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Effects of the physicochemical properties of different nanoparticles on lubrication performance and experimental evaluation in the NMQL milling of Ti–6Al–4V

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Abstract

Processing of Ti alloy is often accompanied with large frictions and high temperature. Nanofluids prepared by adding nanoparticles show good lubrication performance due to the excellent antifriction and antiwear of nanoparticles. The physicochemical properties of nanoparticles are important factors that influence the lubrication performance of nanofluid minimum quantity lubrication (NMQL). An experimental study on Ti alloy (Ti–6Al–4V) milling was conducted to explore the lubrication performance of minimum quantity lubrication (MQL) using different nanofluids. Cottonseed oil was used as the base oil, and the tribological properties of several typical nanoparticles (i.e., Al2O3, MoS2, SiO2, carbon nanotubes, SiC, graphite) were studied. The lubrication performance was evaluated by milling parameters, including milling force, surface roughness (Ra, RSm, Rmr), friction coefficient, microstructures of debris and workpiece surface, and energy spectra of the workpiece surface. Results demonstrated that the milling process based on Al2O3 nanofluid achieved the minimum milling force and friction coefficient, whereas the milling process based on SiO2 nanofluid had the minimum surface roughness value (Ra). Furthermore, the physicochemical properties of nanoparticles and the viscosity of nanofluid were analyzed. Spherical Al2O3 and SiO2 nanoparticles improved the lubrication effect of base oil mostly. The Al2O3 nanoparticles exhibited high hardness, which was conducive to reducing milling force. SiO2 nanofluid demonstrated high viscosity, which could improve workpiece surface quality.

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References

  1. Du SG, Lv C, Ren JX, Yang ZC (2008) Surface morphology and surface tissue study of titanium alloy TC4 high speed milling. Acta Aeronaut Astronaut Sin 29:1710–1715

    Google Scholar 

  2. Ulutan D, Ozel T (2011) Machining induced surface integrity in titanium and nickel alloys: a review. Int J Mach Tools Manuf 51:250–280

    Article  Google Scholar 

  3. Deng ZH, Zhang H, Fu YH, Wan LL, Lv LS (2018) Research on intelligent expert system of green cutting process and its application. J Clean Prod 185:904–911

    Article  Google Scholar 

  4. Zhang JC, Li CH, Zhang YB, Yang M, Jia DZ, Hou YL, Li RZ (2018) Temperature field model and experimental verification on cryogenic air nanofluid minimum quantity lubrication grinding. Int J Adv Manuf Technol 97:209–228

    Article  Google Scholar 

  5. Jia DZ, Li CH, Zhang YB, Yang M, Wang YG, Guo SM, Cao HJ (2017) Specific energy and surface roughness of minimum quantity lubrication grinding Ni-based alloy with mixed vegetable oil-based nanofluids. Precis Eng 50:248–262

    Article  Google Scholar 

  6. Mao C, Sun XL, Huang H, Kang CW, Zhang MJ, Wu YQ (2016) Characteristics and removal mechanism in laser cutting of cBN-WC-10Co composites. J Mater Process Technol 230:42–49

    Article  Google Scholar 

  7. Mao C, Zhang MJ, Zhang J, Tang K, Gan HY, Zhang GF (2015) The effect of processing parameters on the performance of spark plasma sintered CBN-WC-Co composites. J Mater Eng Perform 24:4612–4619

    Article  Google Scholar 

  8. Li BK, Li CH, Zhang YB, Wang YG, Jia DZ, Yang M, Zhang NQ, Wu QD, Han ZG, Sun K (2017) Heat transfer performance of MQL grinding with different nanofluids for Ni-based alloys using vegetable oil. J Clean Prod 154:1–11

    Article  Google Scholar 

  9. Hamdan A, Sarhan AAD, Hamdi M (2012) An optimization method of the machining parameters in high-speed machining of stainless steel using coated carbide tool for best surface finish. Int J Adv Manuf Technol 58:81–91

    Article  Google Scholar 

  10. Zhang YB, Li CH, Jia DZ, Zhang DK, Zhang XW (2015) Experimental evaluation of the lubrication performance of MoS2/CNT nanofluid for minimal quantity lubrication in Ni-based alloy grinding. Int J Mach Tools Manuf 99:19–33

    Article  Google Scholar 

  11. Zhang YB, Li CH, Jia DZ, Zhang DK, Zhang XW (2015) Experimental evaluation of MoS2 nanoparticles in jet MQL grinding with different types of vegetable oil as base oil. J Clean Prod 871:930–940

    Article  Google Scholar 

  12. Li CH, Hou YL, Xiu SC, Cai GQ (2008) Application of lubrication theory to near-dry-green grinding-feasibility analysis. Adv Mater Res 44-46:135–142

    Article  Google Scholar 

  13. Li CH, Li JY, Wang S, Jia DZ (2013) Modeling and numerical simulation of the grinding temperature distribution with nano-particle jet of MQL. Adv in. Mech Eng 7:167–181

    Google Scholar 

  14. Li BK, Li CH, Zhang YB, Wang YG, Yang M, Jia DZ, Zhang NQ, Wu QD, Ding WF (2017) Numerical and experimental research on the grinding temperature of minimum quantity lubrication cooling of different workpiece materials using vegetable oil-based nanofluids. Int J Adv Manuf Technol 93:1971–1988

    Article  Google Scholar 

  15. Han ZL, Li CH (2010) The application of cutting fluid in grinding process is reviewed. Abras Abras Commun 10:7–12

    Google Scholar 

  16. Yang M, Li CH, Zhang YB, Jia DZ, Zhang XP, Hou YL, Li RZ, Wang J (2017) Maximum undeformed equivalent chip thickness for ductile-brittle transition of zirconia ceramics under different lubrication conditions. Int J Mach Tools Manuf 122:55–65

    Article  Google Scholar 

  17. Zhang DK, Li CH, Zhang YB, Zhou DZ (2015) Zhang XW. Experimental research on the energy ratio coefficient and specific grinding energy in nanoparticle jet MQL grinding. Int J Adv Manuf Technol 78:1275–1288

    Article  Google Scholar 

  18. Ding WF, Zhang LC, Li Z, Zhu YJ, Su HH, Xu JH (2017) Review on grinding-induced residual stresses in metallic materials. Int J Adv Manuf Technol 88:2939–2968

    Article  Google Scholar 

  19. Ding WF, Barbara L, Zhu YJ, Li Z, Fu YC, Su HH, Xu JH (2017) Review on monolayer CBN superabrasive wheels for grinding metallic materials. Chin J Aeronaut 30:109–134

    Article  Google Scholar 

  20. Mao C, Tang XJ, Zou HF, Huang XM, Zhou ZX (2012) Investigation of grinding characteristic using nanofluid minimum quantity lubrication. Int J Precis Eng Manuf 13:1745–1752

    Article  Google Scholar 

  21. Mao C, Zhou X, Yin LR, Zhang MJ, Tang K, Zhang J (2016) Investigation of the flow field for a double-outlet nozzle during minimum quantity lubrication grinding. Int J Adv Manuf Technol 85:291–298

    Article  Google Scholar 

  22. Mao C, Ren YH, Gan HY, Zhang MJ, Zhang J, Tang K (2015) Microstructure and mechanical properties of CBN-WC-Co composites used for cutting tools. Int J Adv Manuf Technol 76:2043–2049

    Article  Google Scholar 

  23. Wang YG, Li CH, Zhang YB, Yang M, Li BK, Jia DZ, Hou YL, Mao C (2016) Experimental evaluation of the lubrication properties of the wheel/workpiece interface in minimum quantity lubrication (MQL) grinding using different types of vegetable oils. J Clean Prod 127:487–499

    Article  Google Scholar 

  24. Li BK, Li CH, Zhang YB, Wang YG, Yang M, Jia DZ, Zhang NQ, Wu QD (2017) Effect of the physical properties of different vegetable oil-based nanofluids on MQLC grinding temperature of Ni-based alloy. Int J Adv Manuf Technol 89:3459–3474

    Article  Google Scholar 

  25. Li BK, Li CH, Zhang YB, Wang YG, Jia DZ, Yang M (2016) Grinding temperature and energy ratio coefficient in MQL grinding of high-temperature nickel-base alloy by using different vegetable oils as base oil. Chin J Aeronaut 29:1084–1095

    Article  Google Scholar 

  26. Zhang YB, Li CH, Ji HJ, Yang XH, Yang M, Jia DZ, Zhang XP, Li RZ, Wang J (2017) Analysis of grinding mechanics and improved predictive force model based on material-removal and plastic-stacking mechanisms. Int J Mach Tools Manuf 122:81–97

    Article  Google Scholar 

  27. Hadi M, Atefi R (2015) Effect of minimum quantity lubrication with gamma-Al2O3 nanoparticles on surface roughness in milling AISID3 steel. Ind J Sci Technol 8:296–300

    Article  Google Scholar 

  28. Shen B, Shih AJ, Tung SC (2008) Application of nanofluids in minimum quantity lubrication grinding. Tribol T 51:730–737

    Article  Google Scholar 

  29. Mao C, Zou HF, Huang XM, Zhang JA Zhou ZX (2013) The influence of spraying parameters on grinding performance for nanofluid minimum quantity lubrication. Int J Adv Manuf Technol 64:1791–1799

    Article  Google Scholar 

  30. Yin QA, Li CH, Zhang YB, Yang M, Jia DZ, Hou YL, Li RZ, Dong L (2018) Spectral analysis and power spectral density evaluation in Al2O3 nanofluid minimum quantity lubrication milling of 45 steel. Int J Adv Manuf Technol 97:129–145

    Article  Google Scholar 

  31. Shen B, Kalita P, Malshe AP, Shih A (2008) Performance of novel MoS2 nanoparticles based grinding fluids in minimum quantity lubrication grinding. Trans NAMRI/SME 36:357–364

    Google Scholar 

  32. Kalita P, Malshe AP, Kumar SA, Yoganath VG, Gurumurthy T (2012) Study of specific energy and friction coefficient in minimum quantity lubrication grinding using oil-based nanolubricants. J Manuf Process 14:160–166

    Article  Google Scholar 

  33. Rahmati B, Sarhan AAD, Sayuti M (2014) Morphology of surface generated by end milling AL6061-T6 using molybdenum disulfide (MoS2) nanolubrication in end milling machining. J Clean Prod 66:685–691

    Article  Google Scholar 

  34. Rahmati B, Sarhan AAD, Sayuti M (2014) Investigating the optimum molybdenum disulfide (MoS2) nanolubrication parameters in CNC milling of AL6061-T6 alloy. Int J Adv Manuf Technol 70:1143–1155

    Article  Google Scholar 

  35. Uysal A, Demiren F, Altan E (2015) Applying minimum quantity lubrication (MQL) method on milling of martensitic stainless steel by using nano MoS2 reinforced vegetable cutting fluid. Procedia Soc Behav Sci 195:2742–2747

    Article  Google Scholar 

  36. Dilbag S, Rao PV (2008) Performance improvement of hard turning with solid lubricants. Int J Adv Manuf Technol 38:529–535

    Article  Google Scholar 

  37. Ming EO, Sayuti M, Sarhan AAD (2015) Fuzzy logic-based approach to investigate the novel uses of nano suspended lubrication in precise machining of aerospace AL tempered grade 6061. J Clean Prod 89:286–295

    Article  Google Scholar 

  38. Sayuti M, Erh OM, Sarhan AAD, Hamdi M (2014) Investigation on the morphology of the machined surface in end milling of aerospace AL6061-T6 for novel uses of SiO2 nanolubrication system. J Clean Prod 66:655–663

    Article  Google Scholar 

  39. Sayuti M, Sarhan AAD, Hamdi M (2013) An investigation of optimum SiO2 nanolubrication parameters in end milling of aerospace Al6061-T6 alloy. Int J Adv Manuf Technol 67:833–849

    Article  Google Scholar 

  40. Peng DX, Kang Y, Hwang RM, Shyr SS, Chang YP (2009) Tribological properties of diamond and SiO2 nanoparticles added in paraffin. Tribol Int 42:911–917

    Article  Google Scholar 

  41. Sarhan AAD, Sayuti M, Hamdi M (2012) Reduction of power and lubricant oil consumption in milling process using a new SiO2 nanolubrication system. Int J Adv Manuf Technol 63:505–512

    Article  Google Scholar 

  42. Haddad Z, Abid C, Oztop HF, Mataoui A (2014) A review on how the researchers prepare their nanofluids. Int J Therm Sci 76:168–189

    Article  Google Scholar 

  43. Zhang DK, Li CH, Jia DZ, Zhang YB, Zhang XP (2015) Specific grinding energy and surface roughness of nanoparticle jet minimum quantity lubrication in grinding. Chin J Aeronaut 28:570–581

    Article  Google Scholar 

  44. Wang LJ, Guo CW, Ryuichiro Y, Wu Y (2009) Tribological properties of Mn–Zn–Fe magnetic fluids under magnetic field. Tribol Int 42:792–797

    Article  Google Scholar 

  45. Zhang XP, Li CH, Zhang YB, Jia DZ, Li BK, Wang YG, Yang M, Hou YL, Zhang XW (2016) Performances of Al2O3/SiC hybrid nanofluids in minimum-quantity lubrication grinding. Int J Adv Manuf Technol 86(1–15):3427–3441

    Article  Google Scholar 

  46. Zhang XP, Li CH, Zhang YB, Wang YG, Li BK, Yang M, Guo SM, Liu GT, Zhang NQ (2016) Lubricating property of MQL grinding of Al2O3/SiC mixed nanofluid with different particle sizes and microtopography analysis by cross-correlation. Precis Eng 47:532–545

    Article  Google Scholar 

  47. Lee CG, Hwang YJ, Choi YM, Lee JK, Choi C, Oh JM (2009) A study on the tribological characteristics of graphite nano lubricants. Int J Precis Eng Manuf 10:85–90

    Article  Google Scholar 

  48. Alberts M, Kalaitzidou K, Melkote S (2009) An investigation of graphite nanoplatelets as lubricant in grinding. Int J Mach Tools Manuf 49:966–970

    Article  Google Scholar 

  49. Huang HD, Tu JP, Gan LP, Li CZ (2006) An investigation on tribological properties of graphite nanosheets as oil additive. Wear 261:140–144

    Article  Google Scholar 

  50. Shaji S, Radhakrishnan V (2003) Application of solid lubricants in grinding: investigations on graphite sandwiched grinding wheels. Mach Sci Technol 7:137–155

    Article  Google Scholar 

  51. Shaji S, Radhakrishnan V (2003) Analysis of process parameters in surface grinding with graphite as lubricant based on the Taguchi method. J Mater Process Technol 141:51–59

    Article  Google Scholar 

  52. Wang YG, Li CH, Zhang YB, Yang M, Li BK, Jia DZ, Hou YL, Mao C (2016) Experimental evaluation of the lubrication properties of the wheel/workpiece interface in minimum quantity lubrication (MQL) grinding using different types of vegetable oils. Tribol Int 127:487–499

    Google Scholar 

  53. Miguélez MH, Soldani X, Molinari A (2013) Analysis of adiabatic shear banding in orthogonal cutting of Ti alloy. Int J Mech Sci 75:212–222

    Article  Google Scholar 

  54. Junior ASA, Sales WF, Silva RBD, Costa ES, Machado AR (2017) Lubri-cooling and tribological behavior of vegetable oils during milling of AISI 1045 steel focusing on sustainable manufacturing. J Clean Prod 156:635–647

    Article  Google Scholar 

  55. Wang YG, Li CH, Zhang YB, Yang M, Zhang XP, Zhang NQ, Dai JJ (2017) Experimental evaluation on tribological performance of the wheel/workpiece interface in minimum quantity lubrication grinding with different concentrations of Al2O3 nanofluids. J Clean Prod 142:3571–3583

    Article  Google Scholar 

  56. Feng J (2009) Study on mechanism of Ti6Al4V high speed machining under different cooling lubrication conditions. Shan Dong University, Jinan, pp 35–38

    Google Scholar 

  57. Liu GT, Li CH, Zhang YB, Yang M, Jia DZ, Zhang XP, Guo SM, Li RZ, Zhai H (2018) Process parameters optimization and experimental evaluation for nanofluid MQL in grinding Ti-6Al-4V based on grey relational analysis. Mater Manuf Process 33:950–963

    Article  Google Scholar 

  58. Xu D, Feng P, Li W, Ma Y, Liu B (2014) Research on chip formation parameters of aluminum alloy 6061-T6 based on high-speed orthogonal cutting model. Int J Adv Manuf Technol 72:955–962

    Article  Google Scholar 

  59. Sun J, Guo YB (2008) A new multi-view approach to characterize 3D chip morphology and properties in end milling titanium Ti-6Al-4V. Int J Mach Tools Manuf 48:1486–1494

    Article  Google Scholar 

  60. Velasquez JDP, Bolle B, Chevrier P, Geandier G, Tidu A (2007) Metallurgical study on chips obtained by high speed machining of a Ti-6 wt.%Al-4 wt.%V alloy. Mater Sci Eng A 452:469–474

    Article  Google Scholar 

  61. Ge X, Xia Y, Cao Z (2015) Tribological properties and insulation effect of nanometer TiO2 and nanometer SiO2 as additives in grease. Tribol Int 92:454–461

    Article  Google Scholar 

  62. Jia DZ, Li CH, Zhang DK, Wang S, Hou YL (2014) Investigation into the formation mechanism and distribution characteristics of suspended microparticles in MQL grinding. Recent Pat Mech Eng 7:52–62

    Article  Google Scholar 

  63. Tao X, Jia ZZ, Kang X (1996) The ball-bearing effect of diamond nanoparticles as an oil additive. J Phys D Appl Phys 29:2932–2937

    Article  Google Scholar 

  64. Rapoport L, Leshchinsky V, Lvovsky M, Nepomnyashchy O, Volovik Y, Tenne R (2002) Mechanism of friction of fullerenes. Ind Lubr Tribol 54:171–176

    Article  Google Scholar 

  65. Rapoport L, Leshchinsky V, Lvovsky M, Lapsker I, Volovik Y, Feldman Y, Popovitz-Biro R, Tenne R (2003) Superior tribological properties of powder materials with solid lubricant nanoparticles. Wear 255:794–800

    Article  Google Scholar 

  66. Kao MJ, Lin CR (2009) Evaluating the role of spherical titanium oxide nanoparticles in reducing friction between two pieces of cast iron. J Alloys Compd 483:456–459

    Article  Google Scholar 

  67. Rahim EA, Sasahara H (2011) A study of the effect of palm oil as MQL lubricant on high speed drilling of titanium alloys. Tribol Int 44:309–317

    Article  Google Scholar 

  68. Wang YG (2016) Tribological performance and experimental study of the wheel/workpiece interface in MQL grinding using nanofluids. Qingdao University of Technology, Qingdao

    Google Scholar 

  69. Zhang YB, Li CH, Jia DZ, Li BK, Wang YG, Yang M, Hou YL, Zhang XW (2016) Experimental study on the effect of nanoparticle concentration on the lubricating property of nanofluids for MQL grinding of Ni-based alloy. J Mater Process Technol 232:100–115

    Article  Google Scholar 

  70. Kalin M, Kogovšek J, Remškar M (2012) Mechanisms and improvements in the friction and wear behavior using MoS2 nanotubes as potential oil additives. Wear 280:36–45

    Article  Google Scholar 

  71. Yu HL, Xu Y, Shi PJ, Wang HM, Wei M, Zhao KK, Xu BS (2013) Microstructure, mechanical properties and tribological behavior of tribofilm generated from natural serpentine mineral powders as lubricant additive. Wear 297:802–810

    Article  Google Scholar 

  72. Wang YG, Li CH, Zhang YB, Li BK, Yang M, Zhang XP, Guo SM, Liu GT (2016) Experimental evaluation of the lubrication properties of the wheel/workpiece interface in MQL grinding with different nanofluids. Tribol Int 99:198–210

    Article  Google Scholar 

  73. Sridharan U, Malkin S (2009) Effect of minimum quantity lubrication (MQL) with nanofluid on grinding behavior and thermal distortion. Trans NAMRI/SME 37:629–636

    Google Scholar 

  74. Shen B, Shih AJ (2009) Minimum quantity lubrication (MQL) grinding using vitrified CBN wheels. Trans NAMRI/SME 37:129–136

    Google Scholar 

  75. Guo SM, Li CH, Zhang YB, Wang YG, Li BK, Yang M, Zhang XP, Liu GT (2016) Experimental evaluation of the lubrication performance of mixtures of castor oil with other vegetable oils in MQL grinding of nickel-based alloy. J Clean Prod 140:1060–1076

    Article  Google Scholar 

  76. Sia SY, Bassyony EZ, Sarhan AAD (2014) Development of SiO2 nanolubrication system to be used in sliding bearings. Int J Adv Manuf Technol 71:1277–1284

    Article  Google Scholar 

  77. Li CH (2018) Theory and key technology of nanofluid minimum quantity grinding. Science Press, Beijing, pp 199–214

    Google Scholar 

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Funding

This research was financially supported by the following foundation items: The National Natural Science Foundation of China (51575290), Major Research Project of Shandong Province (2017GGX30135 and 2018GGX103044), Shandong Provincial Natural Science Foundation, China (ZR2017PEE002 and ZR2017PEE011), and Scientific Research Development Project of Shandong Higher Education Institutions, China (J17KB016).

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Correspondence to Changhe Li or Yonghong Liu.

Additional information

1. Milling performance of Ti–6Al–4V under different lubricating conditions was studied.

2. The tribological properties of several typical nanoparticles were studied.

3. Physicochemical properties of different nanoparticles were analyzed.

4. Viscosity of different nanofluids was analyzed to validation.

5. The best workpiece surface quality was obtained by SiO2 NMQL.

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Yin, Q., Li, C., Dong, L. et al. Effects of the physicochemical properties of different nanoparticles on lubrication performance and experimental evaluation in the NMQL milling of Ti–6Al–4V. Int J Adv Manuf Technol 99, 3091–3109 (2018). https://doi.org/10.1007/s00170-018-2611-8

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