Abstract
The formation of potentially “fishy” off flavor components, especially 2,4,7-decatrienals, in various rancid mackerel oils has been semiquantitatively investigated using preparative thin layer chromatography (TLC) and gas liquid chromatography (GLC) methods. A combination of 2 GLC analyses can be directly employed for free aldehyde analysis. This GLC method is faster and gives a better recovery than the alternative TLC proceeding through the dinitrophenylhydrazone derivatives of the carbonyl compounds. Kinetic relations between decatrienal formation and the degree of autoxidation of polyenoic fatty compounds present in mackerel oil are discussed. The decreases in major polyenoic fatty acids rancid oils, measured by the ratios
or
can be related to the formation of 2,4,7-decatrienals and other unsaturated aldehydes.
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References
Meijboom, P.W., and J.B.A. Stroink, JAOCS 49:555 (1972).
Badings, H.T., Neth. Milk Dairy J. 19:69 (1965).
Badings, H.T., JAOCS 50:334 (1973).
Ackman, R.G., J. Fd. Technol. 2:169 (1967).
Ackman, R.G., and C.A. Eaton, Can. Inst. Food Technol. J. 4:169 (1971).
Pohl, P., and H. Wagner, Fette Seifen Anstrichm. 74:424 (1972).
Osbond, J.M., P.G. Philpott and J.C. Wickens, J. Chem. Soc. 2779 (1961).
Taylor, W.R., and F.M. Storng, JAOCS 3:1396 (1950).
Schwartz, D.P., and O.W. Parks, Anal. Chem. 33:1396 (1961).
Bligh, E.G., and W.J. Dyer, Can. J. Biochem. Physiol. 37:911 (1959).
Ke, P.J., and R.G. Ackman, JAOCS 50:429 (1973).
Wyatt, C.J., and E.A. Day, J. Food Sci. 28:305 (1963).
Lea, C.H., and A. Hobson-Frohock, J. Sci. Agr. 16:18 (1965).
Golovnya, R.V., and V.P. Uralets, Die Nahrung 16:497 (1972).
Meijboom, P.W., Fette Seifen Anstrichm. 70:477 (1968).
Morrison, W.R., and L.M. Smith, J. Lipid Res. 5:600 (1964).
Golovnya, R.V., and V.P. Uralets, Dokl. Akad, Nauk. 177:350 (1967).
Hollstein, E., F. Baumgardt and N. Franzke, Die Nahrung 17:659 (1973).
Shono, T., and M. Toyomizu, Sci. Bull. Fac. Agr. (Kyushu Univ. Japan) 26:233 (1972).
Ackman, R.G., C.A. Eaton and P.J. Ke, J. Fish. Res. Bd. Can. 24:2563 (1967).
Ackman, R.G., and R.D. Burgher, JAOCS 42:35 (1965).
Ackman, R.G., Lipids 5:950 (1970).
Nagayama, F., S. Imano and Y. Naito, Bull. Jap. Soc. Sci. Fish. 37:415 (1971).
Ke, P.J., R.G. Ackman and B.A. Linke, New Series Circular No. 53, Environment Canada, Fisheries and Marine Services, Halifax Laboratory, Halifax, Nova Scotia, Canada, 1975.
Dubrarcic, M.F., and W.W. Nawav, J. Agr. Food Chem. 17:639 (1969).
Fisher, M.P., and L.A. Wishner, Lipids, 3:88 (1968).
Yu, T.C., E.A. Day and R.O. Sinnhuber, J. Food Sci. 26:192 (1961).
Shimomura, M., F. Yushimatsu and F. Matsumoto, Kaseisaku Zasshi 22:106 (1971).
Gruger, E.H., Jr., J. Agr. Food Chem. 20:781 (1972).
Miller, A., III, R.A. Scanlon, J.S. Lee and L.M. Libbey, J. Fish Res. Bd. Can. 29:1125 (1972).
Miller, A., III, R.A. Scanlon, J.S. Lee and L.M. Libbey, Appl. Microbiol. 25:952 (1973).
Schultz, H.W., E.A. Day and R.O. Sinnhuber, “Lipids and Their Oxidation,” Avi Publishing Co., Inc., Westport, Connecticut, 1962.
Labuza, T.P., CRC Critical Rev. Food Tech. 2:355 (1971).
Morita, M. and M. Fujimaki, J. Agr. Food Chem. 21:860 (1973).
Kimoto, W.I., and A.M. Gaddis, JAOCS 51:307 (1974).
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Ke, P.J., Ackman, R.G. & Linke, B.A. Autoxidation of polyunsaturated fatty compounds in mackerel oil: Formation of 2,4,7-decatrienals. J Am Oil Chem Soc 52, 349–353 (1975). https://doi.org/10.1007/BF02639193
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DOI: https://doi.org/10.1007/BF02639193