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Validierung PCA-gestützter Analysemethoden zur Authentizitätskontrolle von Lebensmitteln

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Zusammenfassung

Die Auswertung spektroskopischer, chromatographischer und massenspektrometrischer Daten mit der Hauptkomponentenanalyse gewinnt zunehmend an Bedeutung in der Authentizitätskontrolle von Lebensmitteln. Dieser Artikel widmet sich der Validierung solcher Prüfverfahren und beschreibt einen Ansatz zur Bestimmung der Entscheidungsgrenze und des Nachweisvermögens. Zur Illustration wird ein Fallbeispiel aus der Laborroutine vorgestellt.

Abstract

Application of principal components analysis to process spectrometric, chromatographic and mass spectrometric data is becoming increasingly important in food authenticity control. This paper is focussed on the validation of such test methods and describes an approach to establishing the decision border and the detection capability. By way of illustration, an example case from the laboratory routine is presented.

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Literatur

  • Angerosa F, Bréas O, Contento S, Guillou C, Reniero F, Sada E (1999) Application of stable isotope ratio analysis to the characterization of the geographical origin of olive oils. J Agric Food Chem 47:1013–1017

    Article  PubMed  CAS  Google Scholar 

  • Bersimis S, Psarakis S, Panaretos J (2007) Multivariate statistical process control charts: an overview. Qual Reliab Engng Int 23:517–543

    Article  Google Scholar 

  • Brereton (2003) Data analysis for the laboratory and chemical plant. Wiley, Chichester

  • Cagliero C, Bicchi C, Cordero C, Rubiolo P, Sgorbini B, Liberto E (2011) Fast headspace-enantioselective GC–mass spectrometric-multivariate statistical method for routine authentication of flavored fruit foods. Food Chem 132:1071–1079

    Article  Google Scholar 

  • Chew V (1966) Confidence, prediction, and tolerance regions for the multivariate normal distribution. J Am Stat Assoc 61:605–617

    Article  Google Scholar 

  • Chudzinska M, Baralkiewicz D (2010) Estimation of honey authenticity by multielements characteristics using inductively coupled plasma-mass spectrometry (ICP-MS) combined with chemometrics. Food Chem Toxicol 48:284–290

    Article  PubMed  CAS  Google Scholar 

  • Cotte JF, Casabianca H, Giroud B, Albert M, Lheritier J, Grenier-Loustalot MF (2004) Characterization of honey amino acid profiles using high-pressure liquid chromatography to control authenticity. Anal Bioanal Chem 378:1342–1350

    Article  PubMed  CAS  Google Scholar 

  • Eberly J (2000) Intersection of ellipses. Geometric tools, LLC. http://www.geometrictools.com/Documentation/Documentation.html. Accessed 19 Feb 2013

  • Fauhl C, Reniero F, Guillou C (2000) 1H-NMR as a tool for the analysis of mixtures of virgin olive oil with oils of different botanical origin. Magn Reson Chem 38:436–443

    Article  CAS  Google Scholar 

  • Gomez-Ariza JL, Arias-Borrego A, Garcia-Barrera T, Beltran R (2006) Comparative study of electrospray and photospray ionization sources coupled to quadrupole time-of-flight mass spectrometer for olive oil authentication. Talanta 70:859–869

    Article  PubMed  CAS  Google Scholar 

  • Hotelling H (1933) Analysis of a complex of statistical variables into principal components. J Educ Psychol 24:417–441

    Article  Google Scholar 

  • Jackson JE (1991) A user guide to principal components. Wiley, New York

    Book  Google Scholar 

  • Lukas V, Schreiber A, Lacina O, Cajka T, Hajslova J (2012) Liquid chromatography-mass spectrometry-based metabolomics for authenticity assessment of fruit juices. Metabolomics 8:793–803

    Article  Google Scholar 

  • Nijhuis A, De Jong S, Vandeginste BGM (1997) Multivariate statistical process control in chromatography. Chemom Intell Lab Syst 38:51–62

    Article  CAS  Google Scholar 

  • Nijhuis A, De Jong S, Vandeginste BGM (1999) The application of multivariate quality control in gas chromatography. Chemom Intell Lab Syst 47:107–125

    Article  CAS  Google Scholar 

  • Oddone M, Aceto M, Baldizzone M, Musso D, Osella D (2009) Authentication and traceability study of hazelnuts from Piedmont, Italy. J Agric Food Chem 57:3404–3408

    Article  PubMed  CAS  Google Scholar 

  • Pearson K (1901) On lines and planes of closest fit to systems of points in space. Philos Mag 2:559–572

    Google Scholar 

  • Pillonel L, Ampuero S, Tabacchi R, Bosset JO (2003) Analytical methods for the determination of the geographic origin of Emmental cheese: volatile compounds by GC/MS-FID and electronic nose. Eur Food Res Technol 216:1438–2377

    Google Scholar 

  • Remaud GS, Martin Y-L, Martin GG, Naulet N, Martin GJ (1997) Authentication of mustard oils by combined stable isotope analysis (SNIF-NMR and IRMS). J Agric Food Chem 45:1844–1848

    Article  CAS  Google Scholar 

  • Risticevic S, Carasek E, Pawliszyn J (2008) Headspace solid-phase microextraction-gas chromatographic-time-of-flight mass spectrometric methodology for geographical origin verification of coffee. Anal Chim Acta 617:72–84

    Article  PubMed  CAS  Google Scholar 

  • Rodrigues C, Maguas C, Prohaska T (2011) Strontium and oxygen isotope fingerprinting of green coffee beans and its potential to proof authenticity of coffee. Eur Food Res Technol 232:361–373

    Article  CAS  Google Scholar 

  • Vandeginste BGM, Massart DL, Buydens LMC, De Jong S, Lewi PJ, Smeyers-Verbeke J (1998) Handbook of chemometrics and qualimetrics: part B. Elsevier, Amsterdam

    Google Scholar 

  • Vigli G, Philippidis A, Spyros A, Dais P (2003) Classification of edible oils by employing 31P and 1H NMR spectroscopy in combination with multivariate statistical analysis. A proposal for the detection of seed oil adulteration in virgin olive oils. J Agric Food Chem 51:5715–5722

    Article  PubMed  CAS  Google Scholar 

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Danksagung

Der Autor möchte sich herzlich bei Frau Boehm und Herrn Dr. Kuballa vom NMR-Labor des CVUA Karlsruhe für die Durchführung der NMR-Analysen und das Überlassen der Daten bedanken.

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  1. CVUA Karlsruhe, Weißenburgerstraße 3, 76187, Karlsruhe, Germany

    Panagiotis Steliopoulos

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  1. Panagiotis Steliopoulos
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Correspondence to Panagiotis Steliopoulos.

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Steliopoulos, P. Validierung PCA-gestützter Analysemethoden zur Authentizitätskontrolle von Lebensmitteln. J. Verbr. Lebensm. 8, 71–77 (2013). https://doi.org/10.1007/s00003-013-0812-5

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  • DOI: https://doi.org/10.1007/s00003-013-0812-5

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