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Total reorganization energy and its components in processes of one-electron oxidation of phosphorus compounds in acetonitrile

  • Physical Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The ionization processes of phosphorus(III) and (IV) compounds oxidized in the potential range of 1.8–4.0 Vvs. Ag/0.01M AgNO3 in MeCN were studied by chronovoltammetry on a Pt ultramicroelectrode in acetonitrile and by photoelectron spectroscopy in the gas phase. A relationship between the half-wave potential (E 1/2) and vertical ionization potential (IP v)E 1/2=0.89IP v–6.27 is fulfilled in a wide potential range from−0.37 to 3.98 V. The total reorganization energy of the system (1.45–2.50 V) and the energy of reorganization of the solvate shell (0.9–1.9 eV) were estimated.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan'Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan', Russian Federation

    V. V. Yanilkin & V. V. Zverev

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  1. V. V. Yanilkin
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  2. V. V. Zverev
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Translated fromIzvestiya Akademii Nauk. seriya Khimicheskaya, No. 4, pp. 682–689, April, 1999.

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Yanilkin, V.V., Zverev, V.V. Total reorganization energy and its components in processes of one-electron oxidation of phosphorus compounds in acetonitrile. Russ Chem Bull 48, 677–685 (1999). https://doi.org/10.1007/BF02496245

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  • DOI: https://doi.org/10.1007/BF02496245

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