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Recent methods for the determination of peroxide-based explosives

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Abstract

In the last few years, the need to determine peroxide-based explosives in solid samples and air samples has resulted in the development of a series of new analytical methods for triacetonetriperoxide (TATP, acetone peroxide) and hexamethylenetriperoxidediamine (HMTD). In this review, after a short introduction describing the state of the art in the field, these new analytical methods are critically discussed. Particular emphasis is placed on spectroscopic and mass spectrometric methods as well as on chromatographic techniques with selective detection schemes. The potential of these methods to analyse unknown solid samples that might contain one or more of the explosives and to analyse peroxide-based explosives in air is evaluated.

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References

  1. Legler L (1881) Chem Ber 14:602–604

    Google Scholar 

  2. Bayer A, Villiger V (1900) Chem Ber 33:2479

    Article  Google Scholar 

  3. Schaefer WP, Fourkas JT, Tiemann BG (1985) J Am Chem Soc 107:2461–2463

    Article  CAS  Google Scholar 

  4. Wolffenstein R (1895) Chem Ber 28:2265–2269

    CAS  Google Scholar 

  5. Groth P (1969) Acta Chem Scand 23:1311–1329

    Article  CAS  Google Scholar 

  6. Bayer A, Villiger V (1900) Chem Ber 33:858–860

    Google Scholar 

  7. Jiang H, Chu G, Gong H, Qiao QD (1999) J Chem Res 4:288–289

    Article  Google Scholar 

  8. Denekamp C, Gottlieb L, Tamiri T, Tsoglin A, Shilav R, Kapon M (2005) Org Lett 7:2461–2464

    Article  CAS  Google Scholar 

  9. Dubnikova F, Kosloff R, Almog J, Zeiri Y, Boese R, Itzhaky H, Alt A, Keinan E (2005) J Am Chem Soc 127:1146–1159

    Article  CAS  Google Scholar 

  10. Yinon J, Zitrin S (1993) Modern methods and applications in the analysis of explosives. Wiley, Chichester

  11. Bellamy AJ (1999) J Forensic Sci 44:603–608

    CAS  Google Scholar 

  12. Koehler J, Meyer R (1991) Explosivstoffe. VCH, Weinheim

  13. Reutter DJ, Bender EC, Rudolph TL (1983) Proc 1st Int Symp on the Analysis and and Detection of Explosives, 29–31 March 1983, FBI Academy, Quantico, VA, USA, pp 149–158

  14. Cooper RT (2001) Los Angeles Times, 29 Dec, A12

  15. White GM (1992) J Forensic Sci 37:652–656

    Google Scholar 

  16. Evans HK, Tullerners FAJ, Sanchez BL, Rasmussen CA (1986) J Forensic Sci 31:1119–1125

    CAS  Google Scholar 

  17. Schoon A, Götz S, Heuven M, Vogel M, Karst U (2006) Forensic Sci Commun (accepted)

  18. Zitrin S, Kraus S, Glattstein B (1983) Proc 1st Int Symp on the Analysis and and Detection of Explosives, 29–31 March 1983, FBI Academy, Quantico, VA, USA, pp 137–141

  19. Sulzle D, Klaeboe P (1988) Acta Chem Scand A 42:165–170

    Google Scholar 

  20. Oxley J, Zhang J, Smith J, Cioffi E (2000) Propell Explos Pyrot 25:284–287

    Article  CAS  Google Scholar 

  21. Wierzbicki A, Salter EA, Cioffi EA, Stevens ED (2001) J Phys Chem A 105:8763–8768

    Article  CAS  Google Scholar 

  22. Wierzbicki A, Cioffi E (1999) J Phys Chem A 103:8890–8894

    Article  CAS  Google Scholar 

  23. Primera OM, Pacheco L, De la Torre LF, Hernandez SP, Chamberlain RT, Lareau RT (2004) Abstr Paper Am Chem Soc 227:U320-PHYS

    Google Scholar 

  24. Lazrus AL, Kok GL, Gitlin SN, Lind JA, McLaren SE (1985) Anal Chem 57:917–922

    Article  CAS  Google Scholar 

  25. Gallati H, Brodbeck H (1989) Clin Chem Clin Biochem 20:221–225

    Google Scholar 

  26. Tarcha PJ, Chu VP, Whittern D (1987) Anal Biochem 165:230–233

    Article  CAS  Google Scholar 

  27. Mäkinen KK, Tenovuo J (1982) Anal Biochem 126:100–108

    Article  Google Scholar 

  28. Guilbault GG, Brignac PJ, Juneau M (1968) Anal Chem 40:1256–1263

    Article  CAS  Google Scholar 

  29. Meyer J, Büldt A, Vogel M, Karst U (2000) Angew Chem Int Ed Engl 39:1453–1455

    Article  CAS  Google Scholar 

  30. Effkemann S, Pinkernell U, Neumüller R, Schwan F, Engelhardt H, Karst U (1998) Anal Chem 70:3857–3862

    Article  CAS  Google Scholar 

  31. Wang KX, Glaze WH (1998) J Chromatogr A 822:207–213

    Article  CAS  Google Scholar 

  32. Hong JG, Maguhn J, Freitag D, Kettrup A (1998) Fresenius J Anal Chem 361:124–128

    Article  CAS  Google Scholar 

  33. Schulte-Ladbeck R, Kolla P, Karst U (2002) Analyst 127:1152–1154

    Article  CAS  Google Scholar 

  34. Itzhaky H, Keinan E (2004) United States Patent, US 6,767,717 B1

  35. Todd MW, Provencal RA, Owano TG, Paldus BA, Kachanov A, Vodopyanov KL, Hunter M, Coy SL, Steinfeld JI, Arnold JT (2002) Appl Phys B 75:367–376

    Article  CAS  Google Scholar 

  36. Ewing RG, Atkinson DA, Eiceman GA, Ewing GJ (2001) Talanta 54:515–529

    Article  CAS  Google Scholar 

  37. Buttigieg GA, Knight AK, Denson S, Pommier C, Bonner Denton M (2003) Forensic Sci Int 135:53–59

    Article  CAS  Google Scholar 

  38. Dubnikova F, Kosloff R, Zeiri Y, Karpas Z (2002) J Phys Chem A 106:4951–4956

    Article  CAS  Google Scholar 

  39. Wilson PF, Prince BJ, McEwan MJ (2006) Anal Chem 78:575–579

    Article  CAS  Google Scholar 

  40. Cotte-Rodriguez I, Chen H, Cooks RG (2006) Chem Comm 953–955

  41. Takats Z, Wiseman JM, Gologan B, Cooks RG (2004) Science 306:471–473

    Article  CAS  Google Scholar 

  42. Muller D, Levy A, Shelef R, Abramovich-Bar S, Sonenfeld D, Tamiri J (2004) Forensic Sci 49:935–938

    CAS  Google Scholar 

  43. Crowson A, Beardah MS (2001) Analyst 126:1689–1693

    Article  CAS  Google Scholar 

  44. Widmer L, Watson S, Schlatter K, Crowson A (2002) Analyst 127:1627–1632

    Article  CAS  Google Scholar 

  45. Schulte-Ladbeck R, Kolla P, Karst U (2003) Anal Chem 75:731–735

    Article  CAS  Google Scholar 

  46. Schulte-Ladbeck R, Karst U (2003) Anal Chim Acta 482:183–188

    Article  CAS  Google Scholar 

  47. Oxley JC, Smith JL, Shinde K, Moran J (2005) Propell Explos Pyrot 30:127–130

    Article  CAS  Google Scholar 

  48. Schulte-Ladbeck R, Karst U (2003) Chromatographia 57:S61–S65

    Article  Google Scholar 

  49. Xu X, van de Craats AM, Kok EM, de Bruyn PCAM (2004) J Forensic Sci 49:1230–1236

    CAS  Google Scholar 

Download references

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Correspondence to Martin Vogel.

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Schulte-Ladbeck, R., Vogel, M. & Karst, U. Recent methods for the determination of peroxide-based explosives. Anal Bioanal Chem 386, 559–565 (2006). https://doi.org/10.1007/s00216-006-0579-y

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  • DOI: https://doi.org/10.1007/s00216-006-0579-y

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