Abstract
The Na2SO4-induced oxidation of Ni-20Cr-2ThO2 has been studied at 900° and 1000°C in 150 torr O2. A rapid weight-gain period, corresponding to NiO formation occurs after a short incubation period. The duration of the rapid weight gain stage persists for about 2 h and terminates with the development of a continuous Cr2O3 internal layer. Subsequent oxide formation is extremely slow, similar to that reported for normal oxidation of TD-NiCr.
Similar content being viewed by others
References
E. L. Simons, G. V. Browning, and H. A. Liebhafsky:Corrosion, 1955, vol. 2, pp. 505t-14t.
A. U. Seybolt and A. Beltran:Amer. Soc. Test. Mater. Spec. Tech. Publ. 421, 1967, pp. 21–37.
G. A. Goebel and F. S. Pettit:Met. Trans., 1970, vol. 1, pp. 1943–54.
A. U. Seybolt:Trans. TMS-AIME, 1968, vol. 242, pp. 1955–61.
N. S. Bornstein and M. A. DeCresente:Trans. TMS-AIME, 1969, vol. 245, pp. 1947–52.
C. S. Giggins and F. S. Pettit:Met. Trans., 1971, vol. 2, pp. 1071–78.
H. H. Davis, H. C. Graham, and I. A. Kvernes:Oxid. Metals, 1971, vol. 3, pp. 431–51.
G. R. Wallwork and A. Z. Hed:Oxid. Metals, 1971, vol. 3, pp. 229–41.
N. S. Bornstein, M. A. DeCresente, and T. Sturiale: Proc. of the Air Force Materials Laboratory Fiftieth Anniversary Technical Conference on Cor-rosion of Military and Aerospace Equipment, AFML-TR-67-329, November 1967.
W. C. Tripp and H. C. Graham:J. Electrochem. Soc., 1971, vol. 118, pp. 1195–99.
H. C. Graham, W. C. Tripp, and H. H. Davis:Progress in Vacuum Microbalance Techniques, vol. 1, Heyden and Son, Ltd., London, 1972.
J. G. Tschinkel:Corrosion, 1972, vol. 28, pp. 161–69.
E. A. Gulbransen and S. A. Jansson:High Temperature Metallic Corrosion by Sulfur and its Compounds, The Electrochemical Society, Inc., 1970.
G. F. Uhlig, H. H. Davis, and H. C. Graham:Amer. Ceram. Soc. Bull., 1972, vol. 51, p. 337.
W. R. Wolf, M. L. Taylor, B. M. Hughes, T. O. Tiernan, and R. E. Sievers:Ann. Chem., in press.
A. U. Seybolt: Report No. 70-C-189, General Electric Co., Schenectady, N. Y., June 1970.
A. U. Seybolt: Report No. 70-C-051, General Electric Co., Schenectady, N. Y., January 1970.
N. S. Bornstein: Written DiscussionAmer. Soc. Test. Mater. Spec. Tech. Publ. 421, 1967, p. 221.
J. P. Baur, R. W. Bartlett, J. N. Ong, and W. M. Fassell:J. Electrochem. Soc., 1963, vol. 110, pp. 185–89.
F. S. Pettit: Pratt and Whitney Aircraft, Middletown, Connecticut, private communication, 1971.
Author information
Authors and Affiliations
Additional information
Formerly
Formerly
Rights and permissions
About this article
Cite this article
Davis, H.H., Graham, H.C. & Uhlig, G.F. Oxidation of Na2SO4 coated Ni-20Cr-2ThO2 . Metall Trans 3, 3247–3257 (1972). https://doi.org/10.1007/BF02661340
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02661340