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Identification of alkylphosphonic acid derivatives by IR and mass spectrometry

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Abstract

An approach is considered to the problem of identification of alkylphosphonic acid derivatives within Chemical Weapons Convention. The technique is based on correlations between the structural fragments of toxic chemicals and their IR and mass spectra.

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References

  1. Convention on the Prohibition of the Development,Stockpiling, and the Use of Chemical Weapons and on Their Destruction, United States Central and Disarmament Agency, Washington, D.C., 1993.

  2. Rybal’chenko, I.V., Tsekhmister, V.I., and Kireev, A.F.,Zh. Ros. Khim. O-va im. D.I. Mendeleeva, 1994, vol. 38, p. 13.

    CAS  Google Scholar 

  3. Kireev, A.F., Kholstov, V.I., Rodyushkina, E.B., Rybalchenko, I.V., and Suvorkin, V.N.,Proc. 1st Singapore Int. Symp. on Protection Against Toxic Chemicals (SIS-PAT), Singapore, 1988.

  4. Note by the Director-General: Revised Standard Operation Procedure for Evaluation of the Results of OPCW Proficiency Tests, Hague: OPCW, Technical Secretariat, 1998.

  5. First Official Inter-Laboratory Proficiency Test, Hague: OPCW, Technical Secretariat, 1997, vols. 1 and 2.

  6. Second Official Inter-Laboratory Proficiency Test, Hague: OPCW, Technical Secretariat, 1997, vols 1 and 2.

  7. Third Official Proficiency Test, Hague: OPCW, Technical Secretariat, 1997, vols. 1 and 2.

  8. Fourth Official Proficiency Test, Hague: OPCW, Technical Secretariat, 1998, vols. 1 and 2.

  9. Gofts, P.C. and Kosolapov, G.M.,J. Am. Chem. Soc., 1953, vol. 75, p. 3379.

    Article  Google Scholar 

  10. Brodskii, E.S. and Kireev, A.F.,Zh. Anal. Khim., 1997, vol. 52, no. 8, p. 884.

    Google Scholar 

  11. Nekrasov, Yu.S., Sukharev,Yu.N., Tepfer, E.E., and Molgacheva, N.S., Izv.Ross. Akad. Nauk, Ser. Khim., 1996, no. 11, p. 2683.

  12. Piottukh-Peletskii, V.N., Bogdanova, T.F., and Derendyaev, B.G.,Zh. Strukt. Khim., 1996, vol. 37, no. 2, p. 368.

    Google Scholar 

  13. Strokov, I.I., Lebedev, K.S., and Derendyaev, B.G.,Zh. Strukt. Khim., 1996, vol. 37, no. 6, p. 1129.

    CAS  Google Scholar 

  14. Silverstein, R., Bassler, G., and Morril, T.,Spectrophotometric Identification of Organic Compounds, New York: Wiley, 1974. Translated under the titleSpektrometricheskaya identifikatsiya organicheskikh soedinenii, Moscow: Mir, 1977.

    Google Scholar 

  15. Shagidulin, R.R., Chernova, A.V., Vinogradova, VS., and Mukhametov, F.S.,Atlas IK-spektrov fosfororganicheskikh soedinenii (Atlas of IR Spectra of Organophosphorous Compounds), Moscow: Nauka, 1984.

    Google Scholar 

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Kireev, A.F., Rybal’chenko, I.V., Savchuk, V.I. et al. Identification of alkylphosphonic acid derivatives by IR and mass spectrometry. J Anal Chem 55, 837–845 (2000). https://doi.org/10.1007/BF02757846

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  • DOI: https://doi.org/10.1007/BF02757846

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