Abstract
In this study, makino bamboo (Phyllostachys makinoi) fibers were acetylated with different solution ratios of acetic anhydride/dimethylformamide using a liquid phase reaction. This reaction resulted in the production of acetylated bamboo fibers (BFs) with the following weight percent gains (WPGs): 2, 6, 9, 13, and 19%. The effects of the acetylation level on the thermal decomposition kinetics of bamboo fibers were evaluated by thermogravimetric analysis. The results revealed that as the acetylation level increased, both the onset and maximum decomposition temperatures increased. In addition, four model-free iso-conversional methods, the Friedman method, Flynn–Wall–Ozawa method, the Starink method, and the modified Coats–Redfern method, were used to determine the thermal decomposition kinetics. Accordingly, the activation energies of thermal decomposition with conversion rates ranging between 10% and 70% were 191–196, 190–191, 192–194, 182–186, 186–191, and 189–201 kJ/mol for unmodified BFs and acetylated BFs with WPGs of 2, 6, 9, 13, and 19%, respectively. There were no significant dependencies among them. Furthermore, the Avrami method was used to determine the reaction order of unmodified BFs (0.47), which was lower than those of acetylated BFs (0.55–0.74).
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References
Antal MJ, Varhegyi G, Jakab E (1998) Cellulose pyrolysis kinetics: revisited. Ind Eng Chem Res 37(4):1267–1275. https://doi.org/10.1021/ie970144v
Bledzki A, Wu K, Mamum AA, Lucka-Gabor M, Gutowski VS (2008) The effects of acetylated on properties of flex fiber and its polypropylene composites. Express Polym Lett 2(6):413–422. https://doi.org/10.3144/expresspolymlett.2008.50
Boonstra MJ, Tjeerdsma B (2006) Chemical analysis of heat treated softwoods. Eur J Wood Prod 64:204–211. https://doi.org/10.1007/s00107-005-0078-4
Brown ME, Maciejewski M, Vyazovkin S, Nomen R, Sempere J, Burnham A (2000) Computational aspects of kinetic analysis. Part A: the ICTAC kinetics project-data, methods and results. Thermochim Acta 355:125–143. https://doi.org/10.1016/S0040-6031(00)00443-3
Chaouch M, Pétrissans M, Pétrissans A, Gérardin P (2010) Use of wood elemental composition to predict heat treatment intensity and decay resistance of different softwood and hardwood species. Polym Degrad Stab 95:2255–2259. https://doi.org/10.1016/j.polymdegradstab.2010.09.010
Dittenber DB, Ganga Rao HVS (2012) Critical review of recent publications on use of natural composites in infrastructure. Compos Part A-Appl S 43:1419–1429. https://doi.org/10.1016/j.compositesa.2011.11.019
Gai C, Dong Y, Zhang T (2013) The kinetic analysis of the pyrolysis of agricultural residue under non-isothermal conditions. Bioresour Technol 127:298–305. https://doi.org/10.1016/j.biortech.2012.09.089
Gardea-Hernández G, Ibarra-Gómez R, Flores-Gallardo SG, Hernández-Escobar CA, Pérez-Romo P, Zaragoza-Contreras EA (2008) Fast wood fiber esterification. I. Reaction with oxalic acid and cetyl alcohol. Carbohydr Polym 71:1–8. https://doi.org/10.1016/j.carbpol.2007.05.014
Gronli MG, Verhegyi G, Di Blasi C (2002) Thermogravimetric analysis and devolatilization kinetics of wood. Ind Eng Chem Res 41:4201–4208. https://doi.org/10.1021/ie0201157
Huang YF, Kuan WH, Chiueh PT, Lo SL (2011) A sequential method to analyze the kinetics of biomass pyrolysis. Bioresour Technol 102:9241–9246. https://doi.org/10.1016/j.biortech.2011.07.015
Hung KC, Wu JH (2010) Mechanical and interfacial properties of plastic composite panels made from esterified bamboo particles. J Wood Sci 56:216–221. https://doi.org/10.1007/s10086-009-1090-9
Hung KC, Wu TL, Chen YL, Wu JH (2015) Assessing the effect of wood acetylation on mechanical properties and extended creep behavior of wood/recycled-polypropylene composites. Constr Build Master 108:139–145. https://doi.org/10.1016/j.conbuildmat.2016.01.039
Hung KC, Yang CN, Yang TC, Wu TL, Chen YL, Wu JH (2017) Characterization and thermal stability of acetylated slicewood production by alkali-catalyzed esterification. Materials 10:393–406. https://doi.org/10.3390/ma10040393
Kumar V, Tyagi L, Sinha S (2011) Wood flour—reinforced plastic composites: a review. Rev Chem Eng 27:253–264. https://doi.org/10.1515/REVCE.2011.006
Lee CH, Wu TL, Chen YL, Wu JH (2010) Characteristics and discrimination of five types of wood–plastic composites by Fourier transform infrared spectroscopy combined with principal component analysis. Holzforschung 64:699–704. https://doi.org/10.1515/HF.2010.104
Li X, Tabil LG, Panigrahi S (2007) Chemical treatments of natural fiber for use in natural fiber-reinforced composite: a review. J Polym Environ 15:25–33. https://doi.org/10.1007/s10924-006-0042-3
Li Y, Du L, Kai C, Huang R, Wu Q (2013) Bamboo and high density polyethylene composite with heat-treated bamboo fiber: thermal decomposition properties. BioResources 8(1):900–912. https://doi.org/10.15376/biores.8.1.900-912
Liu W, Chen T, Wen X, Qiu R, Zhang X (2014) Enhanced mechanical properties and water resistance of bamboo fiber—unsaturated polyester composites coupled by isocyanatoethyl methacrylate. Wood Sci Technol 48:1241–1255. https://doi.org/10.1007/s00226-014-0668-6
Liu W, Huang J, Wang N, Lei S (2015) The influence of moisture content on the interfacial properties of natural palm fiber-matrix composite. Wood Sci Technol 49:371–387. https://doi.org/10.1007/s00226-015-0702-3
Manyà JJ, Velo E, Puigjaner L (2003) Kinetics of biomass pyrolysis: a reformulated three-parallel-reactions model. Ind Eng Chem Res 42(3):434–441. https://doi.org/10.1021/ie020218p
Mészáros E, Várhegyi G, Jakab E (2004) Thermogravimetric and reaction kinetic analysis of biomass samples from an energy plantation. Energy Fuels 18(2):497–507. https://doi.org/10.1021/ef034030+
Migneault S, Koubaa A, Erchiqui F, Chaala A, Englund K, Wolcott MP (2011) Application of micromechanical models to tensile properties of wood–plastic composites. Wood Sci Technol 45:521–532. https://doi.org/10.1007/s00226-010-0351-5
Ou R, Zhao H, Sui S, Song Y, Wang Q (2010) Reinforcing effects of Kevlar fiber on the mechanical properties of wood-flour/high-density-polyethylene composites. Compos Part A-Appl S 41:1272–1278. https://doi.org/10.1016/j.compositesa.2010.05.011
Oza S, Ning H, Ferguson I, Lu N (2014) Effect of surface treatment on thermal stability of the hemp-PLA composites: correlation of activation energy with thermal degradation. Compos Part B-Eng 67:227–232. https://doi.org/10.1016/j.compositesb.2014.06.033
Pelaez-Samaniego MR, Yadama V, Lowell E, Espinoza-Herrera R (2013) A review of wood thermal pretreatments to improve wood composite properties. Wood Sci Technol 47:1285–1319. https://doi.org/10.1007/s00226-013-0574-3
Rowell RM (1983) Chemical modification of wood. For Prod Abstr 6:363–382
Saba N, Paridah MT, Jawaid M (2015) Mechanical properties of kenaf fibre reinforced polymer composite: a review. Constr Build Mater 76:87–96. https://doi.org/10.1016/j.conbuildmat.2014.11.043
Saheb DN, Jog JP (1999) Natural fiber polymer composites: a review. Adv Polym Technol 18:351–363. https://doi.org/10.1002/(SICI)1098-2329(199924)18:4%3c351:AID-ADV6%3e3.0.CO;2-X
Tronc E, Hernández-Escobar CA, Ibarra-Gómez R, Estrada-Monje A, Navarrete-Bolaños J, Zaragoza-Contreras EA (2007) Blue agave fiber esterification for the reinforcement of thermoplastic composites. Carbohydr Polym 67:245–255. https://doi.org/10.1016/j.carbpol.2006.05.027
Vuthaluru HB (2004) Investigations into the pyrolytic behavior of coal/biomass blends using thermogravimetric analysis. Bioresour Technol 92:187–195. https://doi.org/10.1016/j.biortech.2003.08.008
Wang X, Liu J, Chai Y (2012) Thermal, mechanical, and moisture absorption properties of wood-TiO2 composites prepared by a sol–gel process. BioResources 7(1):893–901. https://doi.org/10.15376/biores.7.1.893-901
Wei L, McDonald AG, Freitag C, Morrell JJ (2013) Effects of wood fiber esterification on properties, weatherability and biodurability of wood plastic composites. Polym Degrad Stab 98:1348–1361. https://doi.org/10.1016/j.polymdegradstab.2013.03.027
Wu JH, Hsieh TY, Lin HY, Shiau IL, Chang ST (2004) Properties of wood plasticization with octanoyl chloride in a solvent-free system. Wood Sci Technol 37:363–372. https://doi.org/10.1007/s00226-003-0198-0
Xu C, Leppӓnen AS, Eklund P, Holmlund P, Sjöholm R, Sundberg K, Willför S (2010) Acetylation and characterization of spruce (Picea abies) galactoglucomannans. Carbohydr Res 345:810–816. https://doi.org/10.1016/j.carres.2010.01.007
Yang HP, Yan R, Chen HP, Lee DH, Zheng CG (2007) Characteristics of hemicellulose, cellulose and lignin pyrolysis. Fuel 86:1781–1788. https://doi.org/10.1016/j.fuel.2006.12.013
Yang CN, Hung KC, Wu TL, Yang TC, Chen YL, Wu JH (2014) Comparisons and characteristics of slicewood acetylation with acetic anhydride by liquid phase, microwave and vapor phase reactions. BioResources 9(4):6463–6475. https://doi.org/10.15376/biores.9.4.6463-6475
Yao F, Wu Q, Lei Y, Guo W, Xu Y (2008) Thermal decomposition kinetics of natural fibers: activation energy with dynamic thermogravimetric analysis. Polym Degrad Stab 93:90–98. https://doi.org/10.1016/j.polymdegradstab.2007.10.012
Zhang F, Endo T, Qiu W, Yang L, Hirotsu T (2002) Preparation and mechanical properties of composite of fibrous cellulose and maleated polyethylene. J Appl Polym Sci 84:1971–1980. https://doi.org/10.1002/app.10428
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This work was financially supported by a research grant from the Ministry of Science and Technology, Taiwan (MOST 106-2628-B-005-008-CC3).
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Jhu, YS., Hung, KC., Xu, JW. et al. Effects of acetylation on the thermal decomposition kinetics of makino bamboo fibers. Wood Sci Technol 53, 873–887 (2019). https://doi.org/10.1007/s00226-019-01105-z
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DOI: https://doi.org/10.1007/s00226-019-01105-z