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Complexes of poly(2-N,N-dimethylaminoethyl) methacrylate with heavy metals II. Oxidation of cyclohexene with tert-butylhydroperoxide

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Abstract

Metal complexes of poly(2-N,N-dimethylaminoethyl) methacrylate were prepared by complex-forming with aqueous solutions of salts of FeSO4.2H2O; CoCl2.6H2O; CuCl2.2H2O; VOSO4.5H2O; Na2MoO4.2H2O and Na2WO4.2H2O. The catalytic activity of the complexes was studied in the oxidation of cyclohexene as a model reaction. The activities of the complexes synthesized towards the reaction of cyclohexene epoxidation can be arranged by the following order: PDMAEM-MoO2 2+> PDMAEM-VO2+ > PDMAEM-WO2 2+> PDMAEM-Co2+ > PDMAEM-Fe3+> PDMAEM-Cu2+. The complexes catalyzing the homolytic decomposition of tert-butylhydroperoxide increased the maximum yield of 2-cyclohexene-1-ol and 2-cyclohexene-1-on. The yield of cyclohexene oxide and 2-cyclohexene-1-ol were 58% and 13%, respectively.

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Authors and Affiliations

  1. Department of Biotechnology, ‘‘Prof. Assen Zlatarov’’ University, Y.Yakimov Str. 1, 8010, Burgas, Bulgaria

    Krassimir Vassilev

  2. Department of Materials Science, ‘‘Prof. Assen Zlatarov’’ University, Y.Yakimov Str. 1, 8010, Burgas, Bulgaria

    Sevdalina Turmanova

Authors
  1. Krassimir Vassilev
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  2. Sevdalina Turmanova
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Correspondence to Sevdalina Turmanova.

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Vassilev, K., Turmanova, S. Complexes of poly(2-N,N-dimethylaminoethyl) methacrylate with heavy metals II. Oxidation of cyclohexene with tert-butylhydroperoxide . Polym. Bull. 60, 467–475 (2008). https://doi.org/10.1007/s00289-007-0879-1

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  • DOI: https://doi.org/10.1007/s00289-007-0879-1

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