Skip to main content

Advertisement

Log in

Laser ablation of electrodes for Li-ion battery remanufacturing

  • ORIGINAL ARTICLE
  • Published:
The International Journal of Advanced Manufacturing Technology Aims and scope Submit manuscript

Abstract

Formation of solid electrolyte interface (SEI) on the electric vehicle (EV) battery electrodes has been indicated as major cause of capacity deterioration in the electric vehicle battery. This paper describes process for the removal of SEI deposited on the EV battery electrodes during continuous cycling. Laser fluence ranging from 0.308 to 2.720 J/cm2 was used to irradiate surfaces of degraded battery electrodes to ablate SEI. Ablation of SEI from the surface of electrodes was done to enable recovery of electrodes for EV battery remanufacturing. Analytical tools including scanning electron microscope (SEM), atomic force microscopy (AFM), X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and electrochemical measurements are used to assess structural changes in the recovered electrodes and determine the functionalities. The analysis show promising results for the restoration of cyclability of recovered electrode to new-like condition.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Tasaki K (2005) Solvent decompositions and physical properties of decomposition compounds in Li-ion battery electrolytes studied by DFT calculations and molecular dynamics simulations. J Phys Chem B 109(7):2920–2933

    Article  Google Scholar 

  2. Tasaki K, Goldberg A, Lian JJ, Wlaker M, Timmmons A, Harris SJ (2009) Solubility of lithium salts formed on the lithium-ion battery negative electrode surface in organic solvents. J Electrochem Soc 156(12):A1019–A1027

    Article  Google Scholar 

  3. Winter M (2009) The solid electrolyte interphase—the most important and the least understood solid electrolyte in rechargeable Li batteries. Z Phys Chem 223(10-11):1395–1406

    Article  Google Scholar 

  4. Zhang Y, Wang CY, Tang X (2011) Cycling degradation of an automotive LiFePO4 lithium-ion battery. J Power Sources 196:1513–1520

    Article  Google Scholar 

  5. Marano, V., Onori, S., Guezennec, Y., Rizzoni, G., & Madella, N. (2009). Lithium-ion batteries life estimation for plug-in hybrid electric vehicles. In Vehicle Power and Propulsion Conference, 2009. VPPC’09. IEEE (pp. 536-543). IEEE.

  6. Saxena S, Le Floch C, MacDonald J, Moura S (2015) Quantifying EV battery end-of-life through analysis of travel needs with vehicle powertrain models. J Power Sources 282:265–276

    Article  Google Scholar 

  7. Wolfs, P. (2010). An economic assessment of “second use” lithium-ion batteries for grid support. In Universities Power Engineering Conference (AUPEC), 2010 20th Australasian (pp. 1-6). IEEE.

  8. Nagpure SC, Downing RG, Bhusan B, Babu SS, Cao L (2011) Neutron depth profiling technique for studying aging in Li-ion batteries. Electrochim Acta 56:4735–4743

    Article  Google Scholar 

  9. Ramoni, M., & Zhang, H. C. (2012). Remanufacturing processes of electric vehicle battery. In Sustainable Systems and Technology (ISSST), 2012 I.E. International Symposium on (pp. 1-1). IEEE.

  10. Ramoni MO, Zhang HC (2013) End-of-life (EOL) issues and options for electric vehicle batteries. Clean Techn Environ Policy 15(6):881–891

    Article  Google Scholar 

  11. Sullivan JL, Gaines L (2012) Status of life cycle inventories for batteries. Energy Convers Manag 58:134–148

    Article  Google Scholar 

  12. Zackrisson M, Avellán L, Orlenius J (2010) Life cycle assessment of lithium-ion batteries for plug-in hybrid electric vehicles—critical issues. J Clean Prod 18(15):1519–1529

    Article  Google Scholar 

  13. Abraham DP, Knuth JL, Dees DW, Bloom I, Christophersen JP (2007) Performance degradation of high-power lithium-ion cells—electrochemistry of harvested electrodes. J Power Sources 170(2):465–475

    Article  Google Scholar 

  14. Broussely M, Herreyre S, Biensan P, Kasztejna P, Nechev K, Staniewicz RJ (2001) Aging mechanism in Li ion cells and calendar life predictions. J Power Sources 97:13–21

    Article  Google Scholar 

  15. Harris, Stephen J. (2013) Method and apparatus for rejuvenation of degraded pouch-type lithium ion battery cells. U.S. Patent 8,535,818

  16. Lee JM, Watkins K (2000) Laser removal of oxides and particles from copper surfaces for microelectronic fabrication. Opt Express 7(2):68–76

    Article  Google Scholar 

  17. Furumoto T, Ueda T, Kasai A, Hosokawa A (2011) Surface temperature during cavity preparation on human tooth by Er: YAG laser irradiation. CIRP Ann Manuf Technol 60(1):555–558

    Article  Google Scholar 

  18. Brygo F, Dutouquet C, Le Guern F, Oltra R, Semerok A, Weulersse JM (2006) Laser fluence, repetition rate and pulse duration effects on paint ablation. Appl Surf Sci 252:2131–2138

    Article  Google Scholar 

  19. Krüger J, Pentzien S, Conradi A (2008) Cleaning of artificially soiled paper with 532-nm nanosecond laser radiation. Appl Phys A 92(1):179–183

    Article  Google Scholar 

  20. Bäuerle, D. W. (2013). Laser processing and chemistry. Springer Science & Business Media.

  21. Kurselis K, Kiyan R, Chichkov BN (2012) Formation of corrugated and porous steel surface by femtosecond laser irradiation. Appl Surf Sci 258:8845–8852

    Article  Google Scholar 

  22. Guan YC, Ng GKL, Zheng HY, Hong MH, Hong X, Zhang Z (2013) Laser surface cleaning of carbonaceous deposits on diesel engine piston. App Surf Sci 270:526–530

    Article  Google Scholar 

  23. Song WD, Hong MH, Lu YF, Chong TC (2003) Laser cleaning of printed circuit boards. Appl Surf Sci 208:463–467

    Article  Google Scholar 

  24. Hinoue T, Kuwamoto N, Watanabe I (1999) Voltammetry using an electrode surface continuously renewed by laser ablation and its demonstration on electro-oxidation of L-ascorbic acid. J Electroanal Chem 466(1):31–37

    Article  Google Scholar 

  25. Breannan JL, Foster RJ (2003) Laser light and electrode: interaction mechanisms and electroanalytical application. J Phys Chem 107:9344–9350

    Article  Google Scholar 

  26. Tarascon JM, Armand M (2001) Issues and challenges facing rechargeable lithium batteries. Nature 414(6861):359–367

    Article  Google Scholar 

  27. Pollet BG, Staffell I, Shang JL (2012) Current status of hybrid, battery and fuel cell electric vehicles: from electrochemistry to market prospects. Electrochim Acta 84:235–249

    Article  Google Scholar 

  28. Hu J, Xie J, Zhao X, Yu H, Zhou X, Cao G, Tu J (2009) Doping effects on electronic conductivity and electrochemical performance of LiFePO4. J Mater Sci Technol 25(3):405–409

    Article  Google Scholar 

  29. Gao F, Tang Z (2008) Kinetic behavior of LiFePO 4/C cathode material for lithium-ion batteries. Electrochim Acta 53(15):5071–5075

    Article  Google Scholar 

  30. Wang GX, Needham S, Yao J, Wang JZ, Liu RS, Liu HK (2006) A study on LiFePO 4 and its doped derivatives as cathode materials for lithium-ion batteries. J Power Sources 159(1):282–286

    Article  Google Scholar 

  31. Kurfer J, Westermeier M, Reinhart G (2012) Cell stacking process of high energy lithium-ion cells. In: Proceedings of the 4 th CIRP conference on assembly technologies and systems., pp 20–22

    Google Scholar 

  32. Lee, S. S., Kim, T. H., Hu, S. J., Cai, W. W., & Abell, J. A. (2010). Joining technologies for automotive lithium-ion battery manufacturing: a review. In ASME 2010 International Manufacturing Science and Engineering Conference (pp. 541-549). American Society of Mechanical Engineers.

  33. Kwon K et al (2003) Characterization of the SEI on a carbon film electrode by combined EQCM and spectroscopic ellipsometry. J Electrochem Soc 150(2):A229–A233

    Article  MathSciNet  Google Scholar 

  34. Zhang HL, Li F, Liu C, Tan J, Cheng HM (2005) New insight into the solid electrolyte interphase with use of a focused ion beam. J Phys Chem B 109(47):22205–22211

    Article  Google Scholar 

  35. Dupré N, Cuisinier M, Guyomard D (2011) Electrode/electrolyte interface studies in lithium batteries using NMR. Interface-Electrochem Soc 20(3):61–67

    Google Scholar 

  36. Peled E, BarTow D, Merson A, Gladkich A, Burstein L, Golodnitsky D (2001) Composition, depth profiles and lateral distribution of materials in the SEI built on HOPG-TOF SIMS and XPS studies. J Power Sources 97:52–57

    Article  Google Scholar 

  37. Kolar J, Strlič M, Müller-Hess D, Gruber A, Troschke K, Pentzien S, Kautek W (2003) Laser cleaning of paper using Nd: YAG laser running at 532 nm. J Cult Herit 4:185–187

    Article  Google Scholar 

  38. Trtica MS, Tarasenko VF, Gaković BM, Fedenev AV, Petkovska LT, Radak BB, Shulepov MA (2005) Surface modifications of TiN coating by pulsed TEA CO 2 and XeCl lasers. Appl Surf Sci 252(2):474–482

    Article  Google Scholar 

  39. Byskov-Nielsen, J. (2010). Short-pulse laser ablation of metals: Fundamentals and applications for micro-mechanical interlocking, Dissertation, University of Aarhus

  40. Yazami R, Reynier YF (2002) Mechanism of self-discharge in graphite–lithium anode. Electrochim Acta 47(8):1217–1223

    Article  Google Scholar 

  41. Swiatowska J, Lair V, Pereira-Nabais C, Cote G, Marcus P, Chagnes A (2011) XPS, XRD and SEM characterization of a thin ceria layer deposited onto graphite electrode for application in lithium-ion batteries. Appl Surf Sci 257(21):9110–9119

    Article  Google Scholar 

  42. Cherkashinin G, Nikolowski K, Ehrenberg H, Jacke S, Dimesso L, Jaegermann W (2012) The stability of the SEI layer, surface composition and the oxidation state of transition metals at the electrolyte–cathode interface impacted by the electrochemical cycling: X-ray photoelectron spectroscopy investigation. Phys Chem Chem Phys 14(35):12321–12331

    Article  Google Scholar 

  43. Alifantis, K. E., Hackney, S. A., & Kumar, R. V. (Eds.). (2010). High energy density lithium batteries: materials, engineering, applications. Wiley, Weinheim

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yang Zhang.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ramoni, M.O., Zhang, Y., Zhang, HC. et al. Laser ablation of electrodes for Li-ion battery remanufacturing. Int J Adv Manuf Technol 88, 3067–3076 (2017). https://doi.org/10.1007/s00170-016-8986-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00170-016-8986-5

Keywords

Navigation