Abstract
Thin films of ZrB x (0 ≤x ≤ 2) have been deposited on Si substrates by dc magnetron sputtering. The effects of annealing the films have been studied as a function of film composition by sheet resistance measurements, supplemented by Rutherford backscat-tering, Auger electron spectroscopy and x-ray diffraction. Significant departures of film composition from stoichiometric ZrB2 can result in an accompanying Zr-Si reaction cou-ple during annealing treatment which influences the overall film behaviour. These ef-fects are discussed with respect to the possible usefulness of ZrB2 films for VLSI metalli-sation and barrier layer applications.
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References
S. P. Murarka, “Suicides for VLSI Applications,” Academic Press Inc., New York, (1983).
M.-A. Nicolet, and S. S. Lau, “VLSI Electronics Microstruc- ture Science,” Vol. 6 (N. G. Einspruch and G. B. Larrabee, eds.), pp. 329–464, Academic Press Inc., New York, (1983).
M.-A. Nicolet, Thin Solid Films52, 415 (1978).
G. V. Samsonov and I. M. Vinitskii, “Handbook of Refractory Compounds,” IFI/Plenum, New York, (1980).
J. R. Shappirio and J. J. Finnegan, Thin Solid Films107, 81 (1983).
J. R. Shappirio, J. J. Finnegan, R. A. Lux, and D. C. Fox, Thin Solid Films119, 23 (1984).
J. Shappirio, J. Finnegan, R. Lux, D. Fox, J. Kwiatkowski, H. Katelus, and M. Nicolet, J. Vac. Sci. Technol.A3, 2255 (1983).
C. Y. Tay, I. R. Harris, and S. J. Wright, J. Electron. Mater.16, 107 (1987).
W. G. Moffat, “The Handbook of Binary Phase Diagrams,” G. E. Co., Schenectady, New York, (1978) (updated 1984).
S. P. Murarka, M. H. Read, C. J. Doherty, and D. B. Fraser, J. Electrochem. Soc.129, 293 (1982).
R. F. Bunshah, R. Nimmagadda, W. Dunford, B. A. Mov-Chan, A. V. Demchishin, and N. A. Chursanov, Thin Solid Films54, 85 (1978).
G. Ottaviani, F. Nava, G. Queirolo, G. Iannuzzi, G. De Santi, and K. N. Tu, Thin Solid Films146, 201 (1987).
J. G. Ryan, S. Roberts, G. J. Slusser, and E. D. Adams, Thin Solid Films153, 329 (1987).
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Tay, C.Y., Harris, I.R. & Wright, S.J. The behaviour of ZrB x (0 ≤x ≤ 2) thin films deposited on si substrate as a function of annealing treatment. J. Electron. Mater. 18, 511–516 (1989). https://doi.org/10.1007/BF02657781
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DOI: https://doi.org/10.1007/BF02657781