Skip to main content
Log in

Hydrogeochemical investigation of Küçük Menderes River coastal wetland, Selçuk–Izmir, Turkey

  • Original Article
  • Published:
Environmental Geology

Abstract

Küçük Menderes River forms a rich coastal wetland inside in the Selçuk plain. Three saline/brackish lakes, one swamp and Küçük Menderes River are these wetlands’ components. Alkaline-slightly alkaline type lakes are recharged from precipitation and karstic springs that discharge from marble-schist and marble-alluvium contacts in the northern and southern parts of the study area. Water types of the wetland are Na–Cl and Na–Ca–Mg–HCO3–Cl in both rainy and dry seasons. Both seawater intrusion and evaporation, as being the sources of the ions, justify the presence of Na–Cl, Na–SO4 and Cl–SO4, in the wetland water. Environmental isotopes were used to identify the relationship between wetland and groundwater in the Selçuk plain. The δ18O and δD composition of wetland area samples have changed between −6.42 to −4.56‰, and −36.40 to −23.80‰, respectively. The lakes and rivers are plotted on the mixing line by slope of 5.2 and these data indicate that wetland is affected from seawater intrusion. The recharge area that was sampled in order to compare the wetland has Ca–HCO3 water type with a neutral-slightly alkaline pH values and the main hydrogeochemical process is weathering the different types of silicates. Iron, manganese and selenium are the dominant minor ions due to the high biological activities and organic matters in the lakes. There are two contamination risks for this wetland: (1) waste disposal site and (2) water treatment plant where the purified waters are released into the river. EC, Al, As, Cd, Cu, Fe and Zn values exceed those of aquatic life standards. In the near future these sites will pose a danger for wetland wild life and surrounding irrigation water suppliers.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14

Similar content being viewed by others

References

  • APHA-AWWA-WPCF (1992) Standard methods for the examination of water and wastewater, 18th edn, USA

  • Canadian Water Quality Guidelines (CWQG) for The Protection of Aquatic Life (2005) http://www.ccme.ca/assets/pdf/wqg_aql_summary_table.pdf

  • Candan O, Dora O (1998) Menderes Masifinde Granulit, Eklojit ve Mavi Sist Kalintilari: Pan-Afrikan ve Tersiyer Metamorfik Evrimine Bir Yaklasim (Residues of granulite, eclogite and blue schists in Menderes Massif: an approach to pan-african and tertiary metamorphic evalotion) (in Turkish). Türkiye Jeoloji Bulteni 41(1):1–35

    Google Scholar 

  • Carnoda A, Carillo-Rivera JJ, Huizar-Alvarez R, Graniel-Castro E (2004) Salinization in coastal aquifers of arid zones: an example from Santo Domingo, Baja California sur, Mexico. Env Geol 45:350–366

    Article  Google Scholar 

  • Carter V (1996) Technical aspects of wetlands: wetland hydrology, water quality and associated functions. USGS Water Supply Paper 2425

  • Cetinkaplan M (2002) Tertiary high pressure/low temperature metamorphism in the Mesozoic Cover Series of the Menderes Massif and Correlation with the Cycladic Crystalline Complex. PhD Thesis, Dokuz Eylul Universitesi Fen Bilimleri Enstitusu, Izmir (Unpublished)

  • Chakrapani G (2002) Water and sediment geochemistry of major Kumaun Himalayan lakes, India. Environ Geol 43:99–107

    Article  Google Scholar 

  • Clark ID, Fritz P (1997) Environmental isotopes in hydrogeology. Lewis, New York

    Google Scholar 

  • Cowardin LM, Golet FC, LaRoe ET (1979) Classification of Wetlands and Deepwater Habitats of the United States. US Department of the Interior, U.S. Fish and Wildlife Service, Office of Biological Services, Washington. FWS/OBS-79/31

  • Craig H (1961) Isotopic variations in meteoric waters. Science 133:1702– 3

    Article  Google Scholar 

  • Deng Y, Stumm W (1993) Kinetics of redox cycling of iron coupled with fulvic acid. Aquatic Sci 55:103–111

    Article  Google Scholar 

  • DSI (1973) Küçük Menderes Ovası Hidrojeolojik Etüt Raporu (Hydrogeologic report of Kucuk Menderes Plain). Devlet Su Isleri Gn. Md. Jeoteknik Hizmetler ve Yeralti Sulari Dair. Bsk, Ankara (in Turkish)

  • DSI (1990) Izmir-Selcuk-Pamucak Ovasi ve Cevresi On Hidrojeolojik Etud raporu (Preliminary Hydrogeologic report of Izmir-Selcuk-Pamucak plain and around). DSI – Izmir Sb (in Turkish)

  • Edet AE, Merkel BJ, Offiong OE (2003) Contamination risk assessment of fresh groundwater using the distribution and chemical speciation of some potentially toxic elements in Calabar (southern Nigeria). Environ Geol 45:1025–1035

    Google Scholar 

  • Elbaz-Poulichet F, Seyler P, Maurice-Bourgoin L, Guyot JL, Dupuy C (1999) Trace element geochemistry in the upper Amazon drainage basin (Bolivia). Chem Geol 157:319–334

    Article  Google Scholar 

  • Egemen O (2005) Kucuk Menderes Nehri’nin Su Kalitesi ve Ekosistemdeki Etkilesimin Incelenmesi (Water quality of Kucuk Menderes River and Interaction between ecosystems) (in Turkish). Ege Universitesi Su Urünleri Fakültesi

  • EPA (2003) http://www.epa.gov/safewater/mcl.html

  • Erdem O (1995) Turkey’s Bird Paradises. Republic of Turkey Ministry of Environment, Green Series: 5, Ankara

  • Erdoğan B (1990) Tectonic relation between İzmir–Ankara zone and Karaburun belt. Min Res Exp Bull Turkey 110:1–15

    Google Scholar 

  • Fan TW-M, Lane AN, Higashi RM (1997) Selenium biotransformations by a euryhaline microalga isolated from a saline evaporation pond. Environ Sci Technol 31(2):569–576

    Article  Google Scholar 

  • Ferguson JF, Gavis J (1972) A review of the arsenic cycle in natural waters. Water Res 6:1259–1274

    Article  Google Scholar 

  • Gallawey W (1975) Process framework for describing the morphologic and stratigraphic evolution of deltatic depositional systems. Deltas. Houston Geol Soc, pp 87–98

  • Gemici Ü (2004) Impact of acid mine drainage from the aboundand Halıköy Mercury Mine (western Turkey) on surface and groundwater. Bull Environ Cont Toxic 72/6:1104–1114

    Google Scholar 

  • Gencer Guler G, Zafer Turkyilmaz B (2003) Selçuk-Pamucak Sulak Alanının Sınıflandırılması Üzerine Bir Araştırma. Ege Üniv Ziraat Fak Derg 40(3):121–128

    Google Scholar 

  • Gokcen SL, Kazanci N, Yasar D, Gokcen N, Bayhan E (1996) Kucuk Menderes Delta Kompleksi ve Gelisiminde Aktif Tektonizma Etkileri (Kucuk Menderes River delta complex and the effects of active tectonism on its development) Ankara (In Turkish). Turkiye Jeoloji Bulteni C.33:15–29

    Google Scholar 

  • Gungor T, Erdogan B (2002) Tectonic significance of Mafic volcanic rocks in a Mesozoic sequence of the Menderes Massif, West Turkey. Int J Earth Sci (Geol Rundsch) 91:386–397

    Article  Google Scholar 

  • Hem JD (1985) Study and interpretation of the chemical characteristics of natural water, 3rd edn. USGS Water-supply paper 2254, USA

  • IAH (International Association of Hydrogeologists) (1979) Map of Mineral and Thermal Water of Europe Scale: 1:500,000. IAH, UK

  • Kayan İ, Kraft JC (1997) Selçuk Ovasında Efes Kültürünün Gelişimine Coğrafi Çevrenin Etkileri, Birinci Uluslararası Geçmişten Günümüze Selçuk Sempozyumu Bildiriler Kitabı, 113–123, İzmir

  • Kretz R (1983) Symbols for rock-forming minerals. Am Mineral 68:277–279

    Google Scholar 

  • La Ruffa G, Panichi C, Kavouridis T, Liberopoulou V, Leontiadis J, Caprai A (1999) Isotope and chemical assessment of geothermal potential of Kos Island\Greece. Geothermics 28:205–217

    Article  Google Scholar 

  • Malcolm R, Soulsby C (2001) Hydrochemistry of groundwater in coastal wetlands: implications for coastal conservation in Scotland. Sci Total Environ 265:269–280

    Article  Google Scholar 

  • Marimuthu S, Reynolds DA, Le Gal La Salle C (2005) A field study of hydraulic, geochemical and stable isotope relationships in a coastal wetlands system. J Hydrol 315:93–116

    Article  Google Scholar 

  • Masscheleyn PH, Delaune RD, Patrick WH Jr (1991) Arsenic and selenium chemistry as affected by sediment redox potential and pH. J Environ Qual 20:522–7

    Article  Google Scholar 

  • Nippon (1996) The Study on Kucuk Menderes River Basin Irrigation Project in the Republic of Turkey. Japon International Cooperation Agengy (JICA) and Devlet Su Isleri (DSI)

  • Olivie-Lauquet G, Gruau G, Dia A, Riou C, Jaffrezic A, Henin O (2001) Release of trace elements in wetlands: role of seasonal variability. Water Resources 35(4):943–952

    Google Scholar 

  • Öner (1997) Selcuk Ovasının Fotojeomorfolojisi (Photogeology of Selcuk Plain). I. Uluslararasi Gecmisten Gunumuze Selcuk Semp., Selcuk Manicipality and Ege University Izmir Research and Application Center, Selcuk (in Turkish)

  • Oremland RS (1994) Biogeochemical transformations of selenium in environments. In: Frankenberger WT Jr, Benson SN (eds) Selenium in the environment. Marcel Dekker, New York, pp 389–419

    Google Scholar 

  • Parkhust DL, Appelo CAJ (1999) User’s guide to PHREEQC (version 2)—a computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations. U.S. Geological Survey Water-Resources Investigations Report 99–4259, 312 pp

  • Piper AM (1944) A graphic procedure in geochemical interpretation of water analyses. Am Geophys Union Trans 25:914–923

    Google Scholar 

  • Pusatli OT (2000) Assessment of Irrigation Water Quality And Contamination In The Kucuk Menderes River Basin Izmir-Turkey: MSc Thessis, Middle East Technical University, Ankara (Unpublished)

  • Rahman MM, Seike Y, Okumura M (2006) Concentrations of Arsenic in brackish lake water: application of Tristimulus Colorimetric determination (Japan). Anal Sci 22:475–478

    Article  Google Scholar 

  • Ramsar (2004) http://www.ramsar.org

  • Ryu JH, Gao S, Dahlgren RA, Zierenberg RA (2002) Arsenic distribution, speciation and solubility in shallow groundwater of Owens Dry Lake, California. Geoch Et Cosmoch Acta 66:2981–2994

    Article  Google Scholar 

  • Sahinci A (1991) Dogal Sularin Jeokimyasi (Geochemistry of natural waters). Reform Matbaası, Beyler-Izmir, 548 (in Turkish)

  • Sıkı M (1997). Selcuk (Izmir) Kus Cenneti’ne Genel Bir Bakis (A general view of Selcuk (Izmir) Bird Paradise). I. Uluslararasi Gecmisten Gunumuze Selcuk Semp., Selcuk Municipality and Ege University Izmir Research and Application Center, Selcuk (in Turkish)

  • Smedly PL, Kinniburgh DG (2002) A review of the source, behavior and distribution of arsenic in natural waters. Appl Geochem 17:517–568

    Article  Google Scholar 

  • Somay MA, Filiz S (2003) Hydrology, hydrogeology and hydrogeochemistry of wetlands: a case study in Izmir Bird Paradise, Turkey. Environ Geol 43:825–835

    Google Scholar 

  • Somay MA, Filiz S (2005) The importance of hydrogeology and hydrogeochemistry in the wetlands. Int Earth Sci Coll on the Aegean Region (IESCA 2005) Abstracts, p 211, Izmir

  • Stumm W, Morgan JJ (1996) Aquatic chemistry. Wiley Interscience, New York, p 1022

  • Thorntwaite WC (1948) An approach toward a rational classification of climate. Geogr Rev 38:55–94

    Article  Google Scholar 

  • TSE 266 (1997) Türk Standardi: Sular-Icme ve Kullanma Sulari (Turkish Drinking Water Standards). 1. Baskı, Ankara (in Turkish)

  • Water Regulations of Turkey (Su Kirliligi Yönetmeliği) (2004) Resmi Gazete, Number: 25687

  • WFD CIS (2003) The role of wetlands in the Water Framework Directive. Directorate General Environment of the European Commission, Brussels

  • WWF-Turkiye (2006) http://www.wwf.org.tr/tr/alan.asp?alang=en&atype=1&aid=18

  • Yazicigil H, Karahanoglu N, Yilmaz K, Gundogdu A, Şakiyan J, Yesilnacar E, Tuzcu B (2000) Investigation and management of the Kucuk Menderes Basin groundwater. Hydrogeology, vol 5. Middle East Technical University, Ankara

  • Yurtsever Y (1983) Models for tracer data analysis. In: Guidebook on nuclear techniques in hydrology. Technical Report. Series no. 91, IAEA, Vienna

Download references

Acknowledgments

This paper forms a part of a PhD study carried out by the first author. This study also supported by Dokuz Eylül University Scientific Research Projects (BAP) (Project no: 03.KB.FEN.057). The authors are also thankful to the reviewer.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. Melis Somay.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Somay, A.M., Gemici, Ü. & Filiz, S. Hydrogeochemical investigation of Küçük Menderes River coastal wetland, Selçuk–Izmir, Turkey. Environ Geol 55, 149–164 (2008). https://doi.org/10.1007/s00254-007-0972-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00254-007-0972-7

Keywords

Navigation