Skip to main content
SpringerLink
Log in

Cobalt and manganese complexes with redox-active ligands in polymerization of acrylonitrile and methyl methacrylate

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The influence of bis[4,6-di-tert-butyl-N-(2,6-dimethylphenyl)-o-iminobenzosemiquinonato]cobalt(ii) and 4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-iminobenzosemiquinonato]-[4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-amidophenolate]manganese(iii) on polymerization of methyl methacrylate and acrylonitrile in the presence of azobisisobutyronitrile (as a traditional radical initiator) and alkyl halides (used for initiation of controlled atom transfer radical polymerization process) was studied. The effect of the nature of the activating agents (amines) and the temperature conditions on the overall polymerization rate of the indicated monomers, as well as molecular weight characteristics of the synthesized polymers, were analyzed. The optimal conditions for the synthesis of polyacrylonitrile and poly(methyl methacrylate) with a relatively narrow molecular weight distribution were selected.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. P. Morgan, Carbon Fibers and Their Composites, Taylor and Francis, New York, 2005, 1200.

    Book  Google Scholar 

  2. M. Chanda, S. K. Roy, Industrial Polymers, Specialty Polymers and Their Application, CRC Press Taylor & Francis Group, London, New York, 2008, 432.

    Book  Google Scholar 

  3. E. V. Kolyakina, D. F. Grishin, Russ. Chem. Rev., 2009, 78, 535.

    Article  CAS  Google Scholar 

  4. M. Yu. Zaremski, Polym. Sci., Ser. C, 2015, 57, 65.

    Article  CAS  Google Scholar 

  5. Nitroxide Mediated Polymerization From Fundamentals to Applications in Materials Science, Ed. D. Gigmes, The Royal Society of Chemistry, UK, 2016, 500 p.

  6. R. Poli, Angew. Chem., Int. Ed. Engl., 2006, 45, 5058.

    Article  CAS  Google Scholar 

  7. K. Satoh, M. Kamigaito, M. Sawamoto, Polymer Sci.: A Comprehensive Ref., Eds K. Matyjaszewski, M. Möller, Elsevier, Netherlands, UK, USA, 2012, 3, 429.

    Book  Google Scholar 

  8. K. Matyjaszewski, N. V. Tsarevsky, J. Am. Chem. Soc., 2014, 136, 6513.

    Article  CAS  Google Scholar 

  9. G. Moad, E. Rizzardo, S. H. Thang, Fundamentals of Controlled Living Radical Polymerization, Eds N. V. Tsarevsky, B. S. Sumerlin, The Royal Society of Chemistry, UK, 2013, 205.

    Book  Google Scholar 

  10. E. V. Kolyakina, D. F. Grishin, Russ. Chem. Rev., 2011, 80, 683.

    Article  CAS  Google Scholar 

  11. A. Debuignea, R. Poli, C. Jérômea, R. Jérômea, C. Detrembleura, Prog. Polym. Sci., 2009, 34, 211.

    Article  Google Scholar 

  12. E. V. Kolyakina, A. I. Poddel´skii, D. F. Grishin, Russ. Chem. Bull., 2014, 63, 987.

    Article  CAS  Google Scholar 

  13. E. V. Kolyakina, A. I. Poddel´sky, D. F. Grishin, Polym. Sci., Ser. C, 2014, 56, 566.

    Article  CAS  Google Scholar 

  14. E. V. Kolyakina, I. D. Grishin, A. I. Poddel´sky, D. F. Grishin, J. Polym. Res., 2016, 23, 222; DOI: 10.1007/s10965-016-1114-2.

    Article  Google Scholar 

  15. E. V. Kolyakina, L. B. Vaganova, A. V. Lado, A. V. Piskunov, V. K. Cherkasov, D. F. Grishin, Russ. Chem. Bull., 2007, 56, 1363.

    Article  CAS  Google Scholar 

  16. A. I. Poddel´sky, V. K. Cherkasov, G. K. Fukin, M. P. Bubnov, L. G. Abakumova, G. A. Abakumov, Inorg. Chim. Acta, 2004, 357, 3632.

    Article  Google Scholar 

  17. A. I. Poddel´sky, V. K. Cherkasov, G. K. Fukin, M. P. Bubnov, Inorg. Chim. Acta, 2005, 358, 3829.

    Article  Google Scholar 

  18. Z. H. Li, Y. M. Zhang, M. Z. Xue, L. Zhou, Y. G. Liu, J. Polym. Sci., Part A: Polym. Chem., 2005, 43, 5207.

    Article  CAS  Google Scholar 

  19. Z. H. Huang, Y. M. Zhang, H. Li, Y. G. Liu, Macromol. Chem. Phys., 2008, 209, 825.

    Article  CAS  Google Scholar 

  20. R. K. Samal, J. Macromol. Sci., Part A: Chemistry, 1982, 18, 719.

    Article  Google Scholar 

  21. K. Fujisawa, M. Nabika, Coord. Chem. Rev., 2013, 257, 119.

    Article  CAS  Google Scholar 

  22. M. Ciftci, M. A. Tasdelen, Y. Yagc, Polym. Int., 2016, 65, 1001.

    Article  CAS  Google Scholar 

  23. A. D. Asandei, Chem Rev., 2016, 116, 2244.

    Article  CAS  Google Scholar 

  24. O. A. Shamenkova, N. A. Kopylova, Yu. D. Semchikov, G. A. Abakumov, Yu. A. Kurskii, V. K. Cherkasov, Polym. Sci., Ser. В, 2005, 47, 314.

    Google Scholar 

  25. Entsiklopediya polimerov [Encyclopedia of polymers], Ed. V. A. Kabanov, Sov. Entsiklopediya, Moscow, 1972, 1, 932 pp. (in Russian).

  26. A. Weissberger, E. Proskauer, J. Riddick, E. Toops, Organic Solvents, Interscience Publishers, New York, 1955.

    Google Scholar 

  27. GOST [USSR State Standard Specification] 6709-72, distilled water. Technical conditions.

  28. Organic Syntheses, Interscience Publishers, New York—London, 1946—1952, 26—32.

  29. B. G. Belen´kiy, L. Z. Vilenchik, Khromatografiya polimerov [Chromatography of Polymers], Khimiya, Moscow, 1978, 344 pp. (in Russian).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. I. Lobachevsky National Reseach State University of Nizhny Novgorod, 23 prosp. Gagarina, 603950, Nizhny Novgorod, Russian Federation

    E. V. Kolyakina, L. N. Gruzdeva & D. F. Grishin

  2. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603950, Nizhny Novgorod, Russian Federation

    A. I. Poddel´sky

Authors
  1. E. V. Kolyakina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. N. Gruzdeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. I. Poddel´sky
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. D. F. Grishin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to D. F. Grishin.

Additional information

Dedicated to Academician of the Russian Academy of Sciences G. A. Abakumov on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1650—1659, September, 2017.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kolyakina, E.V., Gruzdeva, L.N., Poddel´sky, A.I. et al. Cobalt and manganese complexes with redox-active ligands in polymerization of acrylonitrile and methyl methacrylate. Russ Chem Bull 66, 1650–1659 (2017). https://doi.org/10.1007/s11172-017-1937-y

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-017-1937-y

Key words

Search

Navigation