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Crystal structure of polymorphous modifications of Tm2S3 and related compounds

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Abstract

The role of symmetry in crystal structure formation is revealed for the polymorphous modifications of Tm2S3 and related compounds Tm15S{ib22}, Tm5S7, and Tm8S11 using the procedure of selecting and analyzing closepacked planes with cationic, anionic, and combined motifs. The laws of mutual agreement between the cation and anion matrices determining the size of the unit cells are examined, and relationships between the specific cation volumes and symmetry are traced.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, USSR

    S. V. Borisov, N. V. Podberezskaya, N. V. Pervukhina & S. A. Magarill

Authors
  1. S. V. Borisov
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  2. N. V. Podberezskaya
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  3. N. V. Pervukhina
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  4. S. A. Magarill
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Translated fromZhumal Strukturnoi Khimii, Vol. 39, No. 4, pp. 669–675, July–August, 1998.

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Borisov, S.V., Podberezskaya, N.V., Pervukhina, N.V. et al. Crystal structure of polymorphous modifications of Tm2S3 and related compounds. J Struct Chem 39, 543–548 (1998). https://doi.org/10.1007/BF02903628

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  • DOI: https://doi.org/10.1007/BF02903628

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