Skip to main content
Log in

A reconsideration of phase relations in the Ti-Al-Mo and Ti-Al systems

  • Published:
Metallurgical Transactions A Aims and scope Submit manuscript

Abstract

A microstructural and X-ray investigation of Ti-AI-Mo alloys Ti-31 Al-15 Mo, Ti-31 Al-13 Mo, Ti-31Al-9Mo and Ti-35Al-9Mo (containing the Ti3Al, TiAl and β phases) indicates that the existing phase diagram of the ternary system for this composition range published by Ge Dhzhi-Min and Pylaeva is in error above 1473 K. An analysis of phase relations reveals that the error has arisen from their use of the Ti-AI diagram due to Bumps, Kessler and Hansen as a basis for generating the ternary. It is shown that a phase diagram of the ternary, consistent with the experimental results, can be generated using a version of the Ti-AI system due to Margolin. Simple geometric arguments are used to build up a new semi-quantitative description of the Ti-AI-Mo system which can be used as a basis for a detailed investigation of phase equilibria in this system.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. G. Lutjering and S. Weissmann:Acta Met., 1970, vol. 18, pp. 785–95.

    Article  Google Scholar 

  2. A. Gysler and S. Weissmann:Mater. Sci. Eng., 1977, vol. 27, pp. 181–93.

    Article  CAS  Google Scholar 

  3. T. Hamajima, G. Lutjering, and S. Weissmann:Met. Trans., 1973, vol. 4, pp. 847–56.

    Article  CAS  Google Scholar 

  4. M. Hida and S. Weissmann:Met. Trans. A, 1975, vol. 6A, pp. 1541–46.

    Article  CAS  Google Scholar 

  5. Ge Dhzhi-Min and E. N. Pylaeva:Titanium and its Alloys, I.I. Kornilov, ed., pp. 11–23, Israel Programme for Scientific Trans- lations, Jerusalem, 1966.

    Google Scholar 

  6. J. B. McAndrew and H. D. Kessler:J. Metals, Oct. 1956, vol. 8, pp. 1348–53.

    CAS  Google Scholar 

  7. D. Schechtman, M. J. Blackburn, and H. A. Lipsitt:Met. Trans., 1974, vol. 5, pp. 1373–81.

    Article  Google Scholar 

  8. H. A. Lipsitt, D. Schechtman, and R. E. Schafrik:Met. Trans. A, 1975, vol. 6A, pp. 1991–96.

    Article  CAS  Google Scholar 

  9. E. S. Bumps, H. D. Kessler, and M. Hansen:Trans. AIME, 1952, vol. 194, pp. 609–14.

    Google Scholar 

  10. M. Hansen:Constitution of Binary Alloys, p. 139, McGraw-Hill, New York, 1958.

    Google Scholar 

  11. H. Margolin:Metals Handbook, vol. 8 (8th edition), p. 264, ASM, Metals Park, OH, 1973.

    Google Scholar 

  12. E. Ence and H. Margolin:Trans. TMS-AIME, 1961, vol. 221, pp. 151–57.

    CAS  Google Scholar 

  13. M. J. Blackburn and J. C. Williams:Trans. TMS-AIME, 1967, vol. 239, pp. 287–88.

    CAS  Google Scholar 

  14. D. Banerjee: Ph.D. Thesis, Indian Institute of Science, Bangalore, India, 1979.

    Google Scholar 

  15. M. J. Blackburn:The Science, Technology and Application of Titanium, R. I. Jaffee and N. E. Promisel, eds., p. 640, Pergamon Press, London, 1970.

    Google Scholar 

  16. A. Prince:Alloy Phase Equilibria, p. 153, Elsevier, London, 1966.

    Google Scholar 

  17. M. Hansen:Constitution of Binary Alloys, p. 976, McGraw-Hill, New York, 1958.

    Google Scholar 

  18. A. Prince:Alloy Phase Equilibria, p. 146, Elsevier, London, 1966.

    Google Scholar 

  19. E. S. Bumps, H. D. Kessler, and M. Hansen:Trans. ASM, 1953, vol. 45, pp. 1008–28.

    Google Scholar 

  20. C. S. Barrett:Structure of Metals, pp. 229–30, McGraw-Hill, London, 1952.

    Google Scholar 

  21. A. Prince:Alloy Phase Equilibria, p. 230, Elsevier, London, 1966.

    Google Scholar 

  22. H. Bohm and K. Lohberg:Z. Metallkunde, 1958, vol. 49, pp. 173–78.

    CAS  Google Scholar 

  23. T. Hamajima, G. Lutjering, and S. Weissmann:Met. Trans., 1972, vol. 3, pp. 2805–10.

    CAS  Google Scholar 

  24. E. K. Molchanova:Phase Diagrams of Titanium Alloys, p. 169, Israel Programme for Scientific Translation, Jerusalem, 1965.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Formerly with the Indian Institute of Science, Bangalore, India

Formerly with the Department of Metallurgy, Indian Institute of Science, Bangalore 560012, India

Rights and permissions

Reprints and permissions

About this article

Cite this article

Banerjee, D., Krishnan, R.V. & Vasu, K.I. A reconsideration of phase relations in the Ti-Al-Mo and Ti-Al systems. Metall Trans A 11, 1095–1105 (1980). https://doi.org/10.1007/BF02668133

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02668133

Keywords

Navigation