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The Kabanga Ni sulfide deposit, Tanzania: I. Geology, petrography, silicate rock geochemistry, and sulfur and oxygen isotopes

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Abstract

The Kabanga Ni sulfide deposit represents one of the most significant Ni sulfide discoveries of the last two decades, with current indicated mineral resources of 23.23 Mt at 2.64% Ni and inferred mineral resources of 28.5 Mt at 2.7% Ni (Nov. 2008). The sulfides are hosted by a suite of ∼1.4 Ga ultramafic–mafic, sill-like, and chonolithic intrusions that form part of the approximately 500 km long Kabanga–Musongati–Kapalagulu igneous belt in Tanzania and Burundi. The igneous bodies are up to about 1 km thick and 4 km long. They crystallized from several compositionally distinct magma pulses emplaced into sulfide-bearing pelitic schists. The first magma was a siliceous high-magnesium basalt (approximately 13.3% MgO) that formed a network of fine-grained acicular-textured gabbronoritic and orthopyroxenitic sills (Mg# opx 78–88, An plag 45–88). The magma was highly enriched in incompatible trace elements (LILE, LREE) and had pronounced negative Nb and Ta anomalies and heavy O isotopic signatures (δ18O +6 to +8). These compositional features are consistent with about 20% contamination of primitive picrite with the sulfidic pelitic schists. Subsequent magma pulses were more magnesian (approximately 14–15% MgO) and less contaminated (e.g., δ18O +5.1 to +6.6). They injected into the earlier sills, resulting in the formation of medium-grained harzburgites, olivine orthopyroxenites and orthopyroxenites (Fo 83–89, Mg# opx 86–89), and magmatic breccias consisting of gabbronorite–orthopyroxenite fragments within an olivine-rich matrix. All intrusions in the Kabanga area contain abundant sulfides (pyrrhotite, pentlandite, and minor chalcopyrite and pyrite). In the lower portions and the immediate footwall of two of the intrusions, namely Kabanga North and Kabanga Main, there occur numerous layers, lenses, and veins of massive Ni sulfides reaching a thickness of several meters. The largest amount of high grade, massive sulfide occurs in the smallest intrusion (Kabanga North). The sulfides have heavy S isotopic signatures (δ34S wr = +10 to +24) that broadly overlap with those of the country rock sulfides, consistent with significant assimilation of external sulfur from the Karagwe–Ankolean sedimentary sequence. However, based partly on the relatively homogenous distribution of disseminated sulfides in many of the intrusive rocks, we propose that the Kabanga magmas reached sulfide saturation prior to final emplacement, in staging chambers or feeder conduits, followed by entrainment of the sulfides during continued magma ascent. Oxygen isotope data indicate that the mode of sulfide assimilation changed with time. The heavy δ18O ratios of the early magmas are consistent with ingestion of the sedimentary country rocks in bulk. The relatively light δ18O ratios of the later magmas indicate less bulk assimilation of the country rocks, but in addition the magmas selectively assimilated additional S, possibly through devolatization of the country rocks or through cannibalization of magmatic sulfides deposited in the conduits by preceding magma surges. The intrusions were tilted at ca. 1.37 Ga, during the Kibaran orogeny and associated synkinematic granite plutonism. This caused solid-state mobilization of ductile sulfides into shear zones, notably along the base of the intrusions where sulfide-hornfels breccias and lenses and layers of massive sulfides may reach a thickness of >10 m and can extend for several 10 s to >100 m away from the intrusions. These horizons represent an important exploration target for additional nickel sulfide deposits.

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Acknowledgements

The Kabanga Nickel Company is thanked for funding the analytical work and travel to site. Additional funding was provided by NSERC (to SJB) and NSF (grants EAR 0608645 and EAR 0710910 to ER). Special thanks go to the Kabanga exploration staff for their invaluable logistical support and good company. J Brophy, E Elswick, and C Moore are thanked for thoughtful reviews of earlier versions of parts of this paper. Later versions were reviewed by PC Lightfoot, JS Marsh, J-C Duchesne, X Yang, and an anonymous reviewer. Craig Moore and Steve Studley of the Indiana University Stable Isotope Research Facility are thanked for assistance with various phases of stable isotopic analyses. Part of this research was supported by a Society of Economic Geology student research grant to A. Sarkar.

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Correspondence to Wolfgang D. Maier.

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Editorial handling: P. Lightfoot

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Supplementary Table 1

Reproducibility and precision of ICP-MS analyses (XLS 36 kb)

Supplementary Table 2

Composition of Kabanga olivines (XLS 54 kb)

Supplementary Table 3

Composition of Kabanga and Luhuma orthopyroxenes (XLS 22 kb)

Supplementary Table 4

Compositions of Kabanga and Luhuma plagioclase (XLS 19 kb)

Supplementary Table 5

Composition of Kabanga chromites (XLS 39 kb)

Supplementary Table 6

Major and trace element concentrations in Kabanga silicate rocks (XLS 156 kb)

Supplementary Table 7

Composition of Kabanga sedimentary rocks (XLS 48 kb)

Supplementary Table 8

Modeling of Kabanga magmas (XLS 44 kb)

Supplementary Table 9

Oxygen and sulfur isotopes of minerals and whole-rocks from ore-bearing intrusions in the Kabanga area (XLS 61 kb)

Supplementary Table 10

Sulfur and oxygen isotopes of sedimentary country rocks in the Kabanga area (XLS 23 kb)

Supplementary Fig. 1

Photomicrographs of Kabanga sedimentary rocks. (A) Sulfidic andalusite–muscovite schist, MNB, KN01-05, 538 m. (B) Banded pelite, MNB, KN01-01, 1,645 m. (C) Bleached contact zone in hornfels adjacent to ultramafic rock, Kabanga Main, KN05-01, 138 m. (PDF 2,334 kb)

Supplementary Fig. 2

CIPW norms of Kabanga and Luhuma rocks. Silicate rocks from Kapalagulu and Musongati are shown for comparison (Maier et al. 2008a). (PDF 20 kb)

Supplementary Fig. 3

(A, B) Compositional variation of Kabanga orthopyroxenes, plotting Al2O3 and Cr2O3 vs Mg#. Dashed line represents field of Uitkomst orthopyroxenes (Maier et al. 2004) and shaded field represents compositional range of Bushveld orthopyroxenes (data from Teigler and Eales 1996, The Lower and Critical Zones of the western limb of the Bushveld Complex, as indicated by the Nooitgedacht boreholes. Geol Surv S Afr Bull 111: 126p). (C, D) Compositional variation of Kabanga chromites plotting Fe# and Ni vs Mg#. Bushveld Lower Zone (LZ) data are from Teigler and Eales (1996). (PDF 20 kb)

Supplementary Fig. 4

Variation in trace element ratios and S within the MNB body (as intersected by drill core KN01-08). Yellow-shaded blocks indicate observed ranges within units. See Fig. 7 of paper for legend. (PDF 16 kb)

Supplementary Fig. 5

Histogram of whole-rock δ34S in different intrusions at Kabanga and Luhuma, and their sedimentary host rocks. (PDF 15 kb)

ESM 1

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ESM 2

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ESM 3

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Maier, W.D., Barnes, SJ., Sarkar, A. et al. The Kabanga Ni sulfide deposit, Tanzania: I. Geology, petrography, silicate rock geochemistry, and sulfur and oxygen isotopes. Miner Deposita 45, 419–441 (2010). https://doi.org/10.1007/s00126-010-0280-0

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