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V-Ni system

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Abstract

The vanadium-rich portion of the V-Ni system was investigated by thermal analysis, microscopic examination, and X-ray diffraction studies and a phase diagram is proposed. The vanadium solvus was found to exhibit a marked temperature dependence increasing from 6.8 at. pct Ni at 800°C to 24.0 at. pct Ni at 1280°C. A compound having a substituted V3Ni (A15) type structure was shown to occur at the substoichiometric composition of 22 to 23 at. pct Ni. It forms peritectoidally at 900°C with an enthalpy of formation of 1595 cal per mole.

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Authors and Affiliations

  1. Institute for Atomic Research, Ames, Iowa

    E. R. Stevens

  2. Institute for Atomic Research and Professor, Department of Metallurgy, Iowa State University, Ames, Iowa

    O. N. Carlson

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  1. E. R. Stevens
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  2. O. N. Carlson
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Stevens, E.R., Carlson, O.N. V-Ni system. Metall Trans 1, 1267–1271 (1970). https://doi.org/10.1007/BF02900242

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