Abstract
Concentration cells of the type: Mg(s) |MgCl2 in (LiCl-KCl)eut(l) |Mg-Zn(l) have been employed for a study of the thermodynamic properties of dilute Mg-Zn alloys in the range from 0.01 < XMg < 0.17 and at temperatures below the melting point of Mg, 922 K. The data were discussed in terms of the Krupkowski formulae, Wagner's linear relations of In γMg vs XMg and Darken's quadratic formalism.
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References
A. Krupkowski:Bull. Acad. Pol. Sci. Lett., Ser. A, 1950, vol. 1, pp. 15–45.
C, Wagner:Thermodynamics of Alloys, Addison-Wesley Publishing Co., Inc., Cambridge, Mass., 1952.
W. Ptak and Z. Moser:Trans. TMS-AIME, 1968, vol. 242, pp. 558–65.
W. Ptak and Z. Moser:J. Electrochem. Soc., 1972, vol. 119, pp. 843–49.
L. Darken:J. Amer. Chem. Soc., 1950, vol. 2, pp. 2909–16.
Z. Moser and K. Fitzner:Met. Tran., 1972, vol. 3, pp. 3109–14.
R. Hultgren, R. Orr, P. Anderson, and K. Kelley:Selected Values of Thermo- dynamic Properties of Metals and Alloys, John Wiley and Sons, New York, 1953: Supplement, loose-leaf sheets, 1968-71.
P. Chiotti and E. Stevens:Trans. TMS-AIME, 1965, vol. 233, pp. 198–203.
V. Eremenko and G. Tukashenko:Proc. IAEA Symp. on Thermodynamics, Vienna, 1965.
J. Terpilowski:Bull. Acad. Pol. Sci., Ser. Sci. Chim., 1962, vol. 10, pp. 221–25.
U.Z. Kozuka, J. Moriyama, and I. Kushima:J. Electrochem. Soc, Japan, Over- seas ed., 1960, vol. 28, pp. E212-15.
W. Ptak and Z. Moser:Bull. Acad. Pol. Sci, Ser. Sci. Techn., 1972, vol. 20, pp. 735–42.
M. Hansen and K. Anderko:Constitution of Binary Alloys, McGraw-Hill Book Co., New York, 1958.
K. Kelley:U.S. Bur. Mines, Bull. no. 584,1960.
Z. Moser:Butt. Acad. Pol. Sci., Ser. Sci. Techn., 1969, vol. 17, pp. 27–33.
Z. Moser:Bull. Acad. Pol. Sci., Ser. Sci. Techn., 1970, vol. 18, pp. 51–56.
L. S. Darken:Trans. TMS-AIME, 1967, vol. 239, pp. 80–89.
W. Ptak:Arch. Hutn., 1968, vol. 13, pp. 251–72.
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This research was done at the Institute of Inorganic Chemistry, The Technical University of Norway, Trondheim, Norway.
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Moser, Z. Thermodynamic properties of dilute solutions of magnesium in zinc. Metall Trans 5, 1445–1450 (1974). https://doi.org/10.1007/BF02646631
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DOI: https://doi.org/10.1007/BF02646631