Skip to main content
Log in

Mixed metal oxide inorganic/organic coatings

  • Technical Articles
  • Published:
Journal of Coatings Technology

Abstract

Mixed metal oxide ceramer coatings were developed using linseed oil as the organic phase with titanium i-propoxide, and zirconium n-propoxide as the inorganic sol-gel precursors. The overall goal of this study was to develop a primer that will provide corrosion protection and better adhesion to metal substrates with minimal environmental impact. Zinc acetate dihydrate was introduced to the system as an anticorrosive agent. Various coatings properties such as adhesion, hardness, impact resistance, flexibility, and tensile properties were investigated as a function of sol-gel precursor type and content. In addition, electrochemical impedance spectroscopy (EIS) was used to evaluate the corrosion properties of these mixed metal oxide inorganic/organic coatings.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Wicks, Z.W., Jones, F.N., and Pappas, P.S.,Organic Coatings Science and Technology, Volume 1, John Wiley & Sons, New York, 1992.

    Google Scholar 

  2. Formo, M.W., “Drying Oils,” in Bailey’s Industrial Oil and Fat Products, Volume 1, Swern, D. (Ed.), John Wiley & Sons, New York, 1979.

    Google Scholar 

  3. Bellettiere, S.J. and Mahoney, M.D., “Multi-Metallic Complexes: The Next Generation of Driers,”Journal of Coatings Technology,59, No. 752, 101 (1987).

    CAS  Google Scholar 

  4. Holmberg, K.,High Solids Alkyd Resins, Marcel Dekker, New York, 1987.

    Google Scholar 

  5. Rodrigues, D.E. and Wilkes, G.L.,J. Inorg. Organomet. Polymer, 3, 197 (1993);

    Article  CAS  Google Scholar 

  6. Tamami, B., Betrabet, C., and Wilkes, G.L.,Polymer Bull., 30, 39 (1993);

    Article  CAS  Google Scholar 

  7. Huang, H., Glaser, R.H., Brennan, A.B., Rodrigues, D.E., and Wilkes, G.L.,Ultrastructure Processing of Advanced Materials, Uhlmann, D.R., and Ulrich, D.R. (Eds.), John Wiley & Sons, New York, 1992;

    Google Scholar 

  8. Rodrigues, D.E., Brennan, A.B., Betrabet, C., Wang, B., and Wilkes, G.L.,Chem. Mater., 4, 1437 (1992);

    Article  CAS  Google Scholar 

  9. Wang, B., Wilkes, G.L., Smith, C.D., and McGrath, H.E.,Polymer Commun., 32, 400 (1991);

    CAS  Google Scholar 

  10. Wilkes, G.L., Brennan, A.B., Huang, H.H., Rodrigues, D.E., and Wang, B.,Mater. Res. Soc. Symp. Proc., 171, 15 (1990);

    CAS  Google Scholar 

  11. Huang, H.H., Orler, B., and Wilkes, G.L.,Polymer Bull., 14, 557 (1985).

    Article  CAS  Google Scholar 

  12. Wang, S. and Mark, J.E.,Macromol. Rep., 31, 253 (1994);

    Google Scholar 

  13. Wang, S., Ahmad, Z., and Mark, J.E.,Macromol. Rep., 31, 411 (1994);

    Google Scholar 

  14. Zhao, M.X., Ning, Y.P., and Mark, J.E.,Adv. Compos. Mater., 891 (1992);

  15. Wang, S., Ahmad, Z., and Mark, J.E.,Chem. Mater., 6, 943 (1994).

    Article  CAS  Google Scholar 

  16. Surivet, F., Lam, T., Pascault, J.P., and Pham, Q.T.,Macromolecules, 25, 4309 (1992);

    Article  ADS  CAS  Google Scholar 

  17. Surivet, F., Lam, T.M., Pascault, J.P., and Mai, C.,Macromolecules, 25, 5742 (1992);

    Article  ADS  CAS  Google Scholar 

  18. Kaddami, H., Surivet, F., Gerard, J.F., Lam, T.M., and Pascault, J.P.,J. Inorg. Organomet. Polymer, 4, 183 (1994).

    Article  CAS  Google Scholar 

  19. Iyoku, Y., Kakimoto, M., Imai, Y.,High Perform. Polymer, 6, 43 (1994);

    Article  CAS  Google Scholar 

  20. Iyoku, Y., Kakimoto, M., and Imai, Y.,High Perform. Polymer, 6, 53 (1994);

    Article  CAS  Google Scholar 

  21. Morikawa, A., Yamaguchi, H., Kakimoto, M., and Imai, Y.Chem. Mater., 6, 913 (1994).

    Article  CAS  Google Scholar 

  22. Sugama, T., Kukacka, L.E., and Carciello, N.,Prog. Org. Coat., 18, 173 (1990);

    Article  CAS  Google Scholar 

  23. Sugama, T., Carciello, N., and Taylor, C.,J. Non-Cryst. Solids, 134, 58 (1991);

    Article  ADS  CAS  Google Scholar 

  24. Sugama, T., and Taylor, C.,J. Mater. Sci., 27, 1723 (1992);

    Article  ADS  CAS  Google Scholar 

  25. Sugama, T., Fair, J.R., and Reed, A.O., “Polymetallosiloxane Coatings Derived from Two-Step, Acid-Base Catalyzed Sol Precursors of Corrosion Protection of Aluminum Substrates,”Journal of Coatings Technology,65, No. 826, 27 (1993).

    CAS  Google Scholar 

  26. Atik, M., Luna, F.P., Messaddeq, S.H., and Aegerter, M.A.,J. Sol-Gel Sci. Tech., 8, 517 (1997);

    CAS  Google Scholar 

  27. Atik, M., Neto, P.D., Avaca, L.A., and Aegerter, M.A.,Ceramics International, 21, 403 (1995).

    Article  CAS  Google Scholar 

  28. Tzaskomapaulette, P.P. and Naseri, A.,J. Electrochemical Soc., 144, 1307 (1997).

    Article  Google Scholar 

  29. Brinker, C.J. and Scherer, G.W.,Sol-Gel Science., Academic Press, New York, 1990.

    Google Scholar 

  30. Tuman, S.J. and Soucek, M.D., “Novel Inorganic/Organic Coatings Based on Linseed Oil and Sunflower Oil with Sol-Gel Precursors,”Journal of Coatings Technology,68, No. 854, 73 (1996).

    CAS  Google Scholar 

  31. Xiao, H., Han, L.T., Lee, C.C., and Mansfeld, F.,Corrosion, 412, May 1997.

  32. Tuman, S.J., Chamberlain, D., Scholsky, K.M., and Soucek, M.D.,Prog. Org. Coat., 28, 251–258 (1996).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Department of Polymers and Coatings, Fargo, ND 58105.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wold, C.R., Soucek, M.D. Mixed metal oxide inorganic/organic coatings. Journal of Coatings Technology 70, 43–51 (1998). https://doi.org/10.1007/BF02720514

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02720514

Keywords

Navigation