Abstract
The paper describes the underlying principles and discusses the most important advantages and limitations of the experimental technique of magnetically affected reaction yield spectroscopy as developed in the authors’ laboratory and guides the reader step by step through a typical experimental sequence using as example the problem of short-lived radical cations of a series of methyl-substituted benzenes in X-irradiated nonpolar solutions. For two of the eight target substances — benzene itself and mesithylene — the paper reports the first unequivocal observation of their radical cations in liquid alkane solution at room temperature and provides a lower estimate of about 10 ns for their relaxation times in low magnetic field.
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Kalneus, E.V., Stass, D.V. & Molin, Y.N. Typical applications of MARY spectroscopy: Radical ions of substituted benzenes. Appl. Magn. Reson. 28, 213–229 (2005). https://doi.org/10.1007/BF03166757
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DOI: https://doi.org/10.1007/BF03166757