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The Solubility of Iron in Continuous Hot-Dip Galvanizing Baths

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Journal of Phase Equilibria

Abstract

An investigation to evaluate the effect of variations of bath temperature (450 to 480 °C) and Al concentration (0 to 0.5 %) on Fe solubility was conducted in order to better understand the formation of Fe containing intermetallic compounds in continuous galvanizing baths. Solubility relationships were first derived thermodynamically and then confirmed by experimental data. Results show that both temperature and concentration, in the range given above, significantly affect Fe solubility, and that it is important to control them within narrow limits to avoid formation of excessive amounts of intermetallic compounds. The methods used to derive the data thermodynamically and experimentally are reviewed and the results presented. Examples of practical applications are provided.

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Cited References

  1. M. Urednicek and J. Kirkaldy, “Mechanism of Iron Attack Inhibition Arising from Additions of Aluminum to Liquid Zn(Fe) During Galvanizing at 450 °C,”Z. Metallkd,64,419–427(1973).

    Google Scholar 

  2. A. D. Pelton,Thermodynamic Calculations of the Solubility of Fe in Molten Zinc-Aluminum Alloys Rich in Zine, ThermfactLtee, Montréal (1988).

    Google Scholar 

  3. S. May and G. Effenberg, “A Thermodynamic Evaluation of the Aluminum-ZincSystem,”Z. Metallkd., 77,449–453 (1986).

    Google Scholar 

  4. Poncet, M. App. Sc. Thesis, Ecole Polytechnique, Montréal(1980).

  5. R. Hultgren, R.L. Orr, P.D. Anderson, and K.K. Kelly,Selected Values of Thermodynamic Properties of Metals and Alloys, Wiley & Sons, NewYork(1963).

    Google Scholar 

  6. S.V. Radcliffe, B. L. Averback, and M. Cohen, “Relative Thermodynamic Properties of Solid Iron-Aluminum Alloys,”Acta Metall 9 169–176(1961).

    Article  Google Scholar 

  7. A. Coskun and J.F. Elliott, “Activity of Aluminum in Al-Fe Alloys at 1315 °C,”Trans. AIME, 242,253 (1968).

    Google Scholar 

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Paper presented at the 81st Meeting of the Galvanizers Association, Monterrey, Mexico, October 22–24,1989.

Currently with Inland Steel Research Laboratories.

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Bélisle, S., Lezon, V. & Gagné, M. The Solubility of Iron in Continuous Hot-Dip Galvanizing Baths. JPE 12, 259–265 (1991). https://doi.org/10.1007/BF02649914

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  • DOI: https://doi.org/10.1007/BF02649914

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