Abstract
Coplymers of acrylonitrile containing 5 to 28 mole % (11 to 70 weight %) of three alkyl acrylates (butyl, octyl, and octadecyl) were prepared in t-butanol solution. The copolymers were capable of being molded at about 300–400°F. under a pressure of about 2,000 p.s.i. The magnitude of both the tensile strength and the characteristic low temperature of the copolymers varied inversely with the weight percentage of the acrylate present without regard to its alkyl type. The copolymers were oriented with an accompanying three-fold increase in the tensile strength. Good resistance to several selected reagents was shown by all the copolymers.
Similar content being viewed by others
References
Chaterjee, D., and Palit, S.N., Proc. Roy. Soc. (London),A227, 252 (1955).
Clash, R.F. Jr., and Berg, R.M., Modern Plastics,21, No. 11, 119 (1944).
Dietz, T.J., and Hansen, J.E., Rubber Age,68, 699 (1951); Filachione, E.M., Fitzpatrick, T.J., Rehberg, C.E., Woodward, C.F., Palm, W.E., and Hansen, J.E.,ibid., Modern Plastics,72, 631 (1953); Hansen, J.E., and Palm, W.E.,ibid., Modern Plastics,75, 677 (1954).
Fondyce, R.G., and Chapin, E.C., J. Am. Chem.Soc.,69, 581 (1947); Fordyce, R.G.ibid. Modern Plastics,69 1903 (1947); Smith W.V.,ibid. Modern Plastics,70, 2177 (1948); Mino, G., J. Polymer Sci.,22, 369 (1956).
Jordan, E.F., Jr., Palm, W.E., Witnauer, L.P., and Port, W.S., Ind. Eng. Chem.,49, 1695 (1957).
Jordan, E.F. Jr., Doughty, K.M., and Port, W.S., J. Applied Polymer Sci.,4, 203 (1960).
Jordan, E.F. Jr., Palm, W.E., Swern, Daniel, Witnauer, L.P., and Port, W.S., J. Polymer Sci.,32, 33 (1958).
Mandelkerh, L., and Flory, P.J., J. Am. Chem. Soc.,73, 3210 (1951); Fox, T.G., Phys. Rev.86, 652 (1952); Boyer, R.F., J. Appl. Phys.22, 723 (1951);25, 825 (1954).
Marvel, C.S., and Schwen, R., J. Am. Chem. Soc.,79, 6003 (1957); Okamura, S., and Yamashita, J., J. Soc. Textile and Cellulose Ind., Japan,9 444 (1953); [C.A.48, 1010b (1954)]; Tamikado, T., and Iwakura, Y., J. Polymer Sci.36, 173 (1959).
Port, W.S., Jordan, E.F. Jr., Palm, W.E., Witnauer, L.P., Hansen, J.E., and Swern, Daniel, U.S.D.A., Agricultural Research Service, A.I.C.,366 (1953).
Port, W.S., Jordan, E.F. Jr., Palm, W.E., Witnauer, L.P., Hansen, J.E., and Swern, Daniel, Ind. Eng. Chem.,47, 472 (1955).
Rosenberg, J., and Greenberg, H.L., Modern Plastics,35, No. 4, 173 (1957).
Silbert, L.S., Jacobs, Z.B., Palm, W.E., Witnauer, L.P., Port, W.S., and Swern, Daniel, J. Polymer Sci.,21, 161 (1956).
Author information
Authors and Affiliations
Additional information
Eastern Utilization Research and Development Division, Agricultural Research Service, U.S. Department of Agriculture.
About this article
Cite this article
Jordan, E.F., Palm, W.E. & Port, W.S. Polymerizable derivatives of long-chain fatty alcohols. III. Copolymers of some alkyl acrylates and acrylonitrile. J Am Oil Chem Soc 38, 231–233 (1961). https://doi.org/10.1007/BF02636764
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02636764