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Synthesis of Au nanoparticles supported on metal oxides (H3PMo12O40 and TiO2) by PS-PVP block copolymer encapsulation method

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Abstract

Au supported on metal oxides (P-25, HPA) was successfully synthesized by PS-PVP block copolymer encapsulation method. The size of nanoparticles was strongly dependent on calcination conditions (time and temperature). The particle size was also controlled by selection of the appropriate length of PVP part in block copolymer. When particulate gold was doped on the surface of P-25, it strongly improved visible light absorption by plasma resonance. Compared with pure TiO2, Au supported on P-25 demonstrated much higher photocatalytic activity for acetaldehyde decomposition under visible light illumination. The enhanced photocatalytic activity could be attributed to the increase of visible light absorption and catalytic activity of nanoparticulate Au.

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References

  1. M. Haruta,Catal. Today,36, 153 (1997).

    Article  CAS  Google Scholar 

  2. Y. Lou and M. Maye,Chem. Comm.,2001, 473 (2001).

    Article  Google Scholar 

  3. M. Haruta,Catal. Surv. Jpn.,1, 61 (1997).

    Article  CAS  Google Scholar 

  4. N. M. Gupta and A. K. Tripathi,J. Catal.,187, 343 (1999).

    Article  CAS  Google Scholar 

  5. M. Haruta, N. Yamada, T. Kobayashi, and S. Iijima,J. Catal.,115, 301 (1989).

    Article  CAS  Google Scholar 

  6. M. Haruta, T. Kobayashi, H. Sano, and N. Yamada,Chem. Lett.,405 (1987).

  7. C. H. Walker, J. V. St. John, and P. W. Neilson,J. Am. Chem. Soc.,123, 3846 (2001).

    Article  CAS  Google Scholar 

  8. B. S. Uphade, Y. Yamada, T. Akita, T. Nakamura, and M. Haruta,Appl. Catal. A,215, 137 (2001).

    Article  CAS  Google Scholar 

  9. A. Dawson and P. V. Kamat,J. Phys. Chem. B,105, 960 (2001).

    Article  CAS  Google Scholar 

  10. J. Li and H. C. Zeng,Chem. Mater.,18, 4270 (2006).

    Article  CAS  Google Scholar 

  11. A. Orlov, D. A. Jefferson, M. Tikhov, and R. M. Lambert,Catal. Commun.,8, 821 (2007).

    Article  CAS  Google Scholar 

  12. C. Mohr, H. Hofmeister, J. Radnik, and P. Claus,J. Am. Chem. Soc.,125, 1905 (2003).

    Article  CAS  Google Scholar 

  13. B. L. V. Prasad, S. I. Stoeva, C. M. Sorensen, and K. J. Klabunde,Langmuir,18, 7515 (2002).

    Article  CAS  Google Scholar 

  14. M. Brust, M. Walker, D. Bethell, D. J. Schiffrin, and R. Whyman,J. Chem. Soc. Commun.,801 (1994).

  15. M. Maye and Y. Lou,Langmuir,16, 7520 (2000).

    Article  CAS  Google Scholar 

  16. J. P. Spatz, S. Möβmer, M. Möller, T. Herzog, A. Plettl, and P. Ziemann, J. Lumin.,76, 168 (1998).

    Article  Google Scholar 

  17. T. F. Jaramillo, S.-H. Baeck, B. R. Cuenya, and E. W. McFarland,J. Am. Chem. Soc.,125, 7148 (2003).

    Article  CAS  Google Scholar 

  18. M. V. Seregina, L. M. Bronstein, O. A. Platonova, D. M. Chenyshov, P. M. Valetsky, J. Hartmann, E. Wenz, and M. Antonietti,Chem. Mater.,9, 923 (2003).

    Article  Google Scholar 

  19. T. Hayakawa, T. Kouketsu, and M. Kakimoto,Macromol. Res.,14, 52 (2006).

    Article  CAS  Google Scholar 

  20. J. Wang, S. Uma, and K. J. Klabunde,Appl. Catal. B. Environ.,48, 151 (2004).

    Article  CAS  Google Scholar 

  21. O. Yoshihisa, D. A. Tryk, K. Hashimoto, and A. Fujishima,J. Phys. Chem. B.,102, 2699 (1998).

    Article  Google Scholar 

  22. J. Chou, N. R. Franklin, S.-H. Baeck, T. F. Jaramillo, and E. W. McFarland,Catal. Lett.,95, 107 (2004).

    Article  CAS  Google Scholar 

  23. A. Dawson and P. V. Kamat,J. Phys. Chem.,105, 960 (2001).

    Article  CAS  Google Scholar 

  24. C. Zhang, Y. Liu, G. You, B. Li, J. Shi, and S. Qian,Physica, B 357, 334 (2005).

    CAS  Google Scholar 

  25. R. S. Sonawane and M. K. Dongare,J. Mol. Catal. A; Chem.,243, 68 (2005).

    Article  Google Scholar 

  26. V. Iliev, D. Tomova, L. Bilyarska, and G. Tyuliev,J. Mol. Catal. A; Chem.,263, 32 (2007).

    Article  CAS  Google Scholar 

  27. D. Li and H. Haneda,J. Photochem. Photobiol. A; Chem.,155, 171 (2003).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemical Engineering, Inha University, 402-751, Incheon, Korea

    Gil-Pyo Kim, Young-Soo Jung, Seung-Bum Yoon, Dong-Woo Kim & Sung-Hyeon Baeck

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  1. Gil-Pyo Kim
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  2. Young-Soo Jung
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  3. Seung-Bum Yoon
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  4. Dong-Woo Kim
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  5. Sung-Hyeon Baeck
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Correspondence to Sung-Hyeon Baeck.

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Kim, GP., Jung, YS., Yoon, SB. et al. Synthesis of Au nanoparticles supported on metal oxides (H3PMo12O40 and TiO2) by PS-PVP block copolymer encapsulation method. Macromol. Res. 15, 693–696 (2007). https://doi.org/10.1007/BF03218952

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  • DOI: https://doi.org/10.1007/BF03218952

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