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Polymerizable derivatives of long-chain fatty alcohols. III. Copolymers of some alkyl acrylates and acrylonitrile

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Journal of the American Oil Chemists Society

Abstract

Coplymers of acrylonitrile containing 5 to 28 mole % (11 to 70 weight %) of three alkyl acrylates (butyl, octyl, and octadecyl) were prepared in t-butanol solution. The copolymers were capable of being molded at about 300–400°F. under a pressure of about 2,000 p.s.i. The magnitude of both the tensile strength and the characteristic low temperature of the copolymers varied inversely with the weight percentage of the acrylate present without regard to its alkyl type. The copolymers were oriented with an accompanying three-fold increase in the tensile strength. Good resistance to several selected reagents was shown by all the copolymers.

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Eastern Utilization Research and Development Division, Agricultural Research Service, U.S. Department of Agriculture.

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Jordan, E.F., Palm, W.E. & Port, W.S. Polymerizable derivatives of long-chain fatty alcohols. III. Copolymers of some alkyl acrylates and acrylonitrile. J Am Oil Chem Soc 38, 231–233 (1961). https://doi.org/10.1007/BF02636764

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  • DOI: https://doi.org/10.1007/BF02636764

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