Skip to main content
Log in

Co-transport of Cr(VI) and Bentonite Colloid in Saturated Porous Media

  • Published:
Bulletin of Environmental Contamination and Toxicology Aims and scope Submit manuscript

Abstract

Transport of Cr(VI) at the presence of bentonite colloid was carried out in saturated porous media of 16–18 mesh and 40–60 mesh sand columns. Effects of flow rate, pH, ion strength, humic acid and bentonite concentrations on Cr(VI) migration were investigated. The results show that the increase of flow rate accelerated the breakthrough of Cr(VI) and BP, but the transport mass of dissolved Cr(VI) decreased by ~ 15.0% when flow rate increased to 2.5 ml min−1. Increasing IS to 10mM resulted in decrease of Cr(VI) transport mass by 6.86%–21.4%. Increase of pH and decrease of bentonite concentration favored the transport of dissolved Cr(VI). Humic acid had little effect on transport amount of Cr at pH7. Cr(VI) transport was dominated by the dissolved Cr(VI). The transport data of dissolved Cr(VI) were well described by the two-site model. The presence of BP reduced total Cr(VI) transport mass in co-transport.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  • Bessho K, Degueldre C (2009) Generation and sedimentation of colloidal bentonite particles in water. Appl Clay Sci 43:253–259

    Article  CAS  Google Scholar 

  • Chen Q, Liu Y (2005) Study on the rheological properties of Jinxi bentonite. Sci Industrial Minerals Process 6:143–153

    Google Scholar 

  • Chen H, Teng Y, Lu S, Wang Y, Wang J (2015) Contamination features and health risk of soil heavy metals in China. Sci Total Environ 512:143–153

    Article  Google Scholar 

  • Dong D, Zhao X, Hua X, Liu J, Gao M (2009) Investigation of the potential mobility of pb, cd and cr(VI) from moderately contaminated farmland soil to groundwater in Northeast, China. J Hazard Mater 162:1261–1268. https://doi.org/10.1016/j.jhazmat.2008.06.032

    Article  CAS  Google Scholar 

  • Ghiasi B, Niksokhan MH, Mazdeh AM (2020) Co-transport of chromium (VI) and bentonite colloidal particles in water-saturated porous media: Effect of colloid concentration, sand gradation, and flow velocity. J Contam Hydrol 234:103682

    Article  CAS  Google Scholar 

  • Huang D, Khan NA, Wang G, Carroll KC, Brusseau ML (2022) The Co-Transport of PFAS and Cr(VI) in porous media. Chemosphere. https://doi.org/10.1016/j.chemosphere.2021.131834

    Article  Google Scholar 

  • Landkamer LL, Harvey RW, Scheibe TD, Ryan JN (2013) Colloid transport in saturated porous media: elimination of attachment efficiency in a new colloid transport model. Water Resour Res 49:2952–2965. https://doi.org/10.1002/wrcr.20195

    Article  Google Scholar 

  • Liu Y, Xu Z, Hu X, Zhang N, Chen T, Ding ZH (2019) Sorption of Pb(II) and Cu(II) on the colloid of black soil, red soil and fine powder kaolinite: effects of pH, ionic strength and organic matter. Environ Pollutants Bioavailab 31:85–93. https://doi.org/10.1080/26395940.2019.1578186

    Article  CAS  Google Scholar 

  • Lov A, Cornelis G, Larsbo M, Persson I, Sjostedt C, Gustafsson JP, Boye K, Kleja DB (2018) Particle- and colloid-facilitated pb transport in four historically contaminated soils - speciation and effect of irrigation intensity. Appl Geochem 96:327–338. https://doi.org/10.1016/j.apgeochem.2018.07.012

    Article  CAS  Google Scholar 

  • Ma J, Guo H, Lei M, Wan X, Zhang H, Feng X, Wei R, Tian L, Han X (2016) Blocking effect of colloids on arsenate adsorption during co-transport through saturated sand columns. Environ Pollut 213:638–647. https://doi.org/10.1016/j.envpol.2016.03.020

    Article  CAS  Google Scholar 

  • McDevitt B, McLaughlin M, Cravotta CA, Ajemigbitse MA, Sice KJV, Blotevogel J, Borch T, Warner NR (2019) Emerging investigator series: radium accumulation in carbonate river sediments at oil and gas produced water discharges: implications for beneficial use as disposal management. Environ Sci: Proc Impacts 21(2):324–338

    CAS  Google Scholar 

  • Missana T, Alonso Ú, Turrero MJ (2003) Generation and stability of bentonite colloids at the bentonite/granite interface of a deep geological radioactive waste repository. J Contam Hydrol 61:17–31. https://doi.org/10.1016/s0169-7722(02)00110-9

    Article  CAS  Google Scholar 

  • Mohammadi AA, Zarei A, Majidi S, Ghaderpoury A, Hashempour Y, Saghi MH, Alinejad A, Yousefi M, Hosseingholizadeh N, Ghaderpoori M (2019) Carcinogenic and non-carcinogenic health risk assessment of heavy metals in drinking water of Khorramabad, Iran. MethodsX. 6:1642–1651. https://doi.org/10.1016/j.mex.2019.07.017

    Article  Google Scholar 

  • Norrfors KK, Bouby M, Heck S, Finck N, Marsac R, Schäfer T, Geckeis H, Wold S (2015) Montmorillonite colloids: I. characterization and stability of dispersions with different size fractions. Appl Clay Sci 114:179–189. https://doi.org/10.1016/j.clay.2015.05.028

    Article  CAS  Google Scholar 

  • Ogawa H, Takebe S, Yamamoto T (1991) Evaluation of Migration of Cesium-137 adsorbed on fine soil particles through natural aerated soil layer. J Nucl Sci Technol 28:248–254. https://doi.org/10.1080/18811248.1991.9731350

    Article  CAS  Google Scholar 

  • Tasker TL, Warner NR, Burgos WD (2020) Geochemical and isotope analysis of produced water from the Utica/Point Pleasant Shale. Appalachian Basin Environ Sci: Proc Impacts 22(5):1224–1232

    CAS  Google Scholar 

  • Wang M, Gao B, Tang D, Yu C (2018) Concurrent aggregation and transport of graphene oxide in saturated porous media: roles of temperature, cation type, and electrolyte concentration. Environ Pollut 235:350–357

    Article  CAS  Google Scholar 

  • Xie B, Jiang Y, Zhang Z, Cao G, Sun H, Wang N, Wang S (2018) Co-transport of pb (II) and cd (II) in saturated porous media: effects of colloids, flow rate and grain size. Chem Spec Bioavail 30:135–143. https://doi.org/10.1080/09542299.2018.1531727

    Article  CAS  Google Scholar 

  • Xu Z, Niu Z, Pan D, Zhao X, Wei X, Li X, Tan Z, Chen X, Liu C, Wu W (2021) Mechanisms of bentonite colloid aggregation, retention, and release in saturated porous media: role of counter ions and humic acid. Sci Total Environ 793:148545

    Article  CAS  Google Scholar 

  • Yin X, Gao B, Ma LQ, Saha UK, Sun H, Wang G (2010) Colloid-facilitated pb transport in two shooting-range soils in Florida. J Hazard Mater 177:620–625. https://doi.org/10.1016/j.jhazmat.2009.12.077

    Article  CAS  Google Scholar 

  • Zhang X, Tong J, Hu BX, Wei W (2018) Adsorption and desorption for dynamics transport of hexavalent chromium (cr(VI)) in soil column. Environ Sci Pollut Res 25:459–468. https://doi.org/10.1007/s11356-017-0263-0

    Article  CAS  Google Scholar 

  • Zhang K, Yuan Z, Ma S, Xu B (2019) Study on the preparation and shear thinning properties of non-newtonian fluid mold flux. Mater Sci 9:993–1000

    CAS  Google Scholar 

  • Zhang P, Zhang X, Li Y, Han L (2020) Influence of pyrolysis temperature on chemical speciation, leaching ability, and environmental risk of heavy metals in biochar derived from cow manure. Bioresour Technol 302:122850. https://doi.org/10.1016/j.biortech.2020.122850

    Article  CAS  Google Scholar 

  • Zhang Z, Gao C, Sun Y, Jin Q, Yang J, Ge M, Chen Z, Guo Z (2021) Co-transport of U(VI) and bentonite colloids: influence of colloidal gibbsite. Appl Clay Sci 205:106033

    Article  CAS  Google Scholar 

  • Zhao XM, Sobecky PA, Zhao LP, Crawford P, Li MT (2016) Chromium(VI) transport and fate in unsaturated zone and aquifer: 3D sandbox results. J Hazard Mater 306:203–209. https://doi.org/10.1016/j.jhazmat.2015.12.004

    Article  CAS  Google Scholar 

  • Zhu H, Fu H, Yan P, Li X, Zhang L, Wang X, Chai C (2022) Study on the release of GMZ bentonite colloids by static multiple light scattering technique. Colloids Surf A 640:128374. https://doi.org/10.1016/j.colsurfa.2022.128374

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was financially supported by the National Key R and D Program of China (Grant No. 2018YFC1800600) and the National Natural Science Foundation of China (Grant No. 21677075). Ding Z. also thanks for the support of “Jiangsu 333 High Level Talent Training Project (2022–2026 )”.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Zhuhong Ding.

Ethics declarations

Conflict of interest

No potential conflict of interest was reported by the authors.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Supplementary Information

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOCX 17528.6 kb)

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gu, X., Mo, H., Wang, L. et al. Co-transport of Cr(VI) and Bentonite Colloid in Saturated Porous Media. Bull Environ Contam Toxicol 110, 30 (2023). https://doi.org/10.1007/s00128-022-03675-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s00128-022-03675-4

Keywords

Navigation