon functionalized TiO2 nanofibers for high efficiency photocatalysis. Mater Res Express 1(1):015012

  7. Matsuura T, Khayet M (2011) Membrane distillation principles and applications. Elsevier, Ottawa

  8. Qin XH, Wang S (2006) Filtration properties of electrospinning nanofibers. App Polym Sci 102:1285–1290

    Article  CAS  Google Scholar 

  9. Yoon K, Hsiao BS, Chu B (2009) Formation of functional polyethersulfone electrospun membrane for water purification by mixed solvent and oxidation processes. Polymer 50:2893–2899

    Article  CAS  Google Scholar 

  10. Ma H, Burger C, Hsiao BS, Chu B (2014) Fabrication and characterization of cellulose nanofiber based thin-film nanofibrous composite membranes. J Membr Sci 454:272–282

    Article  CAS  Google Scholar 

  11. Obaid M, Tolba GMK, Moaaed M (2015) Effective polysulfone-amorphous SiO2 NPs electrospun nanofibers membrane for high flux oil/water separation. Chem Eng J 279:631–638

  12. Homaeigohar SS, Mahdavi H, Elbahri M (2012) extraordinarily water permeable sol-gel formed nanocomposite nanofibrous membranes. Coll Interface Sci 366:51–56

    Article  CAS  Google Scholar 

  13. Homaeigohar SS, Elbahri M (2012) Novel compaction resistant and ductile nanocomposite nanofibrous microfiltration membranes. Coll Interface Sci 372:6–15

    Article  CAS  Google Scholar 

  14. Luo ML, Tang W, Zhao JQ, Pu C (2006) Hydrophilic modification of poly(ethersulfone) used TiO2 nanoparticles by a sol–gel process. Mater Proc Tech 172:431–436

    Article  CAS  Google Scholar 

  15. Yu J, Kim YG, Kim DY, Lee S, Jo SM (2015) Super high flux microfiltration based on electrospun nanofibrous m-aramid membranes for water treatment. Macromol Res 23(7):601–606

    Article  CAS  Google Scholar 

  16. Kaur S, Sundarrajan S, Rana D, Matsuura T, Ramakrishna S (2012) Influence of electrospun fiber size on the separation efficiency of thin film nanofiltration composite membrane. Membr Sci 392–393:101–111

    Article  Google Scholar 

  17. Pezeshki Modaress M, Mirzadeh H, Zandi M (2012) Fabrication of a porous wall and higher interconnectivity scaffold comprising gelatin/chitosan via combination of salt-leaching and lyophilization methods. Iran Polym J 21:191–200

    Article  CAS  Google Scholar 

  18. ASTM F316 - 03 (2011) Standard test methods for pore size characteristics of membrane filters by bubble point and mean flow pore test

  19. Jiankang H, Dichen L, Yaxiong L, Bo Y, Bingheng L, Qin L (2007) Fabrication and characterization of chitosan/gelatin porous scaffolds with predefined internal microstructures. Polymer 48:4578–4588

    Article  Google Scholar 

  20. Ranjbarzadeh-Dibazar A, Shokrollahi P, Barzin J, Rahimi A (2014) Lubricant facilitated thermo-mechanical stretching of PTFE and morphology of the resulting membranes. Membr Sci 470:458–469

    Article  CAS  Google Scholar 

  21. Barzin J, Feng C, Khulbe K, Matsuura T, Madaeni S, Mirzadeh H (2004) Characterization of polyether sulfone hemodialysis membrane by ultrafiltration and atomic force microscopy. Membr Sci 237:77–85

    Article  CAS  Google Scholar 

  22. Que W, Hu X (2003) Optical and mechanical properties of sol–gel silica–titania hard optical coatings derived from methyltrimethoxysilane and tetrapropylorthotitanate as precursors. Opt Mater 22(1):31–37

    Article  CAS  Google Scholar 

  23. Yu J, Zhao X, Du J, Chen W (2000) Preparation, microstructure and photocatalytic activity of the porous TiO2 anatase coating by sol-gel processing. J Sol Gel Sci Technol 17(2):163–171

    Article  CAS  Google Scholar 

  24. Mituppatham C, Nithitanakul M, Supaphol P (2004) Ultrafine electrospun Polyamide-6 fibers: effect of solution conditions on morphology and average fiber diameter. Macro Chem Phys 25:1289–1297

    Google Scholar 

  25. Saeed SM (2011) Fabrication of scaffold based on hybrid of Glatin/PLGA using in tissue engineering. Dissertation, Iran polymer and petrochemical Institute

  26. Bilad M, Westbroek P, Vankelecom IFJ (2011) Assessment and optimization of electrospun nanofiber-membranes in a membrane bioreactor (MBR). Membr Sci 380:181–191

    Article  CAS  Google Scholar 

  27. Ramakrishna S (2005) An introduction to electrospinning and nanofibers. World Scientific, Singapore

    Book  Google Scholar 

  28. Shamim Z, Saeed B, Amir T, Abo SR, Rogheih D (2012) The effect of flow rate on morphology and deposition area of electrospun nylon 6. Nanofiber Eng Fibers Fabrics 7(4):42–49

    Google Scholar 

  29. Homaeigohar SS (2011) Functional electrospun nanofibrous membranes for water filteration. Dissertation, University of Christian-Albrechts

  30. Gopal R, Kaur S, Ma Z, Chan C, Ramakrishna S, Takeshi Matsuura T (2006) Electrospun nanofibrous filtration membrane. Membr Sci 281:581–586

    Article  CAS  Google Scholar 

  31. Phumlani M, Stephen M, Sabelo M, Edward N (2015) Evaluation of nanofiber mats decorated with silver nanoparticles for organic fouling control. Mater Today Proc 2:4158–4166

    Article  Google Scholar 

  32. Basri H, Ismail AF, Aziz M (2011) Polyethersulfone (PES) silver composite UF membrane: effect of silver loading and PVP molecular weight on membrane morphology and antibacterial activity. Desalination 273:72–80

    Article  CAS  Google Scholar 

  33. Kima Y, Ranaa D, Matsuura T, Chung WJ (2009) Influence of surface modifying macromolecules on the surface properties of poly(ethersulfone) ultra-filtration membranes. Membr Sci 338:84–91

    Article  Google Scholar 

  34. Szentivanyi A, Chakradeo T, Zernetsch H, Glasmacher B (2011) Electrospun cellular microenvironments: understanding controlled release and scaf-fold structure. Adv Drug Del Rev 63:209–220

    Article  CAS  Google Scholar 

  35. Shahgaldi S, Yaakob Z, Ghasemi M, Daud W, Khadem D (2011) Investigation of the effect of electrospun polyethersulfone nanofibers in membrane. Def Diff Forum 312–315:607–612

    Article  Google Scholar 

  36. Daels N, De Vrieze S, Decostere B, Dejans P, Dumoulin A, De Clerck K, Westbroek P, Van Hulle SWH (2010) The use of electrospun flat sheet nanofibre membranes in MBR applications. Desalination 257:170–176

    Article  CAS  Google Scholar 

  37. Bintasan K (2013) Microfiltration membranes via electrospinning of polyethersulfone solutions. Dissertation, University of Duisburg-Essen, Germany, 2013

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Authors and Affiliations

  1. Department of Biomaterials, Iran Polymer and Petrochemical Institute, P.O. Box: 14965/159, Tehran, Iran

    Sakine Khezli, Mojgan Zandi & Jalal Barzin

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  1. Sakine Khezli
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  2. Mojgan Zandi
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  3. Jalal Barzin
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Correspondence to Mojgan Zandi.

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Khezli, S., Zandi, M. & Barzin, J. Fabrication of electrospun nanocomposite polyethersulfone membrane for microfiltration. Polym. Bull. 73, 2265–2286 (2016). https://doi.org/10.1007/s00289-016-1607-5

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  • DOI: https://doi.org/10.1007/s00289-016-1607-5

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