Abstract
A new highly selective terbium(III) electrode was prepared with a polymeric film doped using S-2-benzothiazolyl-2-amino-α-(methoxyimino)-4-thiazolethiol acetate as an electroactive material, benzyl acetate (BA) as a plasticizer, and potassium tetrakis(4-chlorophenyl) borate (KTpClPB) as an anionic site in the percentage ratio 3.17:1.58:63.4:31.7 (ionophore-KTpClPB-BA-PVC, w/w). The electrode exhibited a linear response with a near Nernstian slope of 19.5 mV/decade within the concentration range 1.5 × 10−7−1.0 × 10−2 M terbium ions, with a working pH range from 2.0 to 8.0, and a fast response time of 10 s and presented satisfactory reproducibility. The limit of detection was 9.3 × 10−8 M. The results show that this electrode can be used in ethanol media up to 30% (v/v) concentration without interference. It can be used for 3 months without any considerable divergence in the potentials. Selectivity coefficients for terbium(III) with respect to many cations were investigated. The electrode is highly selective for terbium(III) ions over a large number of monovalent, bivalent, and trivalent cations. This shows the valuable property of the proposed electrode. The stability constant of the ionophore towards Tb3+ ions was determined with the sandwich membrane method. It was successfully used as an indicator electrode in potentiometric determination of terbium(III) ions with EDTA and in direct determination in tap water and binary mixtures with quantitative results. The utility of the proposed electrode was also determined in the presence of ionic and nonionic surfactants and in the presence of fluoride ions in four pharmaceutical (mouthwash) preparations.
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Gschneidner KA, Erying L (1979) Handbook on the physics and chemistry of the rare earths, vol 1. North Holland, Amsterdam
Liang T, Zhang S, Wang L, Kung H, Wang Y, Hu A, Ding S (2005) Environ Geochem Health 27:301–311
Haiduc I, Silvestru C (1990) Coord Chem Rev 99:253–296
Yongxing W, Xiaorong W, Zichum H (2000) Bull Environ Contam Toxicol 64:611–616
Zhao G, Zhao S, Gao J, Kang J, Yang Wu (1997) Talanta 45:303–307
Hrdlicka A, Havel J, Moreno C, Valiente M (1991) Anal Sci 7:925–929
Houk RS, Fassel VA, Reach GD, Svec HJ (1980) Anal Chem 521:2283–2285
Mazzucotelli A, DePaz F, Magi E, Frache B (1992) Anal Sci 8:189–193
Bakker E, Buhlmann P, Pretsch E (1997) Chem Rev 97:3083–3132
Chowdhury DA, Ogata T, Kamata S, Ohashi K (1996) Anal Chem 68:366–370
Ganjali MR, Kiani R, Shamsipur M, Poursaberi T, Salavati-Niasari M, Talebpour Z, Emami M (2004) Electroanalysis 16:1002–1008
Ganjali MR, Rasoolipour S, Rezapour M, Norouzi P, Tajarodi A, Hanifehpour Y (2005) Electroanalysis 17:1534–1539
Ganjali MR, Rahimi M, Maddah B, Moghimi A, Borhany S (2004) Anal Sci 20:1007–1011
Ganjali MR, Tahami M, Shamsipur M, Poursaberi T, Haghgoo S, Hosseini M (2003) Electroanalysis 15:1038–1042
Ganjali MR, Ravanshad J, Hosseini M, Salavati-Niasari M, Pourjavid MR, Baezzat MR (2004) Electroanalysis 16:1771–1776
Singh AK, Mehtab S, Saxena P (2005) Anal Chim Acta 551:45–50
Gupta VK, Singh AK, Gupta B (2006) Anal Chim Acta 575:198–204
Ganjali MR, Ghesmi A, Hosseini M, Pourjavid MR, Rezapour M, Shamsipur M, Salavati-Niasari M (2005) Sens Actuators B 105:334–339
Zamani HA, Rajabzadeh G, Ganjali MR (2006) J Braz Chem Soc 17:1297–1303
Suzuki K, Tohda K, Aruga H, Matsuzoe M, Inoue H, Shirai T (1988) Anal Chem 60:1714–1717
Khayatian G, Shariati S, Salimi A (2003) Bull Kor Chem Soc 24:421–426
Katsu T, Ido K, Takaishi K, Yokosu H (2002) Sens Actuators B 87:331–335
Guilbault GG, Durst RA, Frant MS, Freiser H, Hansen EH, Light TS, Pungor E, Rechnitz G, Rice MN, Rohm TJ, Simon W, Thomas DR (1976) Pure Appl Chem 48:127–135
Ammann D, Pretsch E, Simon W, Lindner E, Bezegh A, Pungor E (1985) Anal Chim Acta 171:119–129
Masoda Y, Zhang Y, Yan C, Li B (1998) Talanta 46:203–213
Schaller U, Bakker E, Suzuki K, Simon W (1993) Anal Chim Acta 280:197–208
Gehrig PM, Morf WE, Welti M, Pretsch E, Simon W (1990) Helv Chim Acta 73:2003–2008
Eugster R, Gehrig PM, Morf WE, Spichiger UE, Simon W (1991) Anal Chem 63:2285–2290
Tohda K, Higuchi T, Dragoe D, Umezawa Y (2001) Anal Sci 17:833–839
Eugster R, Rosatzin T, Rusterholz B, Aebersold B, Pederazza U, Ruegg D, Schmid A, Spichiger UE, Simon W (1994) Anal Chim Acta 289:1–13
Hutchins RS, Molina P, Alajarin M, Vidal A, Bachas LG (1994) Anal Chem 66:3188–3195
Stauthamer WPRV, Engberson JFJ, Verboom W, Reinhoudt DN (1994) Sens Actuators B 17:197–201
Pungor E, Toth K (1985) Anal Proc 22:352–356
Mi Y, Bakker E (1999) Anal Chem 71:5279–5287
Shultz MM, Stefanova OK, Mokrov SB, Mikhelson KN (2002) Anal Chem 74:510–517
Sandblom J, Eisenman G, Walker JL (1967) J Phys Chem 71:3862–3866
Armstrong RP, Horvai G (1990) Electrochim Acta 35:1–7
Umezawa Y, Umezawa K, Sato H (1995) Pure Appl Chem 67:507–518
Bakker E (1997) Electroanalysis 9:7–12
Demirel A, Dogan A, Canel E, Memon S, Yilmaz M, Kilic E (2004) Talanta 62:123–129
Dinten O, Spichiger UE, Chaniotakis N, Gehrig P, Rusterholz B, Morf WE, Simon W (1991) Anal Chem 63:596–599
Wang E, Chen H, Patel H, Sadaragani I, Romero C (1999) Anal Chim Acta 397:287–294
Wardak C, Marczewska B, Lenik J (2006) Electrochim Acta 51:2267–2272
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B.G. gratefully acknowledges the Ministry of Human Resource Development (MHRD), New Delhi, India, for financial support.
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Gupta, V.K., Singh, A.K. & Gupta, B. Electroanalytical performance of a terbium(III)-selective sensor based on a neutral ionophore in environmental and medicinal samples. Anal Bioanal Chem 390, 2171–2181 (2008). https://doi.org/10.1007/s00216-008-1936-9
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DOI: https://doi.org/10.1007/s00216-008-1936-9