Abstract
A major constituent fatty acid (31.2%) fromCalea urticaefolia (Mill.) DC. seed oil is the previously unknowntrans-3,cis-9,cis-12-octadecatrienoic acid. The oil also contains 2.2% of an unidentified acid and others with gas-liquid chromatographic characteristics that correspond to the conventional fatty acids: myristic, 0.1%; palmitic, 9.3%; stearic, 2.9%; oleic, 5.3%; and linoleic, 48.9%.
Similar content being viewed by others
References
Aho, Y., O. Harva and S. Nikkila, Teknillisen Kemian Aikakauslehti19, 390–392 (1962).
AOCS Official and Tentative Methods, 2nd ed., Cd 7–58, Chicago, Ill. (1959).
Arndt, F., Org. Syn., Col. Vol.2, 165–167 (1943).
Aylward, F., and C. V. N. Rao, J. Appl. Chem. (London)6, 248–252 (1956).
Bagby, M. O., C. R. Smith, Jr., K. L. Mikolajczak and I. A. Wolff, Biochemistry1, 632–639 (1962).
Bagby, M. O., C. R. Smith, Jr., T. K. Miwa, R. L. Lohmar and I. A. Wolff, J. Org. Chem.26, 1261–1266 (1961).
Chisholm, M. J., and C. Y. Hopkins, Can. J. Chem.41, 1888–1892 (1963).
Davidoff, F., and E. D. Korn, Biochem. Biophys. Res. Commun.9, 54–58 (1962).
Davidoff, F., and E. D. Korn, J. Biol. Chem.238, 3199–3209 (1963).
Debuch, H., Z. Naturforsch.16B, 561–567 (1961).
Elomaa, E., T. Lehtinen and J. Alkjaeroi, Suomen KemistilehtiB36, 52–54 (1963); CA59, 5014h (1963).
Gellerman, J. L., and H. Schlenk, Experientia19, 522–523 (1963).
Hilditch, T. P., and J. A. Lovern, J. Soc. Chem. Ind. (London)47, 105–111T (1928).
Holman, R. T., in “Food Enzymes,” ed. H. W. Schultz, The Avi Publishing Company, Inc., Westport, Conn., 1960, p. 77.
Jackman, L. M., “Applications of Nuclear Magnetic Resonance Spectroscopy in Organic Chemistry,” Pergamon Press, New York, 1959, p. 60.
Klenk, E., and Knipprath, Z. Physiol. Chem.327, 283–285 (1962).
Lemieux, R. U., and E. von Rudloff, Can. J. Chem.33, 1701–1709 (1955).
MacGee, J., Anal. Chem.31, 298–302 (1959).
Meade, E. M., in “Progress in the Chemistry of Fats and Other Lipids,” Vol. 4, eds. R. T. Holman, W. O. Lundberg and T. Malkins, Pergamon Press, New York, 1957, p. 56.
Miwa, T. K., K. L. Mikolajczak, F. R. Earle and I. A. Wolff, Anal. Chem.32, 1739–1742 (1960).
O’Connor, R. T., JAOCS36, 627–631 (1959).
Pitt, G. A. J., and R. A. Morton, in “Progress in the Chemistry of Fats and Other Lipids,” Vol. 4, eds. R. T. Holman, W. O. Lundberg and T. Malkins, Pergamon Press, New York, 1957, pp. 231 and 242.
Rao, C. V. N., J. Sci. Ind. Research (India)18B, 131–132 (1959).
Schilling, K., Fette Seifen Anstrichmittel63, 421–425 (1961).
Scholfield, C. R., E. P. Jones, J. Nowakowska, E. Selke and H. J. Dutton, JAOCS38, 208–211 (1961).
Scholfield, C. R., J. Nowakowska and H. J. Dutton,Ibid. 37, 27–30 (1960).
Smith, C. R. Jr., M. O. Bagby, T. K. Miwa, R. L. Lohmar and I. A. Wolff, J. Org. Chem.25, 1770–1774 (1960).
Stodola, F. H., Microchem. J.7, 389–399 (1963).
Storey, W. H., Jr., JAOCS37, 676–678 (1960).
Tiers, G. V. D., J. Phys. Chem.62, 1151–1152 (1958).
Author information
Authors and Affiliations
Additional information
No. Utiliz. Res. & Dev. Div., ARS, USDA.
About this article
Cite this article
Bagby, M.O., Siegl, W.O. & Wolff, I.A. A new acid fromcalea urticaefolia seed oil:trans-3,cis-9,cis-12-octadecatrienoic acid. J Am Oil Chem Soc 42, 50–53 (1965). https://doi.org/10.1007/BF02558255
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02558255