Abstract
A ternary CuO/CuS/MnO2 nanocomposite was developed via the hydrothermal method for visible light-assisted photodegradation of methylene blue. The fabricated nanocomposite was characterized using powder X-ray diffraction having a cubic, hexagonal and tetragonal geometry for the CuO, CuS, and MnO2 with a crystallite size of 3.86 nm, 13.63 nm, and 5.65 nm, respectively. Scanning electron microscopy analysis indicated spherical morphology of nanocomposite. The optical bandgap for the CuO, CuS, MnO2, and CuO/CuS/MnO2 was 2.63 eV, 3.1 eV, 2.615 eV, and 1.8 eV, respectively. The as-synthesized nanocomposite showed 98% degradation efficiency toward methylene blue in 160 min. This study suggests a potential route for the investigation of the photocatalytic performance of CuO/CuS/MnO2 nanocomposite under visible light irradiation.
Similar content being viewed by others
References
Ahmed S, Ahmad ZJ (2020) Monitoring Management, Development of hexagonal nanoscale nickel ferrite for the removal of organic pollutant via Photo-Fenton type catalytic oxidation process. Environ Nanotechnol Monit Manag 14:100321
Ahmed S, Rehman HU, Ali Z, Qadeer A, Haseeb A, Ajmal Z (2021) Interfaces Solvent assisted synthesis of hierarchical magnesium oxide flowers for adsorption of phosphate and methyl orange: Kinetic, isotherm, thermodynamic and removal mechanism. Surf Interfaces 23:100953
Ahmed S, Ashiq MN, Li D, Tang P, Feng YJ (2018) Carbon fiber paper@ MgO films: in situ fabrication and high-performance removal capacity for phosphate anions. Environ Sci Pollut Res 25:34788–34792
Ahmed S, Ahmad Z, Kumar A, Rafiq M, Vashistha VK, Ashiq MN, Kumar AJ (2021) Effective removal of methylene blue using nanoscale manganese oxide rods and spheres derived from different precursors of manganese. J Phys Chem Solids 155:110121
Areerob Y, Cho JY, Jang WK, Oh W-C (2018) Enhanced sonocatalytic degradation of organic dyes from aqueous solutions by novel synthesis of mesoporous Fe3O4-graphene/ZnO@ SiO2 nanocomposites. Ultrason Sonochem 41:267–278
Ahmed S, Guo Y, Li D, Tang P, Feng YJ (2018) Superb removal capacity of hierarchically porous magnesium oxide for phosphate and methyl orange. Environ Sci Pollut Res 25:24907–24916
Ali RM, Hamad HA, Hussein MM, Malash GF (2016) Potential of using green adsorbent of heavy metal removal from aqueous solutions: adsorption kinetics, isotherm, thermodynamic, mechanism and economic analysis. Ecol Eng 91:317–332
Khan SA, Arshad Z, Shahid S, Arshad I, Rizwan K, Sher M, Fatima UJ (2019) Synthesis of TiO2/Graphene oxide nanocomposites for their enhanced photocatalytic activity against methylene blue dye and ciprofloxacin. Compos B Eng 175:107120
Mahanthappa M, Kottam N, Yellappa SJ (2019) Enhanced photocatalytic degradation of methylene blue dye using CuSCdS nanocomposite under visible light irradiation. Appl Surf Sci 475:828–838
Ramesh T, Saravanamuthu V, Shik MJ (2008) A review on UV/TiO photocatalytic oxidation 2 process. Korean J Chem Eng 25:64–72
Venkatesh S, Venkatesh K, Quaff AR (2017) Technology Dye decomposition by combined ozonation and anaerobic treatment: Cost effective technology. J Appl Res Technol 15:340–345
Perelo LW (2010) In situ and bioremediation of organic pollutants in aquatic sediments. J Hazard Mater 177:81–89
Robinson T, McMullan G, Marchant R, Nigam PJ (2001) Remediation of dyes in textile effluent: a critical review on current treatment technologies with a proposed alternative. Biores Technol 77:247–255
Ayodhya D, Venkatesham MJ, Kumari AS, Reddy GB, Ramakrishna D, Veerabhadram G (2015) Photocatalytic degradation of dye pollutants undersolar, visible and UV lights using green synthesised CuS nanoparticles. J Exp Nanosci 11:418–432
Lan ZA, Wu M, Fang Z, Chi X, Chen X, Zhang Y, Wang XJ (2021) A fully coplanar donor–acceptor polymeric semiconductor with promoted charge separation kinetics for photochemistry. Angew Chem Int Ed 60:16355–16359
Banerjee T, Podjaski F, Kröger J, Biswal BP, Lotsch BV (2021) Polymer photocatalysts for solar-to-chemical energy conversion. Nat Rev Mater 6:168–190
Yang L, Peng Y, Luo X, Dan Y, Ye J, Zhou Y, Zou ZJ (2021) Beyond C 3 N 4 π-conjugated metal-free polymeric semiconductors for photocatalytic chemical transformations. Chem Soc Rev 50:2147–2172
Li Y, Dong H, Li L, Tang L, Tian R, Li R, Chen J, Xie Q, Jin Z, Xiao JJ (2021) Recent advances in waste water treatment through transition metal sulfides-based advanced oxidation processes. Water Res 192:116850
Xia C, Wang H, Kim JK, Wang JJ (2021) Rational design of metal oxide-based heterostructure for efficient photocatalytic and photoelectrochemical systems. Adv Func Mater 31:2008247
Zhao D, Wang Y, Dong C-L, Huang Y-C, Chen J, Xue F, Shen S, Guo LJ (2021) Boron-doped nitrogen-deficient carbon nitride-based Z-scheme heterostructures for photocatalytic overall water splitting. Nat Energy 6:388–397
Huang C, Wen Y, Ma J, Dong D, Shen Y, Liu S, Ma H, Zhang YJ (2021) Unraveling fundamental active units in carbon nitride for photocatalytic oxidation reactions. Nat Commun 12:1–8
Xiong L, Tang J (2021) Strategies and challenges on selectivity of photocatalytic oxidation of organic substances. Adv Energy Mater 11:2003216
Wu LY, Mu YF, Guo XX, Zhang W, Zhang ZM, Zhang M, Lu TB (2019) Encapsulating perovskite quantum dots in iron-based metal–organic frameworks (MOFs) for efficient photocatalytic CO2 reduction. Angew Chem Int Ed 58:9491–9495
Chung P-H, Kuo C-T, Wang T-H, Lu Y-Y, Liu C-I, Yew T-R (2021) Interfaces, a sensitive visible light photodetector using cobalt-doped zinc ferrite oxide thin films. ACS Appl Mater Interfaces 13:6411–6420
Tobaldi D, Dvoranová D, Lajaunie L, Rozman N, Figueiredo B, Seabra M, Škapin AS, Calvino J, Brezová V, Labrincha JJ (2021) Graphene-TiO2 hybrids for photocatalytic aided removal of VOCs and nitrogen oxides from outdoor environment. Chem Eng J 405:126651
Koop J, Deutschmann OJ (2009) Detailed surface reaction mechanism for Pt-catalyzed abatement of automotive exhaust gases. Appl Catal B 91:47–58
Ku J, Zhang L, Fu W, Wang S, Yin W, Chen HJ (2021) Mechanistic study on calcium ion diffusion into fayalite: a step toward sustainable management of copper slag. J Hazard Mater 410:124630
Liu Y, Kong J, Yuan J, Zhao W, Zhu X, Sun C, Xie JJ (2018) Enhanced photocatalytic activity over flower-like sphere Ag/Ag2CO3/BiVO4 plasmonic heterojunction photocatalyst for tetracycline degradation. Chem Eng J 331:242–254
Rambabu K, Bharath G, Banat F, Show PL (2021) Green synthesis of zinc oxide nanoparticles using Phoenix dactylifera waste as bioreductant for effective dye degradation and antibacterial performance in wastewater treatment. J Hazard Mater 402:123560
Shi J, Yuan T, Zheng M, Wang XJ (2021) Metal-free heterogeneous semiconductor for visible-light photocatalytic decarboxylation of carboxylic acids. ACS Catal 11:3040–3047
Mateo D, Morlanes N, Maity P, Shterk G, Mohammed OF, Gascon JJ (2021) Efficient visible-light driven photothermal conversion of CO2 to methane by nickel nanoparticles supported on barium titanate. Adv Func Mater 31:2008244
Chen Y, Wang X, He X, An Q, Zuo ZJ (2021) Photocatalytic dehydroxymethylative arylation by synergistic cerium and nickel catalysis. J Am Chem Soc 143:4896–4902
Li X, Lin J, Li J, Zhang H, Duan X, Sun H, Huang Y, Fang Y, Wang SJ (2021) Engineering, Temperature-induced variations in photocatalyst properties and photocatalytic hydrogen evolution: differences in UV, visible, and infrared radiation. ACS Sustain Chem Eng 9:7277–7285
Mohammed AM, Mohtar SS, Aziz F, Aziz M, Ul-Hamid A, Salleh WNW, Yusof N, Jaafar J, Ismail AF (2021) Ultrafast degradation of Congo Red dye using a facile one-pot solvothermal synthesis of cuprous oxide/titanium dioxide and cuprous oxide/zinc oxide pn heterojunction photocatalyst. Mater Sci Semicond Process 122:105481
Loan TT, Huy DK, Chung HM, Thanh NK, Hoan TD, Duong NP, Soontaranon S, Klysubun WJ (2021) Structure and magnetic properties of magnetic iron oxide/zinc oxide core/shell nanocomposites: effect of ZnO coating. Mater Today Commun 26:101733
Karuppasamy P, Nisha NRN, Pugazhendhi A, Kandasamy S, Pitchaimuthu SJ (2021) An investigation of transition metal doped TiO2 photocatalysts for the enhanced photocatalytic decoloration of methylene blue dye under visible light irradiation. J Environ Chem Eng 9:105254
Kayani ABA, Kuriakose S, Monshipouri M, Khalid FA, Walia S, Sriram S, Bhaskaran MJ (2021) UV photochromism in transition metal oxides and hybrid materials. Small 17:2100621
Soni V, Singh P, Quang HHP, Khan AAP, Bajpai A, Van Le Q, Thakur VK, Thakur S, Nguyen V-H, Raizada PJ (2022) Emerging architecture titanium carbide (Ti3C2Tx) MXene based photocatalyst toward degradation of hazardous pollutants: recent progress and perspectives. Chemosphere 293:133541
Soni V, Khosla A, Singh P, Nguyen V-H, Van Le Q, Selvasembian R, Hussain CM, Thakur S, Raizada PJ (2022) Current perspective in metal oxide based photocatalysts for virus disinfection: a review. J Environ Manage 308:114617
Hasija V, Patial S, Singh P, Nguyen V-H, Le QV, Thakur VK, Hussain CM, Selvasembian R, Huang C-W, Thakur SJ (2021) Photocatalytic inactivation of viruses using graphitic carbon nitride-based photocatalysts: virucidal performance and mechanism. Catalysts 11:1448
Sharma K, Hasija V, Patial S, Singh P, Nguyen V-H, Nadda Ak, Thakur S, Nguyen-Tri P, Nguyen CC, Kim SY (2022) Recent progress on MXenes and MOFs hybrids: Structure, synthetic strategies and catalytic water splitting. Int J Hydrog Energy
Kumar A, Singh P, Khan AAP, Van Le Q, Thaku S, Raizada PJ (2022) CO2 photoreduction into solar fuels via vacancy engineered bismuth-based photocatalysts: Selectivity and mechanistic insights. Chem Eng J 439:135563
Thakur S, Pandey S, Arotiba OA (2016) Development of a sodium alginate-based organic/inorganic superabsorbent composite hydrogel for adsorption of methylene blue. Carbohydr Polym 153:34–46
Yang R, Fan Y, Ye R, Tang Y, Cao X, Yin Z, Zeng Z (2021) MnO2-based materials for environmental applications. Adv Mater 33:2004862
Taddesse AM, Alemu M, Kebede TJ (2020) Enhanced photocatalytic activity of pnn heterojunctions ternary composite Cu2O/ZnO/Ag3PO4 under visible light irradiation. J Environ Chem Eng 8:104356
Behjati S, Sheibani S, Herritsch J, Gottfried JM (2020) Photodegradation of dyes in batch and continuous reactors by Cu2O-CuO nano-photocatalyst on Cu foils prepared by chemical-thermal oxidation. Mater Res Bull 130:110920
Likodimos V, Dionysiou DD, Falaras P (2010) Bio/Technology Clean water: water detoxification using innovative photocatalysts. Rev Environ Sci Bio/Technol 9:87–94
Kamali M, Dewil R, Appels L, Aminabhavi TM (2021) Nanostructured materials via green sonochemical routes–Sustainability aspects. Chemosphere 276:130146
Hu R, Zhang R, Ma Y, Liu W, Chu L, Mao W, Zhang J, Yang J, Pu Y, Li XA (2018) Enhanced hole transfer in hole-conductor-free perovskite solar cells via incorporating CuS into carbon electrodes. Appl Surf Sci 462:840–846
Shaheen TI, Fouda A, Salem SS (2021) Integration of cotton fabrics with biosynthesized CuO nanoparticles for bactericidal activity in the terms of their cytotoxicity assessment. Ind Eng Chem Res 60:1553–1563
Ghasemian MB, Mayyas M, Idrus-Saidi SA, Jamal MA, Yang J, Mofarah SS, Adabifiroozjaei E, Tang J, Syed N, O’Mullane AP (2019) Self-limiting galvanic growth of MnO2 monolayers on a liquid metal—applied to photocatalysis. Adv Func Mater 29:1901649
Gurgenc TJ (2021) Structural characterization and dielectrical properties of Ag-doped nano-strontium apatite particles produced by hydrothermal method. J Mol Struct 1223:128990
Yang C, Su X, Xiao F, Jian J, Wang J, Chemical AB (2011) Gas sensing properties of CuO nanorods synthesized by a microwave-assisted hydrothermal method. Sens Actuat B Chem 158:299–303
Zhang J, Zhang Z (2008) Hydrothermal synthesis and optical properties of CuS nanoplates. Mater Lett 62:2279–2281
Iyyapushpam S, Nishanthi S, Padiyan DP (2013) Compounds, Photocatalytic degradation of methyl orange using α-Bi2O3 prepared without surfactant. J Alloy Compd 563:104–107
Holzwarth U, Gibson N (2011) The Scherrer equation versus the’Debye-Scherrer equation’. Nat Nanotechnol 6:534–534
Kumar P, Pathak S, Jain K, Singh A, Basheed G, Pant RJ (2022) Compounds, Low-temperature large-scale hydrothermal synthesis of optically active PEG-200 capped single domain MnFe2O4 nanoparticles. J Alloy Compd 904:163992
Kanwal A, Sajjad S, Leghari SAK, Yousaf ZJ (2021) Cascade electron transfer in ternary CuO/α-Fe2O3/γ-Al2O3 nanocomposite as an effective visible photocatalyst. J Phys Chem Solids 151:109899
Yang J, Fu M, Liu H, Yin G, Tan M, Sun X, Huang H (2021) An inexpensive CuO nanoparticles as cocatalyst significantly enhanced the photo-oxidation performance of Bi2.Ga28Al1.2O9 photocatalyst under visible-light. Mater Lett 283:128796
Riyaz S, Parveen A, Azam A (2016) Microstructural and optical properties of CuS nanoparticles prepared by sol–gel route. Persp Sci 8:632–635
Gu Y, Min Y, Li L, Lian Y, Sun H, Wang D, Rummeli MH, Guo J, Zhong J, Xu L (2021) Crystal splintering of β-MnO2 induced by interstitial ru doping toward reversible oxygen conversion. Chem Mater 33:4135–4145
Rittiruam M, Somdee S, Buapin P, Aumnongpho N, Kerdprasit N, Saelee T, Kheawhom S, Chotigkrai N, Praserthdam S, Praserthdam PJ (2021) Compounds, On the deactivation mechanisms of MnO2 electrocatalyst during operation in rechargeable zinc-air batteries studied via density functional theory. J Alloy Compd 869:159280
Somraksa W, Suwanboon S, Amornpitoksuk P, Randorn C (2020) Physical and photocatalytic properties of CeO 2/ZnO/ZnAl 2 O 4 ternary nanocomposite prepared by Co-precipitation method. Mater Res 23
Sajjad S, Khan M, Leghari SAK, Ryma NA, Farooqi SA (2019) Potential visible WO 3/GO composite photocatalyst. Int J Appl Ceram Technol 16:1218–1227
Singhal S, Dixit S, Shukla A (2018) Self-assembly of the Ag deposited ZnO/carbon nanospheres: a resourceful photocatalyst for efficient photocatalytic degradation of methylene blue dye in water. Adv Powder Technol 29:3483–3492
Lei R, Ni H, Chen R, Zhang B, Zhan W (2017) synthesis of WO3/Fe2O3 nanosheet arrays on iron foil for photocatalytic degradation of methylene blue. J Mater Sci Mater Electron 28:10481–10487
Dinari M, Momeni MM, Ahangarpour M (2016) Efficient degradation of methylene blue dye over tungsten trioxide/multi-walled carbon nanotube system as a novel photocatalyst. Appl Phys A 122:1–9
Raghavan N, Thangavel S, Venugopal G (2015) Enhanced photocatalytic degradation of methylene blue by reduced graphene-oxide/titanium dioxide/zinc oxide ternary nanocomposites. Mater Sci Semicond Process 30:321–329
Isai KA, Shrivastava VS (2019) Photocatalytic degradation of methylene blue using ZnO and 2% Fe–ZnO semiconductor nanomaterials synthesized by sol–gel method: a comparative study. SN Appl Sci 1:1–11
Chaudhary K, Shaheen N, Zulfiqar S, Sarwar MI, Suleman M, Agboola PO, Shakir I, Warsi MF (2020) Binary WO3-ZnO nanostructures supported rGO ternary nanocomposite for visible light driven photocatalytic degradation of methylene blue. Synth Met 269:116526
Tian L, Rui Y, Sun K, Cui W, An W (2018) Surface decoration of ZnWO4 nanorods with Cu2O nanoparticles to build heterostructure with enhanced photocatalysis. Nanomaterials 8:33
Zou W, Zhang L, Liu L, Wang X, Sun J, Wu S, Deng Y, Tang C, Gao F, Dong L (2016) Engineering the Cu2O–reduced graphene oxide interface to enhance photocatalytic degradation of organic pollutants under visible light. Appl Catal B 181:495–503
Shang Y, Chen Y, Shi ZJ (2013) Synthesis and visible light photocatalytic activities of Au/Cu2O heterogeneous nanospheres. Acta Phys Chim Sin 29:1819–1826
Nadimi M, Saravani AZ, Aroon M, Pirbazari AE (2019) Photodegradation of methylene blue by a ternary magnetic TiO2/Fe3O4/graphene oxide nanocomposite under visible light. Mater Chem Phys 225:464–474
Anand K, Thangaraj R, Kumar P, Kaur J, Singh R (2015) Synthesis, characterization, photocatalytic activity and ethanol-sensing properties of In2O3 and Eu3+: In2O3 nanoparticles. In: AIP Conference Proceedings, AIP Publishing LLC, pp 110002
Chinnathambi A, Syed A, Elgorban AM, Marraiki N, Al-Rashed S, Yassin MT (2021) Compounds, Performance analysis of novel La6WO12/Ag2WO4 nano-system for efficient visible-light photocatalysis and antimicrobial activity. J Alloy Compd 879:160075
Verma P, Samanta SK (2017) Degradation kinetics of pollutants present in a simulated wastewater matrix using UV/TiO2 photocatalysis and its microbiological toxicity assessment. Res Chem Intermed 43:6317–6341
Author information
Authors and Affiliations
Corresponding authors
Ethics declarations
Conflict of interest
The authors declare that they have no known competing financial interest or personal relationship that could have appeared to influence this work.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Abdullah, M., John, P., Ashiq, M.N. et al. Development of CuO/CuS/MnO2 ternary nanocomposite for visible light-induced photocatalytic degradation of methylene blue. Nanotechnol. Environ. Eng. 8, 63–73 (2023). https://doi.org/10.1007/s41204-022-00266-w
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s41204-022-00266-w