Abstract
Although substantial progress has been achieved in inductovely coupled plasma (ICP) spectroscopy, placing it among the principal spectroscopic tools in analytical chemistry research and applications laboratories, some limitations exist especially for the analysis of ultratrace concentration levels in biological materials. The application of chemical and instrumental techniques to increase the concentration levels of analytes is practical, but complicated by the requirements of maintaining the multielement nature of ICP spectroscopy. Two novel chelating resins [poly(dithiocarbamate) and poly(acrylamidoxime)] have been synthesized and applied with ICP spectrometry to enhance the practical sensitivity for ultratrace concentration determinations in biological and other materials. The determination of a number of trace elements in bone, dialysis solutions, serum, and urine is improved using the resin ICP approach. In addition, speciation of inorganic forms of As, Cr, Se, and Te is possible with the poly(dithiocarbamate) resin, and determination of the chemical forms of these elements in urine was performed.
Similar content being viewed by others
References
Barnes, R. M.,Trends Anal. Chem. 1, (2), 51 (1981).
Barnes, R. M.,Crit. Rev. Anal. Chem. 7 (3), 203 (1978).
Barnes, R. M.,Phil. Trans. Roy. Soc. London, Ser. A. 305, 499 (1982).
Barnes, R. M.,Karl-Marx-Universitaet Leipzig Wissenschaft. Zeit. 28 (4), 383 (1979).
Barnes, R. M.,Advances in Atomic Spectroscopy, in press.
Fassel, V. A., inRecent Advances in Analytical Spectroscopy, K. Fuwa, ed., Pergamon Press, Oxford, 1982, pp.1–14.
Robin, J. P.,Progr. Anal. Atomic Spectr. 5, 79 (1982).
Robin, J. P., Mermet, J. M., Abdallah, M. H., Batal, A., and Trassy, C., inRecent Advances in Analytical Spectroscopy, K. Fuwa, ed., Pergamon Press, Oxford, 1982, pp. 75–82.
Boumans, P. W. J. M., inRecent Advances in Analytical Spectroscopy, K. Fuwa, ed., Pergamon Press, Oxford, 1982, pp. 61–74.
Mermet, J. M., and Hubert, J.,Progr. Anal. Atomic Spectr. 5, 1 (1982).
Delves, H. T.,Progr. Anal. Atomic Spectr. 4, 1 (1981).
Dahlquist, R. L., and Knoll, J. W.,Appl. Spectr. 32, 1 (1978).
Morrison, G. H.,Crit. Rev. Anal. Chem.,8, 287 (1979).
Leyden, D. E., and Wegscheider, W.,Anal. Chem. 53, 1059A (1981).
Berman, S. S., McLaren, J. W., and Willie, S. N.,Anal. Chem. 52, 488 (1980)
Jones, J. W., Capar, S. G., and O’Haver, T. C.,Analyst 107, 353 (1982).
Rasmussen, L.,Anal. Chim. Acta 125, 117 (1981).
McLaren, J. W., Berman, S. S., Sturgeon R. E., and Wilie, S. N., “Application of ICP-AES to Seawater Analysis,” in1982 Winter Conference on Plasma Spectrochemistry, ICP Information Newsletter, Amherst, MA, 1982, pp. 177–178.
Sturgeon, R. E., Berman S. S., Desaulniers, A., and Russell, D. S.,Talanta 27, 27, 85 (1980).
Watanabe, H., Goto, K., Taguchi, S., McLaren, J. W., Berman, S. S., and Russell, D. S.,Anal. Chem. 53, 738 (1981).
Sturgeon, R. E., Berman, S. S., and Willie, S. N.,Talanta 29, 167 (1982).
Sturgeon, R. E., Berman, S. S., Willie, S. N., and Desalniers, J. A. H.,Anal. Chem. 53, 2337 (1981).
Hackett, D. S., and Siggia, S., “Selective Concentration and Determination of Trace Metals Using Poly(dithiocarbamate) Chelating Ion-Exchange Resins,” inEnvironmental Analysis, G. W. Ewing, ed., Academic Press, New York, 1977, pp. 253–265.
Collella, M. B., Siggia, S., and Barnes, R. M.,Anal. Chem. 52, 967 (1980).
Collella, M. B., Siggia, S., and Barnes, R. M.,Anal. Chem. 52, 2347 (1980).
Miyazaki, A., and Barnes, R. M.,Anal. Chem.,53, 299 (1981).
Miyazaki, A., and Barnes, R. M.,Anal. Chem. 53, 364 (1981).
Mahanti, H. S., and Barnes, R. M.,Anal. Chim. Acta (in press).
Zhuang, M., and Barnes, R. M.,Spectrochim. Acta 38B, 259 (1983).
Barnes, R. M. Zhuang, M., and Fodor, P., “Application of Chelating Resins and Inductively Coupled Plasma Spectroscopy for the Determination of Metals in Biological Materials Including Serum and Urine,”Federation of Analytical Chemistry and Spectroscopy Societies Program and Abstracts, Philadelphia, 1982, Abstract 61.
Barnes, R. M., and Genna, J. S.,Anal. Chem.,51, 1065 (1979).
Barnes, R. M., Fodor, P., Inagaki, K., and Fodor, M.,Spectrochim. Acta 38B, 245 (1983).
Fodor, P., and Barnes, R. M.,Spectrochim. Acta 38B, 239 (1983).
Barnes, R. M., and Fodor, P.,Spectrochim. Acta (in press).
Mahanti, H. S., and Barnes, R. M.,Anal. Chim. Acta 149, 395 (1983).
Mahanti, H. S., and Barnes, R. M.,Anal. Chem. 55, 403 (1983).
Barnes, R. M., Fernando, L., Lu, S. J. and Mahanti, H. S.,Appl. Spectr. 37(4) (1983).
Barnes, R. M., and Lu, S. J.,Can. J. Spectr. (in press).
Mahanti, H. S., and Barnes, R. M.,Appl. Spectr. 37, (1983).
Jiang, Z., and Barnes, R. M., “Separation and Pre-Concentration of Trace Elements from Seawater with Poly(dithiocarbamate) Chelating Resin and Their Determination by Inductively Coupled Plasma Spectroscopy,”1982 Winter Conference on Plasma Spectrochemistry, ICP Information Newsletter, Amherst MA, 1982, pp. 184–185.
Pahlavanpour, B., Thompson, M., and Thorne, L.,Analyst 106, 467 (1981).
Pickford, C. J.,Analyst. 106, 464 (1981).
Wolnik, K. A., Fricke, F. L., Hahn, M. H., and Caruso, J. A.,Anal. Chem. 53, 1030 (1981).
Hahn, M. H., Wolnik, K. A., Fricke, F. L., and Caruso, J. A.,Anal. Chem. 54, 1048 (1982).
Goulden, P. D., Anthony, D. H. J., and Austen, K. D.,Anal. Chem. 53, 2027 (1981).
Sommer, D., Ohls, K., and Koch, K.,Fresenius Z. Anal. Chem. 306, 372 (1981).
Ikeda M., Nishibe, J., Hamada, S., and Tujino, R.,Anal. Chem. Acta 125, 109 (1981).
Nakahara, T.,Anal. Chim. Acta 131, 73 (1981).
Matsumoto, K., and Fuwa, K.,Bunseki Kagaku 30, 188 (1981).
Nygaard D. D., and Lowry, J. H.,Anal. Chem. 54, 803 (1982).
Fassel, V. A., “Inductively Coupled Plasma-Atomic Emission Spectroscopy,” An Alternative Approach to ‘Flameless Atomic Absorption Spectroscopy,’” inFlameless Atomic Absorption Analysis: An Update, ASTM STP 618, American Society for Testing and Materials, Philadelphia., 1977, pp. 22–42.
Gunn, A. M., Millard, D. L., and Kirkbright, G. F.,Analyst 103, 1066 (1978).
Kirkbright, G. F., and Snook, R. D.,Anal. Chem. 51, 1938 (1979).
Millard, D. L., Shan, H. C., and Kirkbright, G. F.,Analyst 105, 502 (1980).
Camara Rica, C., Kirkbright, G. F., and Snook, R. D.,Atomic Spectr. 2, 172 (1981).
Camara Rica, C., and Kirkbright, G. F.,Sci. Total Environ. 22, 193 (1982).
Cope, M. J., Kirkbright, G. F., and Burr, P. M.,Analyst 107, 611 (1982).
Aziz, A., Broekaert, J. A. C., and Leis, F.,Spectrochim. Acta 37B, 369 (1982).
Crabi, G., Cavalli, P., Achilli, M., Rossi, G., and Omenetto, N.,Atomic Spectr. 3, 81 (1982).
Ng., K. C., and Caruso, J.,Anal. Chim. Acta 143, 9 (1982).
Swaidan, H., and Christian, G. D.,Can J. Spectr. (in press).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Barnes, R.M. Determination of trace elements in biological materials by inductively coupled plasma spectroscopy with novel chelating resins. Biol Trace Elem Res 6, 93–103 (1984). https://doi.org/10.1007/BF02918324
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02918324
Index Entries
- emission spectrometry, of biological trace elements
- inductively coupled plasma spectroscopy, of biological trace elements
- analytical chemistry, of biological trace elements
- sensitivity, of ICP in biological trace element analysis
- resin, trace element analysis in
- chelation, and biological trace element analysis
- preconcentration, and biological trace element analysis
- bone, biological trace element analysis in
- serum, biological trace element analysis in, urine, biological trace element analysis in
- dialysis solution, for biological trace elements