Abstract
Sediment-hosted stratiform ore deposits that underwent metamorphism and orogenesis are interpreted either to have a multiphase origin that might in part predate these events or to be exclusively related to fluid migration during the orogeny. This controversy concerns the formation of many world-class sediment-hosted ore deposits such as in the Central African Copperbelt. Here we present Re–Os dating results for disseminated and stratiform Cu–Co sulfide pseudomorphs after anhydrite in nodules and layers from the Copperbelt. Results demonstrate that at least some of the ores formed at around 800 Ma during rifting and basin development, and thus predate the Pan-African Lufilian orogeny. Younger Re–Os ages, i.e., between 682 ± 28 and 230 ± 36 Ma, may be due to the replacement of the early Cu–Co sulfides by younger sulfide phases. Alternatively, these younger ages may result from the disturbance or resetting of the Re–Os system during recrystallization/metamorphism or the transition of chalcocite from its high- to its low-temperature polymorph.
Similar content being viewed by others
References
Armstrong RA, Master S, Robb LJ (2005) Geochronology of the Nchanga Granite, and constraints on the maximum age of the Katanga Supergroup, Zambian Copperbelt. J Afr Earth Sci 42:32–40
Barra F, Broughton D, Ruiz J, Hitzman M (2004) Multi-stage mineralization in the Zambian Copperbelt based on Re-Os isotope constraints. Geol Soc Am Abstr Programs 36:516
Bartholomé P, Evrard P, Katekesha F, Lopez-Ruiz J, Ngongo M (1972) Diagenetic ore-forming processes at Kamoto, Katanga, Republic of the Congo. In: Amstutz GC, Bernard AJ (eds) Ores in sediments. Springer, Heidelberg, pp 21–41
Batumike MJ, Cailteux JLH, Kampunzu AB (2007) Lithostratigraphy, basin development and regional correlations of the Neoproterozoic Nguba and Kundelungu rock successions, Central African Copperbelt. Gondwana Res 11:432–447
Bernau R, Roberts S, Richards M, Nisbet B, Boyce A, Nowecki J (2013) The geology and geochemistry of the Lumwana Cu (± Co ± U) deposits, NW Zambia. Miner Deposita 48:137–153
Birck J-L, Barman MR, Capmas F (1997) Re–Os isotopic measurements at the femtomole level in natural samples. Geostand Newslett 21:19–27
Brems D, Muchez P, Sikazwe O, Mukumba W (2009) Metallogenesis of the Nkana copper-cobalt South Orebody, Zambia. J Afr Earth Sci 55:185–196
Brenan JM, Cherniak DJ, Rose LA (2000) Diffusion of osmium in pyrrhotite and pyrite: implications for closure of the Re-Os isotopic system. Earth Planet Sci Lett 180:399–413
Cailteux JLH, Kampunzu AB, Lerouge C, Kaputo AK, Milesi JP (2005) Genesis of sediment-hosted stratiform copper-cobalt deposits, Central African Copperbelt. J Afr Earth Sci 42:134–158
Creaser RA, Papanastassiou DA, Wasserburg GJ (1991) Negative thermal ion mass spectrometry of osmium, rhenium and iridium. Geochim Cosmochim Acta 55:397–401
Dewaele S, Muchez P, Vets J, Fernandez-Alonzo M, Tack L (2006) Multiphase origin of the Cu-Co ore deposits in the western part of the Lufilian fold-and-thrust Belt, Katanga (Democratic Republic of Congo). J Afr Earth Sci 46:455–469
Eglinger A, André-Mayer AS, Vanderhaeghe O, Mercadier J, Cuney M, Decrée S, Feybesse JL, Milesi JP (2013) Geochemical signatures of uraninite: from unconformity to syn-metamorphic uranium deposits in the Panafrican Lufilian Copperbelt. Ore Geol Rev 54:197–213
Eglinger A, Feirrana C, Tarantola A, André-Mayer AS, Vanderhaeghe O, Boiron MC, Dubessy J, Richard A, Brouand M (2014) Metamorphic evolution of U-bearing highly saline Ca-Na fluids in syntectonic Pan-African quartz veins in the domes region (Lufilian belt, Zambia). Contrib Mineral Petrol 167:967–995
El Desouky HA, Muchez P, Cailteux J (2009) Two contrasting sulfide phases and contrasting fluid systems in the Katanga Copperbelt, Democratic Republic of Congo. Ore Geol Rev 36:315–332
El Desouky HA, Muchez P, Boyce A, Schneider J, Cailteux JLH, Dewaele S, von Quadt A (2010) Genesis of sediment-hosted stratiform copper-cobalt mineralization at Luiswishi and Kamoto, Katanga Copperbelt (Democratic Republic of Congo). Miner Deposita 45:735–763
Hanson RE, Wardlaw MS, Wilson TJ, Mwale G (1993) U-Pb zircon ages from the Hook granite massif and Mwembeshi dislocation: constraints on Pan-African deformation, plutonism, and transcurrent shearing in central Zambia. Precambrian Res 63:189–209
Hitzman MW, Selley D, Bull S (2010) Formation of sedimentary rock-hosted stratiform copper deposits through earth history. Econ Geol 105:627–639
Huang X-W, Zhao X-F, Qi L, Zhou M-F (2013) Re-Os and S isotopic constraints on the origins of two mineralization events at the Tangdan sedimentary rock-hosted stratiform Cu deposit, SW China. Chem Geol 347:9–19
John T, Schenk V, Mezger K, Tembo F (2004) Timing and PT evolution of whiteschist metamorphism in the Lufilian arc–Zambezi belt orogen (Zambia): implications for the assembly of Gondwana. J Geol 112:71–90
Kampunzu AB, Cailteux J (1999) Tectonic evolution of the Lufilian Arc during Neoproterozoic Pan African orogenesis. Gondwana Res 2:401–421
Kampunzu AB, Kramers JD, Makutu MN (1998) Rb-Sr whole rock ages of the Lueshe, Kirumba and Numbi igneous complexes (Kivu, Democratic Republic of Congo) and the break-up of the Rodinia supercontinent. J Afr Earth Sci 26:29–36
Kampunzu AB, Tembo F, Matheis G, Kapenda D, Huntsman-Mapila P (2000) Geochemistry and tectonic setting of mafic igneous units in the Neoproterozoic Katangan basin, central Africa: implications for Rodinia break up. Gondwana Res 3:125–153
Key RM, Liyungu AK, Njamu FM, Somwe V, Banda J, Mosley PN, Armstrong RA (2001) The western arm of the Lufilian Arc in NW Zambia and its potential for copper mineralization. J Afr Earth Sci 33:503–528
Machel HG (1999) Effects of groundwater flow on mineral diagenesis, with emphasis on carbonate aquifers. Hydrogeol J 7:94–107
Master S, Rainaud C, Armstrong RA, Phillips D, Robb LJ (2005) Provenance ages of the Neoproterozoic Katanga Supergroup (Central African Copperbelt), with implications for basin evolution. J Afr Earth Sci 42:41–60
McGowan RR, Roberts S, Foster RP, Boyce AJ, Coller D (2003) Origin of the copper-cobalt deposits of the Zambian Copperbelt: an epigenetic view from Nchanga. Geologija 31:497–500
Midende G, Boulvais P, Tack L, Melcher F, Gerdes A, Dewaele S, Demaiffe D, Decrée S (2014) Petrography, geochemistry and U-Pb zircon age of the Matongo carbonatite Massif (Burundi): implication for the Neoproterozoic geodynamic evolution of Central Africa. J Afr Earth Sci 100:656–674
Muchez Ph, Corbella, M (2012) Factors controlling the zonation and paragenesis of copper sulphides in sediment-hosted stratiform ore deposits, the central African Copperbelt. Proceedings,Geofluids VII, International Conference, IFP Energies nouvelle, Reuil-Malmaison (France), pp. 235–238
Muchez P, Vanderhaeghen P, El Desouky H, Schneider J, Boyce A, Dewaele S, Cailteux J (2008) Anhydrite pseudomorphs and the origin of stratiform Cu-Co ores in the Katanga Copperbelt (Democratic Republic of Congo). Miner Deposita 43:575–589
Porada H, Berhorst V (2000) Towards a new understanding of the Neoproterozoic—early Palaeozoic Lufilian and northern Zambezi Belts in Zambia and the Democratic Republic of Congo. J Afr Earth Sci 30:727–771
Posfai M, Buseck P (1994) Djurleite, digenite, and chalcocite; intergrowths and transformations. Am Mineral 79:308–315
Rainaud C, Master S, Armstrong RA, Philipps D, Robb LJ (2005) Monazite dating and 40Ar-39Ar thermochronology of metamorphic events in the Central African Copperbelt during the Pan-African Lufilian Orogeny. J Afr Earth Sci 42:183–199
Ramdohr P (1969) The ore minerals and their intergrowths. Pergamon, Oxford
Selley D, Broughton D, Scott R, Hitzman M, Bull S, Large R, McGoldrick P, Croaker M, Pollington N, Barra F (2005) A new look at the geology of the Zambian Copperbelt. In: Hedenquist JW, Thompson JFH, Goldfarb RJ, Richards JP (eds) Economic Geology One Hundredth Anniversary Volume. Society of Economic Geologists, Littleton (USA), pp 965–1000
Sillitoe RH, Perelló J, García A (2010) Sulfide-bearing veinlets throughout the stratiform mineralization of the Central African Copperbelt: temporal and genetic implications. Econ Geol 105:1361–1368
Smoliar MI, Walker RJ, Morgan JW (1996) Re–Os isotope constraints on the age of group IIA, IIIA, IVA, and IVB iron meteorites. Science 271:1099–1102
Stein HJ (2014) Dating and tracing the history of ore formation. In: Holland HD, Turekian KK (eds) Treatise on geochemistry, vol 13, 2nd edn. Elsevier, Oxford, pp 87–118
Steven N, Armstrong R (2003) A metamorphosed Proterozoic carbonaceous shale-hosted Co-Ni-Cu deposit at Kalumbila, Kabompo Dome: the Copperbelt ore shale in northwestern Zambia. Econ Geol 98:893–908
Sweeney MA, Binda PL, Vaughan DJ (1991) Genesis of the ores of the Zambian Copperbelt. Ore Geol Rev 6:51–76
Torrealday HI, Hitzman MW, Stein HJ, Markley RJ, Armstrong R, Broughton D (2000) Re-Os and U-Pb dating of the vein-hosted mineralization at the Kansanshi copper deposit, northern Zambia. Econ Geol 95:1165–1170
Völkening J, Walczyk T, Heumann KG (1991) Osmium isotope determinations by negative thermal ionization mass spectrometry. Int J Mass Spectrom Ion Phys 105:147–159
Zhao X-F, Zhou M-F, Li J-W, Qi L (2013) Late Paleoproterozoic sedimentary rock-hosted stratiform copper deposits in South China: their possible link to the supercontinent cycle. Miner Deposita 48:129–136
Acknowledgments
We sincerely thank Holly Stein and an anonymous reviewer for their constructive comments that improved the manuscript and Hartwig Frimmel as the associate editor. We are grateful to Catherine Zimmerman for her assistance with the Re–Os analyses and Prof. E. Pirard (University of Liège, Belgium) for providing samples. Research was carried out in the framework of project G.0414.08 of the FWO-Vlaanderen.
Conflict of interest
The authors state that there is no disclosure of potential conflict of interest.
Compliance with ethical rules applicable to the journal Mineralium Deposita
Subject: Ethical statement
The authors of the article “Diagenetic origin of the stratiform Cu–Co deposit at Kamoto in the Central African Copperbelt” that has been submitted to Mineralium Deposita confirm that they have read the sections “Ethical responsibilities of the authors,” “Compliance with ethical standards,” and “Disclosure of potential conflicts of interest” in the instruction for authors.
The authors confirm that they have followed the guidelines for ethical and professional conduct which conform the rules of good scientific practice. They guarantee the integrity of the research. The research has been carried which conforms the ethical standards: the research is objective and transparent, and the principles and professionalism have been followed. The framework (project) in which this study has been carried out is acknowledged.
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Below is the link to the electronic supplementary material.
ESM 1
(RTF 136 kb)
Rights and permissions
About this article
Cite this article
Muchez, P., André-Mayer, AS., El Desouky, H.A. et al. Diagenetic origin of the stratiform Cu–Co deposit at Kamoto in the Central African Copperbelt. Miner Deposita 50, 437–447 (2015). https://doi.org/10.1007/s00126-015-0582-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00126-015-0582-3