Summary
(PP-g-DMAEMA)-g-NIPAAm was synthesized using gamma radiation from a 60Co source. Graft polymerization of N,N’-dimethylaminoethylmethacrylate (DMAEMA) onto polypropylene (PP) was accomplished in about 100 percent yield by the mutual irradiation technique at a dose of 10 kGy. Grafting of N-isopropylacrylamide (NIPAAm) onto PP-g-DMAEMA was carried out by the pre-irradiation method with doses from 20 to 100 kGy. The influence of temperature, reaction time, and monomer concentration on grafting yield was studied. Grafting processes were confirmed by infrared spectroscopy (FTIR-ATR). (PP-g-DMAEMA)-g-NIPAAm films were characterized by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The lower critical solution temperature (LCST) and critical pH point of the films were obtained by water contact angle and percent swelling measurements. The LCST was also determined by DSC. We report here hare a new binary graft copolymer which shows two LCST values, synthesized in two steps.
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Göpferich A (2008) Eur J Pharm Biopharm 68:1
Li W, Wu W, Liu W (2008) Int J Pharm 346:133
Kisselev AM, Manias E (2007) Fluid Phase Equilibr 261:69
Beltran S, Baker JP, Hooper HH, Blanch HW, Prausnitz JM (1991) Macromolecules 24:549
Park T G, Hoffman AS (1992) J App Polym Sci 46:659
Feil H, Bae YH, Feijen J, Kim SW (1992) Macromolecules 25:5528
Brazel CS, Peppas NA (1995) Macromolecules 28:8016
Seok-Gil E, Hudson SM (2004) Prog Polym Sci 29:1173
Chen G, Ito Y, Imanishi Y (1997) Macromolecules 30:7001
Yuk SH, Cho SH, Lee SH (1997) Macromolecules 30:6856
Yoshida R, Takahashi T, Yamaguchi T, Ichijo H (1997) Adv Mater 9:175
Wu C, Zhou S (1997) Macromolecules 30:574
Bucio E, Aliev R, Burillo G (2002) Polymer Bull 47:571
Sen M, Sari M (2005) Eur Polym J 41:1304
Cho SH, Jhon MS, Yuk SH (1999) Eur Polym J 35:1841
Traitel T, Cohen Y, Kost J (2000) Biomaterials 21:1679
Kim EJ, Cho SH, Yuk SH (2001) Biomaterials 22:2495
Wettering P, Hennik WE (1999) J Control Rel 60:249
Park TG, Hoffman AS (1990) J Biomed Mater Res 24:21
Zhuang Y, Wang G, Yang H, Zhu Z, Fu J, Song W, Zhao H (2005) Polym Int 54:617
Kobayashi J, Kikuchi A, Sakai K, Okano T (2002) J Chrom A 958:109
Burillo G, Bucio E, Arenas E, Lopez G (2007) Macromol Mater Eng 292:214
Bucio E, Burillo G, Adem E, Coqueret X (2005) Macromol Mater Eng 290:745
Bergbreiter DE, Case BL, Liu YS, Caraway JW (1998) Macromolecules 30:6053
Schmaljohann D, Oswald J, Jorgensen B, Nitschke M, Beyerlein D, Werner C (2003) Biomacromolecules 4:1733
Cho SH, Jhon MS, Yuk SH, Lee HB (1997) J Poly Sci B Polym Phys 35:595
Siegel RA, Firestone BA (1988) Macromolecules 21:3254
Yalong Z, Ling X, Min Y, Maolin Z, Jianrui W, Hongfei H (2006) Eur Polym J 42:2959
Feil H, Bae YH, Feijen J, Kim SW (1992) Macromolecules 25:5528
Liu S, Weaver JVM, Tang Y, Billingham NC, Armes SP, Tribe K (2002) Macromolecules 35:6121
Lee SB, Russell AJ, Matyjaszewski K (2003) Biomacromolecules 4:1386
Vamvakaki M, Billingham SP, Armes SP (1999) Macromolecules 32:2088
Wetering P, Cherng JY, Talsma H, Crommelin DJA, Hennik WE (1998) J Control Rel 53:145
Wakebayashi D, Nishiyama N, Itaka K, Miyata K, Yamasaki Y, Harada A, Koyama H, Nagasaki Y, Kataoka K (2004) Biomacromolecules 5:2128
Alvarez-Lorenzo C, Barriero-Iglesias R, Concheiro A, Iourtchenko L, Bromberg L, Temchenko M, Deshmukh S, Hatton TA (2005) Langmuir 21:5142
Cai H, Zhang ZP, Sun PC, He BL, Zhu XX (2005) Rad Phys Chem 74:26
Yoo MK, Sung YK, Lee YM, Cho CS (1998) Polymer 39:3703
Sun Q, Deng Y (2005) J Am Chem Soc 127:8274
Frietas RFS, Cussler EL (1987) Chem Eng Sci 42:97
Ringrose BJ, Kronfli EK (2000) Eur Polym J 36:591
Shaozao T, Guangji L, Jiarui S (2000) J Appl Polym Sci 77:1861
Bucio E, Aliev R, Burillo G (1998) Rad Phys Chem 52:193
Ramírez-Fuentes YS, Bucio E, Burillo G (2007) Nucl Instrum Meth B 265:183
Chen J, Wu Z, Yang L, Zhang Q, Sun J, Shi Y, Xia L, Kaetsu I (2007) Rad Phys Chem 76:1367
Arenas E, Bucio E, Burillo G (2007) Polym Bull 58:401
Emileh A, Vasheghani-Farahani E, Imani (2007) Eur Polym J 43:1986
Yan-Lei S, Chao L (2007) J Colloid Interface Sci 316:344
Siegel RA (1993) Adv Polym Sci 109:233
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Meléndez-Ortiz, H.I., Bucio, E. Radiation synthesis of a thermo-pH responsive binary graft copolymer (PP-g-DMAEMA)-g-NIPAAm by a two step method . Polym. Bull. 61, 619–629 (2008). https://doi.org/10.1007/s00289-008-0982-y
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DOI: https://doi.org/10.1007/s00289-008-0982-y