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Cation identity dependence of crown ether photonic crystal Pb2+ sensing

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Abstract

We quantitatively modeled the volume phase transition of a hydrogel containing a crystalline colloidal array with a crown ether ligand which binds Pb2+. The hydrogel volume response and the wavelength diffracted depend on the Pb2+ concentration and on both the ionic strength and the valence of the nonbinding ionic species. We successfully modeled the response of this hydrogel Pb2+ sensor to ionic strength and the cation valence of the added salts.

Cation identity dependence of crown ether photonic crystal Pb+ sensing

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References

  1. Flory PJ (1953) Principles of polymer chemistry. Cornell University Press, Ithaca, NY

  2. Dumitriu S (2002) Polymeric biomaterials, 2nd edn. Marcel Dekker, New York

  3. Andrade JD (1976) Hydrogels for medical and related applications. American Chemical Society, Washington DC

  4. DeRossi D, Kajiwara K, Osada Y, Yamauchi A (1991) Polymer gels: fundamentals and biomedical applications. Plenum, New York

  5. Ottenbrite RM, Huang SJ, Park K (1996) Hydrogels and biodegradable polymers for bioapplications. American Chemical Society, Washington DC

  6. Peppas NA (1987) Hydrogels in medicine and pharmacy. CRC Press, Boca Raton, FL

  7. Peppas NA (1991) J Bioact Compat Polym 6:241

    CAS  Google Scholar 

  8. Park K, Shalaby SWS, Park H (1993) Biodegradable hydrogels for drug delivery. Technomic, Lancaster, PA

  9. Weiss RG, Terech P (2006) Molecular gels: materials with self-assembled fibrillar networks. Springer, Berlin, Heidelberg, New York

  10. Annaka M, Tanaka T (1992) Nature 355:430

    Article  CAS  Google Scholar 

  11. Mafe S, Manzanares JA, English AE, Tanaka T (1997) Phys Rev Lett 79:3086

    Article  CAS  Google Scholar 

  12. English AE, Tanaka T, Edelman ER (1997) J Chem Phys 107:1645

    Article  CAS  Google Scholar 

  13. English AE, Tanaka T, Edelman ER (1998) Polymer 39:5893

    Google Scholar 

  14. Ricka J, Tanaka T (1984) Macromolecules 17:2916

    Article  CAS  Google Scholar 

  15. Hirokawa Y, Tanaka T, Sato E (1985) Macromolecules 18:2782

    Article  CAS  Google Scholar 

  16. Kudaibergenov SE, Sigitov VB (1999) Langmuir 15:4230

    Google Scholar 

  17. Kim JJ, Park K (1999) Bioseparation 7:177

    Article  CAS  Google Scholar 

  18. Hassan CM, Doyle FJ III, Peppas NA (1997) Macromolecules 30:6166

    Article  CAS  Google Scholar 

  19. Park K (1997) Controlled drug delivery. American Chemical Society, Washington DC

    Google Scholar 

  20. Lee KY, Moony DJ (2001) Chem Rev 101:1869

  21. Miyata T, Uragami T, Nakamae K (2002) Adv Drug Delivery Rev 54:79

    Google Scholar 

  22. Holtz JH, Asher SA (1997) Nature 389:829

    Article  CAS  Google Scholar 

  23. Holtz JH, Janet SWH, Munro CH, Asher SA (1998) Anal Chem 70:780

    Article  CAS  Google Scholar 

  24. Asher SA, Peteu SF, Reese CE, Lin MX, Finegold DN (2002) Anal Bioanal Chem 373:632

    Article  CAS  Google Scholar 

  25. Walker JP, Asher SA (2005) Anal Chem 77:1596

    Article  CAS  Google Scholar 

  26. Reese CE, Asher SA (2003) Anal Chem 75:391

    Article  CAS  Google Scholar 

  27. Goponenko AV, Asher SA (2005) J Am Chem Soc 127:10753

    Article  CAS  Google Scholar 

  28. Reese CE, Baltusavich ME, Keim JP, Asher SA (2001) Anal Chem 73:5038

    Article  CAS  Google Scholar 

  29. Asher SA, Sharma AC, Goponenko AV, Ward MM (2003) Anal Chem 75:1676

    Article  CAS  Google Scholar 

  30. Lee K, Asher SA (2000) J Am Chem Soc 122:9534

    Article  CAS  Google Scholar 

  31. Alexeev VL, Sharma AC Goponenko AV, Das S, Lednev IK, Wilcox CS, Finegold DN, Asher SA (2003) Anal Chem 75:2316

    Article  CAS  Google Scholar 

  32. Asher SA, Alexeev VL, Goponenko AV, Sharma AC, Lednev IK, Wilcox CS, Finegold DN (2003) J Am Chem Soc 125:3322

    Article  CAS  Google Scholar 

  33. Reese CE, Guerrero CD, Weissman JM, Lee K, Asher SA (2000) J Colloid Interf Sci 232:76

    Google Scholar 

  34. Mark JE, Erman B (1988) Rubberlike elasticity, a molecular primer. Wiley, New York

  35. James HM, Guth E (1942) Ind Eng Chem 34:1365

    Article  CAS  Google Scholar 

  36. James HM (1947) J Chem Phys 15:651

    Article  CAS  Google Scholar 

  37. James HM, Guth E (1947) J Chem Phys 15:669

    Article  CAS  Google Scholar 

  38. Flory PJ (1950) J Chem Phys 18:108

    Article  CAS  Google Scholar 

  39. Wall FT, Flory PJ (1951) J Chem Phys 19:1435

    Article  CAS  Google Scholar 

  40. Asher SA, Flaugh PL, Washinger G (1986) Spectroscopy 1:26

    CAS  Google Scholar 

  41. Carlson RJ, Asher SA (1984) Appl Spectrosc 38:297

    Article  CAS  Google Scholar 

  42. Asher SA, Holtz JH, Liu L, Wu Z (1994) J Am Chem Soc 116:4997

    Article  CAS  Google Scholar 

  43. Weissamn JM, Sunkara HB, Tse AS, Asher SA (1996) Science 274:959

    Article  Google Scholar 

  44. Pan G, Sood AK, Asher SA (1988) J Appl Phys 84:83

    Article  Google Scholar 

  45. Okubo T (1988) Acc Chem Res 21:281

    Article  CAS  Google Scholar 

  46. Izatt RM, Terry RE, Nelson DP, Chan Y, Eatough DJ, Bradshaw JS, Hansen LD, Christensen JJ (1976) J Am Chem Soc 98:7626

    Article  CAS  Google Scholar 

  47. Izatt RM, Terry RE, Haymore BL, Hansen LD, Dalley NK, Ayondet AG, Christensen JJ (1976) J Am Chem Soc 98:7620

    Article  CAS  Google Scholar 

  48. Manege LC, Takayanagi T, Oshima M, Iwachido T, Motomizu S (1999) Bull Chem Soc Jpn 72:1301

    Article  CAS  Google Scholar 

  49. Goldcamp MJ, Ashley K, Edison SE, Pretty J, Shumaker J (2005) Electroanalysis 17:1015

    Article  CAS  Google Scholar 

  50. Lewis GN, Randall M (1921) J Am Chem Soc 43:1112

    Article  CAS  Google Scholar 

  51. Pitzer KS (1984) J Chem Educ 61:104

    Article  CAS  Google Scholar 

Download references

Acknowledgement

We gratefully acknowledge financial support from NIH Grant EB004132. We are grateful to Dr Matti Ben-Moshe, who supplied us with his colloid.

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Authors and Affiliations

  1. Department of Chemistry, Chevron Science Center, University of Pittsburgh, Pittsburgh, PA, 15260, USA

    Fangyong Yan & Sanford Asher

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  1. Fangyong Yan
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  2. Sanford Asher
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Correspondence to Sanford Asher.

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Yan, F., Asher, S. Cation identity dependence of crown ether photonic crystal Pb2+ sensing. Anal Bioanal Chem 387, 2121–2130 (2007). https://doi.org/10.1007/s00216-006-1088-8

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