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The B−Ti (Boron-Titanium) system

  • B−Ti
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Bulletin of Alloy Phase Diagrams

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Cited References

  • 49Ehr: P. Ehrlich, “Binary System of Titanium with Nitrogen, Carbon, Boron, and Beryllium,”Z. Anorg. Chem., 259, 1–41 (1949) in German. (Equi Diagram; Experimental)

    Article  Google Scholar 

  • 49Nor: J.T. Norton, H. Blumenthal, and S.J. Sindeband, “Structure of Diborides of Titanium, Zirconium, Columbium, Tantalum and Vanadium,”Metall Trans. 185, 749–751 (1949). (Crys Structure; Experimental)

    Google Scholar 

  • 50And: L.H. Andersson and R. Kiessling, “Investigations on the Binary Systems of Boron with Chromium, Colubium, Nickel, and Thorium, Including a Discussion of the Phase TiB in the Titanium-Boron System,”Acta Chem. Scand., 4, 160–164 (1950). (Crys Structure; Experimental)

    Article  Google Scholar 

  • 51Bre: L. Brewer, D.L. Sawyer, D.H. Templeton, and C.H. Dauben, “A Study of the Refractory Borides,”J. Am. Ceram. Soc., 34, 173–179 (1951). (Equi Diagram, Crys Structure; Experimenal)

    Article  Google Scholar 

  • 51Gre: H.M Greenhouse, O.E. Accountius, and H.H. Sisler, “High-Temperature Reactions in the System Titanium Carbide-Boron Carbide,”J. Am. Ceram. Soc., 73, 5086–5087 (1951). (Equi Diagram; Experimental)

    Google Scholar 

  • 51Ogd: H.R. Ogden and R.I. Jaffee, “Titanium-Boron Alloys,”Trans. AIME, 191, 335–336 (1951). (Equi Diagram; Experimental)

    Google Scholar 

  • 52Gla: F.W. Glaser, “Contribution to the Metal-Carbon-Boron Systems,”Trans. AIME 194 391–396 (1952). (Equi Diagram; Experimental)

    Google Scholar 

  • 52Kie: R. Kieffer, F. Benesovky and E.R.Honak, “A New Method of Preparing Borides of the Transition Metals, Particularly of Titanium and Zirconium Borides,”Z. Anorg. Chem., 268, 191–200 (1952) in German. (Equi Diagram; Experimental)

    Article  Google Scholar 

  • 52Pos: B. Post and F.W. Glaser, “Borides of Some Transition Metals,”J. Chem. Phys., 20, 1050–1051 (1952). (Crys Structure; Experimental)

    Article  ADS  Google Scholar 

  • 53Sch: P. Schwarzkopf and F.W. Glaser, “Structure and Chemical Properties of Borides of Transition Metals of the Fourth, Fifth and Sixth Group,”Z. Metallkd., 44, 353–358 (1953) in German., (Crys Structure; Experimental)

    Google Scholar 

  • 54Dec: B.F. Decker and J.S. Kasper, “The Crystal Structure TiB,”Acta Crystallogr, 7, 77–80 (1954). (Crys Structure; Experimental)

    Article  Google Scholar 

  • 54Pal: A.E. Palty, H. Margolin, and J.P.Nielsen, “Titanium-Nitrogen and Titanium-Boron Systems,”Trans. ASM, 46, 312–328 (1954). (Equi Diagram; Experimental)

    Google Scholar 

  • 54Pos: B. Post, F.W. Glaser, and D. Moskowitz, “Transition Metal Diborides,”Acta Metall., 2, 20–25 (1954). (Equi Diagram; Experimental)

    Article  Google Scholar 

  • 55Bre: L. Brewer and H. Haraldsen, “The Thermodynamic Stability of Refractory Metal Boride,”J. Electrochem. Soc., 102, 399–406 (1955). (Thermo; Experimental)

    Article  Google Scholar 

  • 57Lsk: I.I.Lskoldsky and L.R. Bogorodskaya, “The Possibility of Production of Metalloceramic (Sintered) Hard Alloys Based on Chromium, Titanium, and Tungsten Borides,”Zh. Prikl. Khim., 30, 177–185 (1957) in Russian; TR:J. Appl. Chem. USSR, 30, 177-185 (1957). (Equi Diagram; Experimental)

    Google Scholar 

  • 57Wal: B. Walker, C. Ewing, and R. Miller, “Heat capacity of Titanium Diboride from 30 to 700°C,”J. Phys. Chem., 61, 1682–1683 (1957). (Thermo; Experimental)

    Article  Google Scholar 

  • 58Epe: V.A. Epelbaum and M.I. Starostina, Thermochemical Investigations of Boron and Certain Borides”,Bor. Trudy Konf. Khim., Bora i Ego Soedinenii, 97-101 (1958) in Russian. (Thermo; Experimental)

  • 59Kre: A.N. Krestovnikov and M.S. Vendrikh, “Themodynamics of Titanium Diborides,”Izv. Tsvetn. Metall., 2, 54–57 (1959) in Russian. (Thermo; Experimental)

    Google Scholar 

  • 60Sey: A.U. Seybolt, “An Exploration of High Boron Alloys,”Trans. ASM, 52, 971–989 (1960). (Equi Diagram; Experimental)

    Google Scholar 

  • 60Wit: A. Wittmann, H. Nowotny, and H. Boller, “Investigation of the Ternary System Titanium-Molybdenum-Boron,”Monaatsh. Chem., 91, 608–615 (1960) in German. (Crys Structure; Experimental)

    Article  Google Scholar 

  • 61Low: C.E. Lowell and W.S. Williams, “High Temperature Calorimeter for the Determination of Heats of Formation of Refractory Compounds,”Rev. Sci. Instrum., 32, 1120–1123 (1961). (Thermo; Experimental)

    Article  ADS  Google Scholar 

  • 61Wil: W. Williams, “The Heat of Formation of Titanium Diboride: Experimental and Analytical Resolution of Literature Conflict,”J. Phys. Chem., 65, 2213–2216 (1961). (Thermo;Experimental)

    Article  Google Scholar 

  • 62Mez: R. Mezaki, E. Tilleux, D.W. Barnes, and J.L. Margrave, “Thermodynamics of Nuclear Materials (1962),” IAEA, Vienna, 775–788 (1962). (Thermo; Experimental)

    Google Scholar 

  • 62Sch: R. Schissel and O. Trulson, “Mass Spectrometric Study of the Vaporization of the Titanium-Boron System,”J. Phys. Chem., 66, 1492–1496 (1962). (Thermo, Pressure; Experimental)

    Article  Google Scholar 

  • 63Fes: V.V. Fesenko and A.S. Bolgar, “Evaporation Rate and Vapor Pressure of Carbides, Silicides, Nitrides, and Borides,”Sov. Powder Metall. Met. Ceram., 1, 11 (1963) in Russian (Thermo; Experimental)

    Google Scholar 

  • 63Mcd: R.A. McDonald, F.D. Oetting, and H. Prophet, Rep. N64-18824, Dow Chemical Co., Midland, MI (1963). (Thermo; Experimental)

    Google Scholar 

  • 63Nee: D.S. Neel, C.D. Pears, and S. Oglesby, Tech. Doc. Rep. No. ASD-TDR-62-765, Southern Res. Inst., Birmingham, AL (1963). (Thermo; Experimental)

    Google Scholar 

  • Indicates key paper63Wes: E.F. Westrum, “Heat Capacity,” Chapt. XV, Tech. Doc. Rep. No. RTD-TDR-63-4096, Part I, L. Kaufman and E.Y.Clougherty, Ed., Man Labs, Inc., Cambridge, MA, 239–261 (1963). (Thermo; Experimental)

    Google Scholar 

  • Indicates key paper64Fen: R.G. Fenish, “Phase Relationships in the Titanium-Boron System,” NRM-138, 1−37 (1964). (Equi Diagram; Experimental)

  • 64Kib: G.M. Kibler, T.F. Lyon, M.I. Linvesky, and V.J. Desantis, Tech. Rep. No. WADD-TR-60-646, Part III, Vol. 2, General Electric Co., Evansdale, OH (1964). (Thermo; Experimental)

    Google Scholar 

  • 64Kib: V.A. Kirilin, A.E. Sheindlin, V. Ya. Chekhovskoi, and V.I. Tyukaev, “Enthalpy and Heat Capacity of Titanium Diboride at 273.15-2600°K”,Teplofiz. Vys. Temp., 2, 710–715 (1964) in Russian. (Thermo; Experimental)

    Google Scholar 

  • 65Geb: J.J. Gebhardt and R.F. Cree, “Vapor-Deposited Borides of Group IVA Metal”,J. Am. Ceram. Soc., 48, 262–267 (1965). (Crys Structure; Experimental)

    Article  Google Scholar 

  • 65Kau: L. Kaufman and E.V. Clougherty, “Investigation of Boride Compounds for High Temperature Applications”,Metals for the Space Age, Plansee Proceedings 1964, Plansee Metallwek, Reute, Austria, F. Benesovsky, Ed., 722−758 (1965). (Thermo; Experimental)

  • Indicates key paper.66Fen: R.G. Fenish, “A New Intermediate Compound in the Titanium-Boron System, Ti3B4”,Trans. AIME, 236, 804 (1966). (Crys Structure; Experimental)

    Google Scholar 

  • Indicates key paper.66Hub: E.J. Huber, “The Heat of Formation of Titanium Diboride”,J. Chem. Eng. Data, 11 (3), 430–431 (1966). (Thermo; Experimental)

    Article  MathSciNet  Google Scholar 

  • Indicates key paper66Rud: E. Rudy and St. Windisch, “Ternary Phase Equilibria in Transition Metal-Boron-Carbon-Silicon Systems Part I. Related Binary System Volume VII. Ti−B System”, Technical Rep. No. AFML-TR-65-2, Part I, Vol. VII (1966). (Equi Diagram; Experimental)

  • 69Spe: K.E. Spear, H. Schafer, and P.W. Gilles, “Thermodynamics of Vanadium Borides”, inHigh Temperature Technology, Butterworths, London, 201–212 (1969). (Thermo; Experimental)

    Google Scholar 

  • 71Stu: D.R. Stull and H. Prophet, “JANAF Thermochemical Tables”, 2nd ed., Nat. Stand. Ref. Data Ser., Nat. Bur. Stand. (U.S.),37 (1971). (Thermo; Compilation)

  • Indicates key paper75Akh: V.V. Akhachinskij and N.A. Chirin, “Enthalpy of Formation of Titanium Diboride”, Thermodynamics of Nuclear Materials 1974, Vol. II, IAEA, Vienna, 467–476 (1975). (Thermo; Experimental)

    Google Scholar 

  • 76The: J. Thebault, R. Pailler, G. Bontemps-Moley, M. Bourdeau, and R. Naslain, “Chemical Compatibility in Boron Fiber-Titanium Composite Materials”,J. Less-Common Met., 47, 221–233 (1976). (Equi Diagram; Experimental)

    Article  Google Scholar 

  • 77Cal: B. Callmer, “An Accurate Refinement of the β-Rhombohedral Boron Structure”,Acta Cryst Allogr., B, 33, 1951–1954 (1977). (Crys Structure; Experimental)

    Article  Google Scholar 

  • 79Cha: M.W. Chase, “JANAF Thermochemical Data (Boron, March 31, 1979; Titanium, June 30, 1979)”, Dow Chemical Co., Midland, MI (1979). (Thermo; Experimental)

    Google Scholar 

  • 80Yur: T.J. Yurick and K.E. Spear, “Thermodynamics of TiB2 from Ti−B−N Studies”,Thermodynamics of Nuclear Materials 1979, Vol. I, IAEA, Vienna, 73–90 (1980). (Thermo; Experimental)

    Google Scholar 

  • 81Leb: A. Lebugle, R. Nyholm, and N. Martensson, “Electron Spectroscopy Studies of Titanium Boronitrides”,J. Less-Common Met., 82 (1/2), 269–275 (1981). (Equi Diagram, Crys Structure; Experimental)

    Article  Google Scholar 

  • 81Ner: V.A. Neronov, M.A. Korchagin, V.V. Aleksandrov, and S.N. Gusenko, “Investigation of the Interaction Between Boron and Titanium”,J. Less-Common Met., 82, 125–129 (1981). (Equi Diagram; Experimental)

    Article  Google Scholar 

  • 81Tav: G.F. Tavadze, O.Sh. Okrostsvaridze, F.N. Tavadze, G.V. Tasagareishvili, and G.A. Mazmishvili, “Crystallization of Eutectic Systems Ti−B, V−B, Zr−B, and Hf−B at Ultrahigh Rates of Cooling”,J. Less-Common Met., 82, 368 (1981). (Meta Phases; Experimental)

    Article  Google Scholar 

  • 84Kau: L. Kaufman, B. Uhrenius, D. Birnie, and K. Taylor, “Coupled Pair Potential, Thermochemical and Phase Diagram Data for Transition Metal Binary Systems-VII”,Calphad, 8(1), 25–66 (1984). (Equi Diagram; Theory)

    Article  Google Scholar 

  • Indicates key paper86Spe: K.E. Spear, P. McDowell, and F. McMahon, “Experimental Evidence for the Existence of the Ti3B4 Phase”,J. Am. Ceram. Soc., 69 (1), C4-C5 (1986). (Equi Diagram, Crys Structure; Experimental)

    Article  Google Scholar 

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Dr. Murray was supported by the Office of Naval Research and the National Bureau of Standards through the Metallurgy Division and the Office of Standard Reference Data. Drs. Liao and Spear were supported by the National Bureau of Standards, Metallurgy Division. Thermodynamic calculations have been made using computer programs generously made avaiable by E.-Th. Henig and H.L. Lukas of the Max-Planck Institute, Stuttgart, Federal Republic of Germany. Literature searched through 1984. Dr. Murray is the ASM/NBS Data Program Category Editor for binary titanium alloys, and Dr. Spear is the ASM/NBS Data Program Category Editor for binary boron systems.

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Murray, J.L., Liao, P.K. & Spear, K.E. The B−Ti (Boron-Titanium) system. Bulletin of Alloy Phase Diagrams 7, 550–555 (1986). https://doi.org/10.1007/BF02869864

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